Immobilized palladium nanoparticles on MNPs@A-N -AEB as an efficient catalyst for C-O bond formation in water as a green Solvent

2018 ◽  
Vol 32 (9) ◽  
pp. e4463 ◽  
Author(s):  
Firouz Matloubi Moghaddam ◽  
Mohammad Eslami
Keyword(s):  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Green Solvent ◽  
Efficient Catalyst

scholarly journals Palladium nanoparticles as efficient catalyst for C–S bond formation reactions

RSC Advances ◽  
2020 ◽  
Vol 10 (52) ◽  
pp. 31022-31026 ◽  
Author(s):  
Mei-Na Zhang ◽  
Shahid Khan ◽  
Junjie Zhang ◽  
Ajmal Khan
Keyword(s):  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Cross Coupling ◽  
Cyclic Carbonates ◽  
Efficient Catalyst ◽  
Heterogenous Catalysis ◽  
Bond Formation Reactions

Heterogenous catalysis: economical and sustainable synthesis of allylic sulfone featuring tri- and even tetrasubstituted olefin scaffold via decarboxylative cross-coupling from vinyl cyclic carbonates with sodium sulfinates using PdNPs as a catalyst.

Palladium nanoparticles on amino-modified silica-catalyzed C–C bond formation with carbonyl insertion

2021 ◽  
Author(s):  
Elham Etemadi-Davan ◽  
Dariush Khalili ◽  
Ali Reza Banazadeh ◽  
Ghazal Sadri ◽  
Pourya Arshad
Keyword(s):  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Modified Silica

Self-assembled material of palladium nanoparticles and a thiacalix[4]arene Cd(ii) complex as an efficient catalyst for nitro-phenol reduction

2015 ◽  
Vol 39 (10) ◽  
pp. 8130-8135 ◽  
Author(s):  
Darsi Rambabu ◽  
Chullikkattil P. Pradeep ◽  
Pooja Pooja ◽  
Abhimanew Dhir
Keyword(s):  
Palladium Nanoparticles ◽  
Cadmium Complex ◽  
Efficient Catalyst ◽  
Self Assembled

A cadmium complex based on the thiacalix[4]arene scaffold is utilized to synthesize a material with palladium nanoparticles, which behaves as an efficient catalyst for the conversion of 4-nitrophenol to 4-aminophenol.

scholarly journals Polyethyleneimine-Oleic Acid Micelles-Stabilized Palladium Nanoparticles as Highly Efficient Catalyst to Treat Pollutants with Enhanced Performance

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1890
Author(s):  
Xiang Lai ◽  
Xuan Zhang ◽  
Shukai Li ◽  
Jie Zhang ◽  
Weifeng Lin ◽  
...  
Keyword(s):  
Oleic Acid ◽  
Metal Nanoparticles ◽  
Noble Metal ◽  
Palladium Nanoparticles ◽  
Human Life ◽  
Catalytic Performance ◽  
Water Soluble ◽  
Noble Metal Nanoparticles ◽  
Hydrodynamic Diameter ◽  
Efficient Catalyst

Water soluble organic molecular pollution endangers human life and health. It becomes necessary to develop highly stable noble metal nanoparticles without aggregation in solution to improve their catalytic performance in treating pollution. Polyethyleneimine (PEI)-based stable micelles have the potential to stabilize noble metal nanoparticles due to the positive charge of PEI. In this study, we synthesized the amphiphilic PEI-oleic acid molecule by acylation reaction. Amphiphilic PEI-oleic acid assembled into stable PEI-oleic acid micelles with a hydrodynamic diameter of about 196 nm and a zeta potential of about 34 mV. The PEI-oleic acid micelles-stabilized palladium nanoparticles (PO-PdNPsn) were prepared by the reduction of sodium tetrachloropalladate using NaBH4 and the palladium nanoparticles (PdNPs) were anchored in the hydrophilic layer of the micelles. The prepared PO-PdNPsn had a small size for PdNPs and good stability in solution. Noteworthily, PO-PdNPs150 had the highest catalytic activity in reducing 4-nitrophenol (4-NP) (Knor = 18.53 s−1mM−1) and oxidizing morin (Knor = 143.57 s−1M−1) in aqueous solution than other previous catalysts. The enhanced property was attributed to the improving the stability of PdNPs by PEI-oleic acid micelles. The method described in this report has great potential to prepare many kinds of stable noble metal nanoparticles for treating aqueous pollution.

An easily prepared palladium-hydrogel nanocomposite catalyst for C–C coupling reactions

2014 ◽  
Vol 2 (44) ◽  
pp. 18952-18958 ◽  
Author(s):  
Mitasree Maity ◽  
Uday Maitra
Keyword(s):  
Palladium Nanoparticles ◽  
Room Temperature ◽  
Coupling Reaction ◽  
Coupling Reactions ◽  
Sodium Cyanoborohydride ◽  
Efficient Catalyst ◽  
Suzuki Coupling Reaction ◽  
Reaction In Water ◽  
Hydrogel Nanocomposite

Palladium nanoparticles were efficiently prepared in situ by sodium cyanoborohydride reduction of Pd(ii) at room temperature using calcium-cholate hydrogel fibers as templates. The PdNPs self-organize on the gel fibers, which supports the controlled growth as well as stabilization of PdNPs. The hybrid xerogel was used as an efficient catalyst for the Suzuki coupling reaction in water.

Palladium chloride catalyzed photochemical Heck reaction

2013 ◽  
Vol 91 (5) ◽  
pp. 348-351 ◽  
Author(s):  
Suresh B. Waghmode ◽  
Sudhir S. Arbuj ◽  
Bina N. Wani ◽  
C.S. Gopinath
Keyword(s):  
Visible Light ◽  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Aryl Halides ◽  
Palladium Chloride ◽  
Carbon Bond ◽  
Excellent Yield ◽  
Carbon Carbon Bond ◽  
Uv Visible

PdCl2 catalyzed carbon–carbon bond formation (Heck reaction) between substituted aryl halides and olefins was carried out without a ligand, under irradiation with UV–visible light. The results demonstrated that UV–visible light accelerated the rate of the reaction, leading to an excellent yield of corresponding products. The recovered palladium nanoparticles could be thermally recycled several times. PdCl2 gave excellent conversion up to the fifth addition of substrate.

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