Thermal and scanning electron microscopy/energy-dispersive spectroscopy analysis of styrene-butadiene rubber-butadiene rubber/silicon dioxide and styrene-butadiene rubber-butadiene rubber/carbon black-silicon dioxide composites

2005 ◽  
Vol 96 (6) ◽  
pp. 2273-2279 ◽  
Author(s):  
S. A. S. Venter ◽  
M. H. Kunita ◽  
R. Matos ◽  
R. C. Nery ◽  
E. Radovanovic ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Carbon Black ◽  
Silicon Dioxide ◽  
Styrene Butadiene Rubber ◽  
Black Silicon ◽  
Butadiene Rubber ◽  
Spectroscopy Analysis ◽  
Styrene Butadiene ◽  
Scanning Electron

Irradiated rubber composite with nano and micro fillers for mining rock application

2019 ◽  
Vol 107 (8) ◽  
pp. 737-753
Author(s):  
Hanan M. Eyssa ◽  
Wael S. Mohamed ◽  
Mai M. El-Zayat
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Thermal Properties ◽  
Carbon Black ◽  
Field Emission ◽  
Rubber Matrix ◽  
Styrene Butadiene Rubber ◽  
Mechanical And Thermal Properties ◽  
Butadiene Rubber ◽  
Scanning Electron

Abstract In this work, nanosilica and micro carbon black (CB) as a fillers were used to improve the properties of styrene butadiene rubber/natural rubber blends (SBR/NR) crosslinked by γ radiation. Nanosilica was prepared from silica sand and used as eco-friendly material. These composites were characterized by field emission scanning electron microscopy (FESEM) and the measurements of the physic-mechanical and thermal properties were measured. Field emission scanning electron microscopy showed that the composites reinforced by nanosilica and the measurements of the CB are uniformly dispersed in the blends matrix. The results showed that the physico-mechanical and thermal properties were improved indicating a good interaction between the fillers and rubber matrix. The volume fraction measurements confirmed the formation of crosslinking network structure. Meanwhile, the reinforcement of SBR/NR blend loaded with nanosilica showed improved mechanical than blend loaded with both the nanosilica/carbon black and the CB alone. The highest enhancement was obtained for the three fillers by using a concentration of 35 phr at a dose of 150 kGy of γ-irradiation. Thermogravimetric analysis (TGA) indicated that the thermal stability of SBR/NR blend reinforced by nanosilica is higher than those blends reinforced with combined filler the silica. It was also found that the irradiated SBR/NR nanocomposites were more stable than the un-irradiated ones.

scholarly journals Insights into the Payne Effect of Carbon Black Filled Styrene-butadiene Rubber Compounds

2020 ◽  
Vol 39 (1) ◽  
pp. 81-90
Author(s):  
An Zhao ◽  
Xuan-Yu Shi ◽  
Shi-Hao Sun ◽  
Hai-Mo Zhang ◽  
Min Zuo ◽  
...  
Keyword(s):  
Carbon Black ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Payne Effect ◽  
Rubber Compounds ◽  
Styrene Butadiene

STUDY ON NANOMORPHOLOGY OF HIGH-STRUCTURE CARBON BLACK AND ITS BOUND RUBBER BY AFM

2012 ◽  
Vol 19 (01) ◽  
pp. 1250003
Author(s):  
JIAN CHEN ◽  
YONGZHONG JIN ◽  
JINGYU ZHANG ◽  
YAFENG WU ◽  
CHUNCAI MENG
Keyword(s):  
Carbon Black ◽  
Cluster Structure ◽  
Chemical Activity ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Atomic Force ◽  
Filled Rubber ◽  
Bound Rubber ◽  
Styrene Butadiene ◽  
High Structure

Bound rubber in carbon black (CB) filled rubber (natural rubber (NR) and styrene–butadiene rubber (SBS)) was prepared by the solvent method. The nanomorphology of CB and rubber/CB soluble rubber was observed by atomic force microscope. The results show that high-structure CB DZ13 has a "grape cluster" structure which consists of many original particles with the grain size of about 30–50 nm. Graphitizing process of CB decreases the amount of bound rubber. The NR/DZ13 soluble rubber with island–rim structure has been obtained, where the islands are DZ13 particles and the rims around the islands are occupied by NR film. But when the graphitized DZ13 particles were used as fillers of rubber, we have only observed that some graphitized DZ13 particles were deposited on the surface of the globular-like NR molecular chains, instead of the spreading of NR molecular chains along the surface of DZ13 particles, indicating that graphitized DZ13 has lower chemical activity than ungraphitized DZ13. Especially, we have already observed an interesting unusual bound rubber phenomenon, the blocked "bracelet" structure with the diameter of about 600 nm in which CB particles were blocked in ring-shaped SBS monomer.

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