scholarly journals The effect of hygrothermal fatigue on physical/mechanical properties and morphology of neat epoxy resin and graphite/epoxy composite

1985 ◽  
Vol 30 (6) ◽  
pp. 2527-2549 ◽  
Author(s):  
Jovan Mijović ◽  
King-Fu Lin
2021 ◽  
pp. 2150011
Author(s):  
S. G. Thakor ◽  
V. A. Rana ◽  
H. P. Vankar ◽  
T. R. Pandit

This work outlines the characterization of epoxy resin [Bisphenol A-(epichlorhydrin): epoxy] and hardener [[Formula: see text](3-dimethylaminopropyl)-1,3-propylenediamine] with various inorganic nano-fillers. Dielectric characterizations of epoxy, hardener, neat epoxy (epoxy + hardener) and nano-epoxy (nano-filler + neat epoxy) composites loaded with 1 wt.% of inorganic nano-fillers (SiO2, Al2O3, TiO2 and ZnO) were carried out using precision LCR meter, over the frequency range of 1 kHz–2 MHz at a constant temperature of 300.15 K. The structural information of nano-fillers, neat epoxy and nano-epoxy composites was understood by Fourier transform infrared spectroscopy and by XRD. Moreover, hardness and shear strength (shear punch) were also determined in order to gain additional information about the mechanical properties of epoxy composite. Influence of inorganic nano-fillers on the dielectric properties, structural chemistry and mechanical properties of neat epoxy composite is discussed thoroughly in this study.


2020 ◽  
Vol 15 (4) ◽  
Author(s):  
Durgaprasad Kollipara ◽  
Prabhakar Gope VNB ◽  
Raja Loya

Composites have tremendous applicability due to their excellent capabilities. The performance of composites mainly depends on the reinforcing material applied. A Graphene nanoparticle (GNP) is successful as an efficient reinforcing material due to its versatile as well as superior properties. Even at very low content, graphene can dramatically improve the properties of polymer and metal matrix composites. In this paper the effects of GNP on composites based on epoxy resin were analyzed. Different contents of GNP (0 – 4.5 vol. %) were added to the epoxy resin. The GNP/epoxy composite was fabricated under room temperature. Mechanical tests result such as tensile, flexural and hardness test show enhancements of the mechanical properties of the GNP/epoxy composite. The experimental results clearly show an improvement in Young’s modulus, tensile strength, and hardness as compared to pure epoxy. The results of this research are strong evidence for GNP/epoxy composites being a potential candidate for use in a variety of industrial applications, especially for automobile parts, aircraft components, and electronic parts such as super capacitors, transistors, etc.


Author(s):  
Darunee Aussawasathien ◽  
Erol Sancaktar

Electrospun polyacrylonitrile (PAN) fiber precursor based Carbon Nanofiber (CNF) mats were produced and impregnated with epoxy resin. The mechanical properties of as-prepared nanofibers in the mat and short fiber filled epoxy nanocomposite forms were determined to demonstrate the effect of fiber aspect ratio and interconnecting network on those properties. Our experimental results reveal that epoxy nanocomposites containing Electrospun Carbon Nano Fibers (ECNF) with high fiber aspect ratio and high interconnecting network in the non-woven mat form yield better mechanical properties than those filled with short ECNFs. The ECNF mat in epoxy nanocomposites provides better homogeneity, more interlocking network, and easier preparation than short ECNFs. Mechanical properties of ECNF mat-epoxy nanocomposites, which we obtained using tensile and flexural tests, such as stiffness and modulus increased, while toughness and flexural strength decreased, compared to the neat epoxy resin. Dynamic Mechanical Analysis (DMA) results showed, higher modulus for ECNF mat-epoxy nanocomposites, compared to those for neat epoxy resin and short ECNF-epoxy nanocomposites. The epoxy nanocomposites had high modulus, even though the glass transition temperature, Tg values dropped at some extents of ECNF mat contents when compared with the neat epoxy resin. The cure reaction was retarded since the amount of epoxy and hardener decreased at high ECNF contents together with the hindering effect of the ECNF mat to the diffusion of epoxy resin and curing agent, leading to low crosslinking efficiency.


2013 ◽  
Vol 12 (02) ◽  
pp. 1350008 ◽  
Author(s):  
TARIG A. HASSAN ◽  
VIJAYA K. RANGARI ◽  
FREDRIC BAKER ◽  
SHAIK JEELANI

In the present investigation, silicon carbide (β-SiC) nanoparticles (~ 30 nm) were coated on silicon dioxide (SiO2) nanoparticles (~ 200 nm) using sonochemical method. The resultant hybrid nanoparticles were then infused into SC-15 epoxy resin to enhance the thermal and mechanical properties of SC-15 epoxy for structural application. To fabricate an epoxy-based nanocomposite containing SiC/SiO2 hybrid nanoparticles, we have opted a two-step process. In the first step, the silica nanoparticles were coated with SiC nanoparticles using high intensity ultrasonic irradiation. In a second step, 1 wt.% of as-prepared SiC/SiO2 particles were dispersed in epoxy part-A (diglycidylether of bisphenol A) using a high intensity ultrasound for 30 min at 5°C. The part-B (cycloaliphatic amine hardener) of the epoxy was then mixed with part-A- SiC/SiO2 mixture using a high-speed mechanical stirrer for 10 min. The SiC/SiO2 /epoxy resin mixture was cured at room temperature for 24 h. The SiC nanoparticles coating on SiO2 was characterized using X-ray diffraction (XRD) and high resolution transmission electron microscope (TEM). The as-prepared nanocomposite samples were characterized using thermo gravimetric analysis (TGA) and differential scanning calorimeter (DSC). Compression tests have been carried out for both nanocomposite and neat epoxy systems. The results indicated that 1 wt.% (SiC) + (SiO2) loading derived improvements in both thermal and mechanical properties when compared to the neat epoxy system.


2015 ◽  
Vol 761 ◽  
pp. 374-379
Author(s):  
Mohammad Hafizudin ◽  
Taufik Roni Sahroni ◽  
Mohd Razali Muhamad ◽  
Nurul Farah ◽  
M.R. Kamal

This paper presents the mechanical properties of oil palm empty fruit bunch (OPEFB) fiber/epoxy resin reinforced cast LM6 (aluminum based) alloy composites. The metal matrix composite was fabricated by incorporating OPEFB/epoxy resin using mono filaments concept in the as cast LM6 alloys. Three different diameters (10, 12 and 14 mm) of the maximum force of metal matrix composite materials along with controlled sample (cast LM6 alloy + OPEFB/epoxy resin) were determined from three point bend testing. Test results showed that maximum force of mixture between OPEFB fibers composite and cast LM6 alloy for metal matrix composite are higher than that of cast LM6 alloy. Thus the utilization of OPEFB/epoxy composite as mono filaments in metal matrix composite can be significant in improving the strength of the cast LM6 alloy. Beside that increasing the diameter size of OPEFB/epoxy composite will reduce the weight of metal matrix composite (cast LM6 + OPEFB/epoxy composite).


Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2258
Author(s):  
Shiuh-Chuan Her ◽  
Wei-Chun Hsu

Buckypaper consisting of a carbon nanotube (CNT) sheet has a great potential for sensing and structural applications due to the exceptional piezoresistive and mechanical properties of CNTs. In this work, buckypaper was impregnated with the epoxy resin to improve the fragility and handling capability. The mechanical properties of the buckypaper/epoxy composite were determined by the tensile and nanoindentation tests. A thermogravimetric analyzer (TGA) was used to evaluate the thermal stability. Strain and temperature sensing performances of the buckypaper/epoxy composite based on the piezoresistive effect were investigated using a meter source. Experimental results indicated that the elastic modulus and ultimate strength of the buckypaper/epoxy composite were increased by 82% and 194%, respectively, in comparison with the pristine buckypaper, while the strain and temperature sensitivities were decreased by 33% and 0.2%, respectively. A significant increase of the tensile strength accompanied with a moderate decrease of the strain sensitivity demonstrates that the overall performance of buckypaper/epoxy composite is better than that of pristine buckypaper.


2019 ◽  
Vol 962 ◽  
pp. 242-248
Author(s):  
Lim Kar Sing ◽  
Libriati Zardasti ◽  
Norhazilan Md Noor ◽  
Nordin Yahaya

The use of Fibre Reinforced Polymer (FRP) composites together with infill grout has been proven effective for repairing damaged steel pipelines. This paper study the mechanical properties of epoxy grouts where an amount of 0.2% and 0.8% of graphene nanoplatelets particles were added to commercial epoxy resin to evaluate their behaviour regarding neat epoxy resin. Compressive tests, tensile tests and flexural tests were conducted to study the effect of graphene nanoplatelets towards neat epoxy resin. By comparing graphene-modified grouts and neat epoxy grout, there is no increment of strength under compression and tensile test due to poor dispersion of graphene nanoplatelets. Nevertheless, the addition of graphene has produced a noticeable improvement in flexural properties. This signifies that with the inclusion of graphene nanoplatelets, the properties of epoxy grout can be improved if a better dispersion can be achieved.


2018 ◽  
Vol 9 (1) ◽  
pp. 1-22
Author(s):  
C. Karikal Chozhan ◽  
A. Chandramohan ◽  
M. Alagar

The silicon-containing epoxy/clay nanocomposites were developed by incorporating the surface-modified MMT clay upto 7wt% into Si-epoxy resin. The surface of the montmorillonite (MMT) clay was modified with two surface modifiers namely cetyltrimethylammonium bromide (CTAB) and 3-aminopropyltriethoxysilane (γ-APS). The surface modified clay reinforced Si-epoxy composites were developed in the form of castings, and were characterized for their thermal and mechanical properties. Thermal behaviour of the composites was characterized by differential scanning calorimetry (DSC), thermo gravimetric analysis (TGA) and dynamic mechanical analysis (DMA). Mechanical properties were studied as per ASTM standards. Data result from the different studies, it is inferred that the surface modified clay reinforced Si-epoxy composites exhibit lower Tg than that of neat epoxy matrix (127°C <165°C). The decomposition temperature for 60% weight loss of clay reinforced Si-epoxy composites is 674–823°C which is higher when compared to that of neat epoxy matrix. For 5wt% clay reinforced Si-epoxy composites, the values of tensile, flexural and impact strength are increased to 26%, 21% and 29% respectively. The storage modulus (E’) is increased from 5932 to 6308 MPa for clay reinforced Si-epoxy resin. XRD analysis confirmed the well-dispersed exfoliated nanocomposites structure.


2020 ◽  
Vol 3 (2) ◽  
pp. 135-139
Author(s):  
M. Jr. Bratychak ◽  
◽  
P. D. Stukhlyak ◽  
N. V. Chopyk ◽  
V. M. Zemke ◽  
...  

The main physical-mechanical and thermophysical characteristics of composite materials based on epoxy resin ED-20 and peroxide resin ED-20P (modified with tert-butyl hydroperoxide ED-20 of a molecular weight 480) in the ratio of 30 mass parts of ED-20P to 70 mass parts of ED- 20 and unsaturated oligoester TGM-3 were researched. Butyl methacrylate was used as the active diluent of epoxy-oligoester mixtures. The polyethylene polyamine was used as hardener in a steochemical ratio. For the comparison we studied compositions which did not contain ED-20P resin. The advantage of compositions included ED-20P modified resin has been shown.


The effects of micro cellulose reinforcement on the mechanical properties of epoxy composites were investigated. Micro cellulose were extracted from Hibiscuss sabdariffa fibers using the steam explosion technique and repeated chemical treatments. Reinforcing of epoxy resin with micro cellulosic fibers was done in particle form. Tensile, hardness and impact results revealed that mechanical properties of micro cellulose reinforced composites increases for 10%, 20% and 30% fiber loading and then decrease for 40% loading. Composite with 30% of micro cellulose enhanced the overall mechanical properties of composite, due to the enhanced fiber-matrix adhesion and micro cellulose reinforcement.


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