Synthesis, characterization, and thermal properties of phosphorus-containing, wholly aromatic thermotropic copolyesters

2002 ◽  
Vol 86 (5) ◽  
pp. 1278-1284 ◽  
Author(s):  
Yu-Zhang Wang ◽  
Xiao-Ting Chen ◽  
Xu-Dong Tang
Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 127 ◽  
Author(s):  
Yu Sun ◽  
Yazhen Wang ◽  
Li Liu ◽  
Tianyuan Xiao

A 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) acrylate, (6-oxidodibenzo [c,e][1,2] oxaphosphinin-6-yl) methyl acrylate (DOPOAA), has been prepared. Copolymers of styrene (St) and DOPOAA were prepared by emulsion polymerization. The chemical structures of copolymers containing levels of DOPOAA were verified using Fourier transform infrared (FT-IR) spectroscopy and 1H nuclear magnetic resonance (1H-NMR) spectroscopy. The thermal properties and flame-retardant behaviors of DOPO-containing monomers and copolymers were observed using thermogravimetric analysis and micro calorimetry tests. From thermogravimetric analysis (TGA), it was found out that the T5% for decomposition of the copolymer was lower than that of polystyrene (PS), but the residue at 700 °C was higher than that of PS. The results from micro calorimetry (MCC) tests indicated that the rate for the heat release of the copolymer combustion was lower than that for PS. The limiting oxygen index (LOI) for combustion of the copolymer rose with increasing levels of DOPOAA. These data indicate that copolymerization of the phosphorus-containing flame-retardant monomer, DOPOAA, into a PS segment can effectively improve the thermal stability and flame retardancy of the copolymer.


1981 ◽  
Vol 17 (12) ◽  
pp. 1259-1263 ◽  
Author(s):  
Ch. Bechev ◽  
K. Troev ◽  
At. Grozeva ◽  
K. Dimov ◽  
G. Borisov

2011 ◽  
Vol 96 (9) ◽  
pp. 1557-1561 ◽  
Author(s):  
Lian-Lian Wei ◽  
De-Yi Wang ◽  
Hong-Bing Chen ◽  
Li Chen ◽  
Xiu-Li Wang ◽  
...  

Polimery ◽  
2007 ◽  
Vol 52 (11/12) ◽  
pp. 836-840 ◽  
Author(s):  
MENGHUA HOU ◽  
WEIQU LIU ◽  
QIANQIAN SU ◽  
YUNFENG LIU

Author(s):  
Ying-Ling Liu ◽  
Ging-Ho Hsiue ◽  
Chih-Wein Lan ◽  
Jen-Kwan Kuo ◽  
Ru-Jong Jeng ◽  
...  

2003 ◽  
Vol 14 (2) ◽  
pp. 147-156 ◽  
Author(s):  
Ru-Jong Jeng ◽  
Geng-Sheng Lo ◽  
Chih-Ping Chen ◽  
Ying-Ling Liu ◽  
Ging-Ho Hsiue ◽  
...  

2002 ◽  
Vol 83 (13) ◽  
pp. 2741-2748 ◽  
Author(s):  
Kuo-Chung Cheng ◽  
Su-Yun Yu ◽  
Wen-Yen Chiu

Sign in / Sign up

Export Citation Format

Share Document