Fly-ash particles and precipitated silica as fillers in rubbers. II. Effects of silica content and Si69-treatment in natural rubber/styrene–butadiene rubber vulcanizates

2007 ◽  
Vol 104 (5) ◽  
pp. 3396-3405 ◽  
Author(s):  
N. Sombatsompop ◽  
E. Wimolmala ◽  
T. Markpin
Keyword(s):  
Fly Ash ◽  
Natural Rubber ◽  
Silica Content ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Precipitated Silica ◽  
Styrene Butadiene

scholarly journals Effect of Admixtures on Mechanical Properties of Cementitious Mortar

2020 ◽  
Vol 6 (11) ◽  
pp. 2175-2187
Author(s):  
Ahmed Jawad Shaukat ◽  
Hu Feng ◽  
Anwar Khitab ◽  
Ahmad Jan
Keyword(s):  
Fly Ash ◽  
Mechanical Strength ◽  
Silica Fume ◽  
Weight Ratio ◽  
Silica Content ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Water To Cement Ratio ◽  
Primary Focus ◽  
Styrene Butadiene

In the current study, the primary focus is to investigate the effect of Styrene Butadiene Rubber (SBR), silica fume and fly ash on compressive and flexure strengths of cementitious mortar. Three types of specimens are prepared; the first series comprises of control specimen; the second one consists of the mortar’s specimen modified with SBR and the third one consists of the mortar’s specimen modified with SBR in a combination of fly ash and silica fumes. Mortar samples are cast in the weight ratio of 1:2.75 (cement: sand). The SBR is added at a rate of 20% of the mass of cement. The water to cement ratio (W/C) is kept at 0.5 for control specimens and the quantity of mixing water in SBR-containing samples is reduced by the same amount as the SBR is added: The adjustment is meant to obtain same consistency for all the specimens.  20% fly ash and 2.5% silica fume are added to the mortar as replacement of cement. Compressive and flexure tests are carried out according to ASTM standards. Moreover, SEM is also performed on samples at the age of 28 days. Studies reveal that SBR and SCMs reduce the mechanical strength of the mortars. SEM and EDS studies show that SBR hinders the formation of albite, whereas silica content from silica fumes and fly ash converts CaCO3 to Wollastonite (a white loose powder), which is responsible for the reduction of mechanical strength. The study also confirms that the addition of SBR in place of water hinders the formation of primary and secondary hydration products. Doi: 10.28991/cej-2020-03091610 Full Text: PDF

scholarly journals Hybrid Silica-Based Fillers in Nanocomposites: Influence of Isotropic/Isotropic and Isotropic/Anisotropic Fillers on Mechanical Properties of Styrene-Butadiene (SBR)-Based Rubber

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2413
Author(s):  
Mariapaola Staropoli ◽  
Vincent Rogé ◽  
Enzo Moretto ◽  
Joffrey Didierjean ◽  
Marc Michel ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Silica Nanoparticles ◽  
Synergetic Effect ◽  
Mechanical Analysis ◽  
Rubber Matrix ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Precipitated Silica ◽  
Scanning Transmission ◽  
Styrene Butadiene

The improvement of mechanical properties of polymer-based nanocomposites is usually obtained through a strong polymer–silica interaction. Most often, precipitated silica nanoparticles are used as filler. In this work, we study the synergetic effect occurring between dual silica-based fillers in a styrene-butadiene rubber (SBR)/polybutadiene (PBD) rubber matrix. Precipitated Highly Dispersed Silica (HDS) nanoparticles (10 nm) have been associated with spherical Stöber silica nanoparticles (250 nm) and anisotropic nano-Sepiolite. By imaging filler at nano scale through Scanning Transmission Electron Microscopy, we have shown that anisotropic fillers align only in presence of a critical amount of HDS. The dynamic mechanical analysis of rubber compounds confirms that this alignment leads to a stiffer nanocomposite when compared to Sepiolite alone. On the contrary, spherical 250 nm nanoparticles inhibit percolation network and reduce the nanocomposite stiffness.

Tensile Behavior after Oxidative Aging of Gum and Black-Filled Vulcanizates of SBR and NR

1999 ◽  
Vol 72 (4) ◽  
pp. 721-730 ◽  
Author(s):  
G. R. Hamed ◽  
J. Zhao
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
Tensile Behavior ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Oxidative Aging ◽  
Prolonged Aging ◽  
Aging Period ◽  
Early Aging ◽  
Styrene Butadiene

Abstract Typical sulfur-cured vulcanizates of styrene-butadiene rubber (SBR) and natural rubber (NR) were prepared, and subjected to air-oven aging at 100 °C. Gum specimens exhibited an initial aging period in which stiffness was unchanged, while tensile strength and strain-to-break were significantly reduced. In contrast, black-filled vulcanizates stiffened during early aging. After intermediate aging times, NR specimens softened, while SBR stiffened. With prolonged aging, all compositions became hard and inextensible.

Thermal conductivity of styrene butadiene rubber compounds with natural rubber prophylactics waste as filler

1999 ◽  
Vol 35 (9) ◽  
pp. 1687-1693 ◽  
Author(s):  
N.S. Saxena ◽  
P. Pradeep ◽  
G. Mathew ◽  
S. Thomas ◽  
M. Gustafsson ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Natural Rubber ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Compounds ◽  
Styrene Butadiene

Gas products generation mechanism during co-pyrolysis of styrene-butadiene rubber and natural rubber

2021 ◽  
Vol 401 ◽  
pp. 123302
Author(s):  
Qirong Yang ◽  
Shuangpeng Yu ◽  
Haowen Zhong ◽  
Ting Liu ◽  
Erren Yao ◽  
...  
Keyword(s):  
Natural Rubber ◽  
Generation Mechanism ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Gas Products ◽  
Styrene Butadiene
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