The role of the terminal functional group of self-assembled monolayers on fiber matrix adhesion

2007 ◽  
Vol 106 (1) ◽  
pp. 462-469 ◽  
Author(s):  
E. Feresenbet ◽  
D. Raghavan ◽  
G. A. Holmes
Keyword(s):  
Functional Group ◽  
Self Assembled Monolayers ◽  
Matrix Adhesion ◽  
Assembled Monolayers ◽  
Fiber Matrix ◽  
Self Assembled ◽  
Terminal Functional Group

scholarly journals Influence of the nature of the alkanethiol terminal group on the electrochemical stability and blocking ability of self-assembled nanofilms on Au electrode

2021 ◽  
Vol 340 ◽  
pp. 01013
Author(s):  
Svetlana Ovchinnikova ◽  
Tatyana Aleksandrova
Keyword(s):  
Functional Group ◽  
Energy State ◽  
Terminal Group ◽  
Electrochemical Stability ◽  
Self Assembled Monolayers ◽  
Oh Groups ◽  
End Groups ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Terminal Functional Group

We studied the effect of the nature of the terminal group of thiols with the same chain length HS (CH2)8 – R (R: -CH3, -CH2OH, -NH2) on the electrodesorption behaviour of well-formed SAMs (the self-assembled monolayers), their stability and blocking ability using voltammetry and chronoamperometry. The nature of the terminal functional group determines the surface properties of SAM and provides the basis for subsequent interactions (for example, with peptides, proteins, DNA) in order to create sensors and bioagents. For the studied thiols, the hydrophilicity of the end groups increases in the series -CH3<< -NH2 ≤ -CH2OH; they also differ in polarity and the possibility of protonation of the amino group. For thiols with -CH3 and -CH2OH groups, an increase in the hydrophilicity of the terminal group leads to the formation of less stable and less ordered films. The replacement of carbon by nitrogen with approximately the same hydrophilicity of the groups (-CH2OH and -NH2) leads to the formation of a more stable film consisting of molecules in the same energy state, butwith poorer insulatingproperties.

scholarly journals Mechanical and Charge Transport Properties of Alkanethiol Self-Assembled Monolayers on a Au(111) Surface:  The Role of Molecular Tilt

Langmuir ◽  
2008 ◽  
Vol 24 (5) ◽  
pp. 2219-2223 ◽  
Author(s):  
Yabing Qi ◽  
Imma Ratera ◽  
Jeong Y. Park ◽  
Paul D. Ashby ◽  
Su Ying Quek ◽  
...  
Keyword(s):  
Charge Transport ◽  
Transport Properties ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

scholarly journals The Rate of Charge Tunneling through Self-Assembled Monolayers Is Insensitive to Many Functional Group Substitutions

2012 ◽  
Vol 124 (19) ◽  
pp. 4736-4739 ◽  
Author(s):  
Hyo Jae Yoon ◽  
Nathan D. Shapiro ◽  
Kyeng Min Park ◽  
Martin M. Thuo ◽  
Siowling Soh ◽  
...  
Keyword(s):  
Functional Group ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Charge Tunneling

Air Oxidation of Self-Assembled Monolayers on Polycrystalline Gold:  The Role of the Gold Substrate

Langmuir ◽  
1998 ◽  
Vol 14 (22) ◽  
pp. 6419-6423 ◽  
Author(s):  
Mong-Tung Lee ◽  
Chen-Chan Hsueh ◽  
Michael S. Freund ◽  
Gregory S. Ferguson
Keyword(s):  
Self Assembled Monolayers ◽  
Gold Substrate ◽  
Air Oxidation ◽  
Assembled Monolayers ◽  
Polycrystalline Gold ◽  
Self Assembled

Modification of Aliphatic Self-Assembled Monolayers by Free-Radical-Dominant Plasma:  The Role of the Plasma Composition

Langmuir ◽  
2004 ◽  
Vol 20 (23) ◽  
pp. 10093-10099 ◽  
Author(s):  
Chih-Chiang Weng ◽  
Jiunn-Der Liao ◽  
Yi-Te Wu ◽  
Ming-Chen Wang ◽  
Ruth Klauser ◽  
...  
Keyword(s):  
Free Radical ◽  
Self Assembled Monolayers ◽  
Plasma Composition ◽  
Assembled Monolayers ◽  
Self Assembled

Molecular gated transistors: Role of self-assembled monolayers

2010 ◽  
Vol 256 (19) ◽  
pp. 5789-5795 ◽  
Author(s):  
O. Shaya ◽  
E. Halpern ◽  
B. Khamaisi ◽  
M. Shaked ◽  
Y. Usherenko ◽  
...  
Keyword(s):  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled
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