Physical and electrochemical properties of low molecular weight poly(ethylene glycol)-bridged polysilsesquioxane organic–inorganic composite electrolytes via sol–gel process

2006 ◽  
Vol 103 (4) ◽  
pp. 2752-2758 ◽  
Author(s):  
C. Y. Yuan ◽  
S. Y. Chen ◽  
J. C. Tang ◽  
H. C. Yang ◽  
Y. W. Chen-Yang
Keyword(s):  
Molecular Weight ◽  
Ethylene Glycol ◽  
Sol Gel ◽  
Low Molecular Weight ◽  
Composite Electrolytes ◽  
Poly Ethylene Glycol ◽  
Sol Gel Process ◽  
Bridged Polysilsesquioxane ◽  
Poly Ethylene ◽  
Inorganic Composite

Microporous Bio-Membrane Materials Based on High Molecular Weight Polylactide and Low Molecular Weight Poly(ethylene glycol)

2012 ◽  
Vol 567 ◽  
pp. 123-126
Author(s):  
Teng Fei Shen ◽  
Man Geng Lu ◽  
Li Yan Liang
Keyword(s):  
Molecular Weight ◽  
Ethylene Glycol ◽  
High Weight ◽  
Low Molecular Weight ◽  
Poly Ethylene Glycol ◽  
Degradation Rates ◽  
Degradation Behaviors ◽  
The Mean ◽  
Poly Ethylene ◽  
Lower Glass Transition Temperature

In this work, microporous membrane biomaterials based on high weight molecular polylactide (PLA) and low molecular weight poly(ethylene glycol) (PEG) using rapid solvent evaporation method were prepared and investigated. The effect of PEG segments added on the thermal and degradation behaviors was studied. According to the results, produced PLA/PEG biomaterial has lower glass transition temperature (Tg)in comparison with neat PLA. It was also found that the degradation rates of the PLA/PEG biomaterials were significantly increased with adding of PEG, which explained by increasing hydrophilic groups. For better porous fixation, CL-blocked polyisocyanate (CL-bp), which was synthesized from reaction of isophorone diisocyanate (IPDI) with dimethylol propionic acid (DMPA) and Trimethylolpropane (TMP) followed by addition of caprolactam (CL), were introduced. The microporous forms were observed by the scanning electron microscope (SEM), which showed the mean diameters of prepared PLA/PEG microporous were around 10μm.

Plasticization of poly(lactide) with blends of tributyl citrate and low molecular weight poly(d,l-lactide)-b-poly(ethylene glycol) copolymers

2009 ◽  
Vol 45 (10) ◽  
pp. 2839-2848 ◽  
Author(s):  
Yahia Lemmouchi ◽  
Marius Murariu ◽  
Ana Margarida Dos Santos ◽  
Allan J. Amass ◽  
Etienne Schacht ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Ethylene Glycol ◽  
Low Molecular Weight ◽  
Poly Ethylene Glycol ◽  
Poly Ethylene

Star-Shaped Poly(ethylene glycol)-block-polyethylenimine Copolymers Enhance DNA Condensation of Low Molecular Weight Polyethylenimines

2002 ◽  
Vol 3 (5) ◽  
pp. 926-936 ◽  
Author(s):  
Holger Petersen ◽  
Klaus Kunath ◽  
Alison L. Martin ◽  
Snjezana Stolnik ◽  
Clive J. Roberts ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Ethylene Glycol ◽  
Dna Condensation ◽  
Low Molecular Weight ◽  
Poly Ethylene Glycol ◽  
Poly Ethylene

Controlled Hierarchical Pore Structures in Ethylene-Bridged Polysilsesquioxane Gels

2003 ◽  
Vol 788 ◽  
Author(s):  
Yuki Kobayashi ◽  
Kazuki Nakanishi ◽  
Kazuyuki Hirao
Keyword(s):  
Phase Separation ◽  
Ethylene Glycol ◽  
Triblock Copolymers ◽  
Sol Gel ◽  
Poly Ethylene Glycol ◽  
Bridged Polysilsesquioxane ◽  
Sol Gel Transition ◽  
Poly Ethylene ◽  
Hierarchical Pore ◽  
Gel Transition

ABSTRACTFormation of hierarchical macropores and mesopores in ethylene-bridged polysilsesquioxane sol-gel systems via concurrent sol-gel transition and phase separation induced by the incorporation of supramolecular templats has been investigated. A series of poly(ethylene-glycol)-poly(propyleneglycol)- poly(ethyleneglycol) triblock copolymers, EOPOEOs, have been employed as supramolecular templates, while 1,2-bis(trimethoxysilyl)ethane was used as a polysilsesquioxane source. Successful combination of templated mesopores and well-defined macropores due to phase-separation has been found in the system with EOPOEOs having 70 PO units and respective 20 EO units. Although similar macroporous morphology has been obtained for all the EOPOEOs with EO chain longer or shorter than 20 units, the optimum composition for the co-continuous macropores and that for templated mesopores deviated from each other, resulting in the failure of producing hierarchical macropores and mesopores.

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