Poly(methyl acrylate) and copolymer of acrylic acid and butyl acrylate prepared by γ-irradiation in the presence of 1,1-diphenylethene: Synthesis and application in emulsion polymerization

2007 ◽  
Vol 105 (6) ◽  
pp. 3492-3499 ◽  
Author(s):  
Zongtao Wu ◽  
Zhicheng Zhang
Keyword(s):  
Acrylic Acid ◽  
Emulsion Polymerization ◽  
Methyl Acrylate ◽  
Butyl Acrylate ◽  
Γ Irradiation

Ab initio RAFT emulsion polymerization of butyl acrylate mediated by poly(acrylic acid) trithiocarbonate

2013 ◽  
Vol 4 (3) ◽  
pp. 752-762 ◽  
Author(s):  
Marion Chenal ◽  
Laurent Bouteiller ◽  
Jutta Rieger
Keyword(s):  
Acrylic Acid ◽  
Ab Initio ◽  
Emulsion Polymerization ◽  
Butyl Acrylate ◽  
Poly Acrylic Acid

Research on Synthesis of Neutral Sizing Agent by Soap-Free Emulsion Polymerization

2011 ◽  
Vol 233-235 ◽  
pp. 2755-2759
Author(s):  
Hong Xiang Zhu ◽  
Shuang Fei Wang ◽  
Ying Hui Wang ◽  
Nan Nan Xia ◽  
Hui He
Keyword(s):  
Acrylic Acid ◽  
Microwave Irradiation ◽  
Emulsion Polymerization ◽  
Butyl Acrylate ◽  
Sodium Lauryl Sulfate ◽  
Reaction System ◽  
Protective Atmosphere ◽  
Lauryl Sulfate ◽  
Comprehensive Properties ◽  
Soap Free Emulsion Polymerization

In this paper, a sizing agent applied in papermaking was synthesized via emulsion polymerization using styrene (St), methyl acrylic acid (MAA), methyl methacrylate (MMA) and butyl acrylate (BA) as monomer. In this process, potassium persulfate (KPS) was used as a initiator and sodium lauryl sulfate (SDS) and OP-10 were used as the emulsifier or no emulsifier was used, while NB2Bwas used as a protective atmosphere for the reaction system. The product of emulsion polymerization with St and BA has a good comprehensive properties and a certain sizing effectiveness. Furthermore, the microwave irradiation could not only produce emulsions with small diametric particles but also shorten the polymerized time greatly.

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