Thermal properties of side-chain phosphorus-containing epoxide cured with amine

2002 ◽  
Vol 83 (13) ◽  
pp. 2741-2748 ◽  
Author(s):  
Kuo-Chung Cheng ◽  
Su-Yun Yu ◽  
Wen-Yen Chiu
Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 127 ◽  
Author(s):  
Yu Sun ◽  
Yazhen Wang ◽  
Li Liu ◽  
Tianyuan Xiao

A 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) acrylate, (6-oxidodibenzo [c,e][1,2] oxaphosphinin-6-yl) methyl acrylate (DOPOAA), has been prepared. Copolymers of styrene (St) and DOPOAA were prepared by emulsion polymerization. The chemical structures of copolymers containing levels of DOPOAA were verified using Fourier transform infrared (FT-IR) spectroscopy and 1H nuclear magnetic resonance (1H-NMR) spectroscopy. The thermal properties and flame-retardant behaviors of DOPO-containing monomers and copolymers were observed using thermogravimetric analysis and micro calorimetry tests. From thermogravimetric analysis (TGA), it was found out that the T5% for decomposition of the copolymer was lower than that of polystyrene (PS), but the residue at 700 °C was higher than that of PS. The results from micro calorimetry (MCC) tests indicated that the rate for the heat release of the copolymer combustion was lower than that for PS. The limiting oxygen index (LOI) for combustion of the copolymer rose with increasing levels of DOPOAA. These data indicate that copolymerization of the phosphorus-containing flame-retardant monomer, DOPOAA, into a PS segment can effectively improve the thermal stability and flame retardancy of the copolymer.


Steroids ◽  
2006 ◽  
Vol 71 (11-12) ◽  
pp. 949-954 ◽  
Author(s):  
Weiqin Jiang ◽  
George Allan ◽  
Xin Chen ◽  
James J. Fiordeliso ◽  
Olivia Linton ◽  
...  

1981 ◽  
Vol 17 (12) ◽  
pp. 1259-1263 ◽  
Author(s):  
Ch. Bechev ◽  
K. Troev ◽  
At. Grozeva ◽  
K. Dimov ◽  
G. Borisov

2012 ◽  
Vol 70 (1) ◽  
pp. 131-146 ◽  
Author(s):  
Francisco López-Carrasquero ◽  
Elizabeth Rangel-Rangel ◽  
Mayrin Cárdenas ◽  
Carlos Torres ◽  
Nahir Dugarte ◽  
...  

2020 ◽  
Vol 11 (2) ◽  
pp. 517-526 ◽  
Author(s):  
Zhiqiang Cao ◽  
Luke Galuska ◽  
Zhiyuan Qian ◽  
Song Zhang ◽  
Lifeng Huang ◽  
...  

Branching closer to the backbone causes tighter packing in the side-chain direction and lower side chain and backbone dynamics.


2011 ◽  
Vol 96 (9) ◽  
pp. 1557-1561 ◽  
Author(s):  
Lian-Lian Wei ◽  
De-Yi Wang ◽  
Hong-Bing Chen ◽  
Li Chen ◽  
Xiu-Li Wang ◽  
...  

1994 ◽  
Vol 5 (4) ◽  
pp. 203-215 ◽  
Author(s):  
Daniel Taton ◽  
Alain Le Borgne ◽  
Nicolas Spassky ◽  
Claude Friedrich ◽  
Claudine Noël

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