Influence of molecular weight on impact fracture behavior of injection molded high density polyethylene: Scanning electron micrograph observations

2008 ◽  
Vol 109 (2) ◽  
pp. 1161-1167 ◽  
Author(s):  
Bin Li ◽  
Guan Gong ◽  
Bang-Hu Xie ◽  
Wei Yang ◽  
Ming-Bo Yang
Keyword(s):  
Molecular Weight ◽  
High Density Polyethylene ◽  
Fracture Behavior ◽  
High Density ◽  
Impact Fracture ◽  
Electron Micrograph ◽  
Scanning Electron Micrograph ◽  
Impact Fracture Behavior ◽  
Injection Molded ◽  
Scanning Electron

Characterization of Impact Fracture Behavior of Biodegradable PLA/PCL Polymer Blend

2006 ◽  
Vol 326-328 ◽  
pp. 1569-1572 ◽  
Author(s):  
Tetsuo Takayama ◽  
Mitsugu Todo ◽  
Kazuo Arakawa
Keyword(s):  
Fracture Behavior ◽  
Impact Resistance ◽  
Impact Fracture ◽  
Fracture Mechanisms ◽  
Thermoplastic Polymer ◽  
Fracture Properties ◽  
Impact Fracture Behavior ◽  
The Impact ◽  
Scanning Electron

Attempts have been made to improve the impact resistance of biodegradable thermoplastic polymer, PLA. A ductile biodegradable polymer, PCL, has been used to improve such property of PLA by using blending technique. Details of the impact fracture properties and mechanisms of PLA/PCL blends, however, have not fully been understood yet. Recently, it was also found that LTI can improve the immiscibility between PLA and PCL. In this study, PLA/PCL and PLA/PCL/LTI blends were prepared, and their impact fracture toughness values were measuredto assess the effect of PCL content and LTI addition on the impact resistance. Fracture mechanisms of the polymer blends were also characterized by scanning electron microscopy.

Analytical and High-Resolution EM Study of Crystalline Phases formed at Metal-Ceramic Interface

1990 ◽  
Vol 48 (2) ◽  
pp. 426-427
Author(s):  
N. Merk ◽  
A. P. Tomsia ◽  
G. Thomas
Keyword(s):  
Cross Section ◽  
Dissimilar Materials ◽  
Ceramic Materials ◽  
Electron Micrograph ◽  
Scanning Electron Micrograph ◽  
Structural Applications ◽  
Metal Ceramic ◽  
The Subject ◽  
Ceramic Compounds ◽  
Scanning Electron

A recent development of new ceramic materials for structural applications involves the joining of ceramic compounds to metals. Due to the wetting problem, an interlayer material (brazing alloy) is generally used to achieve the bonding. The nature of the interfaces between such dissimilar materials is the subject of intensive studies and is of utmost importance to obtain a controlled microstructure at the discontinuities to satisfy the demanding properties for engineering applications . The brazing alloy is generally ductile and hence, does not readily fracture. It must also wett the ceramic with similar thermal expansion coefficient to avoid large stresses at joints. In the present work we study mullite-molybdenum composites using a brazing alloy for the weldment.A scanning electron micrograph from the cross section of the joining sequence studied here is presented in Fig. 1.

scholarly journals Applicability of the Cox-Merz Rule to High-Density Polyethylene Materials with Various Molecular Masses

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1218
Author(s):  
Raffael Rathner ◽  
Wolfgang Roland ◽  
Hanny Albrecht ◽  
Franz Ruemer ◽  
Jürgen Miethlinger
Keyword(s):  
Molecular Weight ◽  
Pressure Drop ◽  
High Molecular Weight ◽  
High Density Polyethylene ◽  
Parallel Plate ◽  
Empirical Relationship ◽  
Polymer Processing ◽  
High Density ◽  
Viscosity Data ◽  
Molecular Masses

The Cox-Merz rule is an empirical relationship that is commonly used in science and industry to determine shear viscosity on the basis of an oscillatory rheometry test. However, it does not apply to all polymer melts. Rheological data are of major importance in the design and dimensioning of polymer-processing equipment. In this work, we investigated whether the Cox-Merz rule is suitable for determining the shear-rate-dependent viscosity of several commercially available high-density polyethylene (HDPE) pipe grades with various molecular masses. We compared the results of parallel-plate oscillatory shear rheometry using the Cox-Merz empirical relation with those of high-pressure capillary and extrusion rheometry. To assess the validity of these techniques, we used the shear viscosities obtained by these methods to numerically simulate the pressure drop of a pipe head and compared the results to experimental measurements. We found that, for the HDPE grades tested, the viscosity data based on capillary pressure flow of the high molecular weight HDPE describes the pressure drop inside the pipe head significantly better than do data based on parallel-plate rheometry applying the Cox-Merz rule. For the lower molecular weight HDPE, both measurement techniques are in good accordance. Hence, we conclude that, while the Cox-Merz relationship is applicable to lower-molecular HDPE grades, it does not apply to certain HDPE grades with high molecular weight.

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