scholarly journals Palladium nanoparticles as efficient catalyst for C–S bond formation reactions

RSC Advances ◽  
2020 ◽  
Vol 10 (52) ◽  
pp. 31022-31026 ◽  
Author(s):  
Mei-Na Zhang ◽  
Shahid Khan ◽  
Junjie Zhang ◽  
Ajmal Khan
Keyword(s):  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Cross Coupling ◽  
Cyclic Carbonates ◽  
Efficient Catalyst ◽  
Heterogenous Catalysis ◽  
Bond Formation Reactions

Heterogenous catalysis: economical and sustainable synthesis of allylic sulfone featuring tri- and even tetrasubstituted olefin scaffold via decarboxylative cross-coupling from vinyl cyclic carbonates with sodium sulfinates using PdNPs as a catalyst.

ChemInform Abstract: PVC-Supported Palladium Nanoparticles: An Efficient Catalyst for Suzuki Cross-Coupling Reactions at Room Temperature.

ChemInform ◽  
2013 ◽  
Vol 44 (33) ◽  
pp. no-no ◽  
Author(s):  
Mamidi Samarasimhareddy ◽  
Girish Prabhu ◽  
Thimmalapura M. Vishwanatha ◽  
Vommina V. Sureshbabu
Keyword(s):  
Palladium Nanoparticles ◽  
Room Temperature ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Efficient Catalyst ◽  
Cross Coupling Reactions ◽  
Supported Palladium

ESP-Promoted Suzuki-Miyaura Cross-Coupling and Peptide Bond Formation Reactions in Water at Room Temperature

2017 ◽  
Vol 2 (18) ◽  
pp. 4983-4987 ◽  
Author(s):  
Manashjyoti Konwar ◽  
Preeti Rekha Boruah ◽  
Prakash J. Saikia ◽  
Nageshewar D. Khupse ◽  
Diganta Sarma
Keyword(s):  
Room Temperature ◽  
Bond Formation ◽  
Cross Coupling ◽  
Peptide Bond ◽  
Peptide Bond Formation ◽  
Bond Formation Reactions

Design and synthesis of a new phosphinite-functionalized clay composite for the stabilization of palladium nanoparticles. Application as a recoverable catalyst for C–C bond formation reactions

RSC Advances ◽  
2014 ◽  
Vol 4 (53) ◽  
pp. 27674-27682 ◽  
Author(s):  
Habib Firouzabadi ◽  
Nasser Iranpoor ◽  
Arash Ghaderi ◽  
Mohammad Gholinejad ◽  
Sajjad Rahimi ◽  
...  
Keyword(s):  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Design And Synthesis ◽  
Recoverable Catalyst ◽  
Bond Formation Reactions

Pd-catalyzed C–C bond formation in green media, combining the advantages of homogeneous IL phase, phosphorylated ligands and a new heterogeneous clay support.

scholarly journals Synthesis and Reactivity of (N2P2)Ni Complexes Stabilized by a Novel Diphosphonite Pyridinophane Ligand

2021 ◽  
Author(s):  
Kei Fuchigami ◽  
Michael B. Watson ◽  
Giang N. Tran ◽  
Nigam P. Rath ◽  
Liviu M. Mirica
Keyword(s):  
Photoelectron Spectroscopy ◽  
Aryl Halide ◽  
Bond Formation ◽  
Cross Coupling ◽  
Electrochemical Studies ◽  
Redox Potentials ◽  
Efficient Catalyst ◽  
X Ray ◽  
Ni Species

A series of (N2P2)Ni<sup>II</sup> complexes (N2P2 = P,P’-ditertbutyl-2,11-diphosphonito[3.3](2,6)pyridinophane) stabilized by a modified tetradentate pyridinophane ligand containing two phosphonite groups were synthesized and characterized. Cyclic voltammetry (CV) studies revealed the accessibility of the Ni<sup>I</sup> oxidation state at moderate redox potentials for these Ni<sup>II</sup> complexes. <i>In situ</i> EPR, low-temperature UV-vis, and electrochemical studies were employed to detect the formation of Ni<sup>I</sup> species during the reduction of Ni<sup>II</sup> precursors. Furthermore, the [(N2P2)Ni<sup>I</sup>(CNtBu)](SbF<sub>6</sub>) complex was isolated upon reduction of the Ni<sup>II</sup> precursor with 1 equiv of CoCp<sub>2</sub>, and was characterized by EPR and X-ray photoelectron spectroscopy (XPS). Finally, the (N2P2)Ni<sup>II</sup>Br<sub>2</sub> complex acts as an efficient catalyst for the Kumada cross-coupling of an aryl halide with an aryl or alkyl Grignard, suggesting that the N2P2 ligand can support the various Ni species involved in the catalytic C-C bond formation reactivity.

Palladium nanoparticles supported on agarose-functionalized magnetic nanoparticles of Fe3O4 as a recyclable catalyst for C–C bond formation via Suzuki–Miyaura, Heck–Mizoroki and Sonogashira–Hagihara coupling reactions

RSC Advances ◽  
2014 ◽  
Vol 4 (33) ◽  
pp. 17060-17070 ◽  
Author(s):  
Habib Firouzabadi ◽  
Nasser Iranpoor ◽  
Mohammad Gholinejad ◽  
Samira Akbari ◽  
Neda Jeddi
Keyword(s):  
Magnetic Nanoparticles ◽  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Recyclable Catalyst ◽  
Coupling Reactions ◽  
Functionalized Magnetic Nanoparticles ◽  
Bond Formation Reactions

Palladium nanoparticles supported on agarose functionalized Fe3O4 catalyzed C–C bond formation reactions.

scholarly journals Microwave-assisted synthesis of palladium nanoparticles supported on copper oxide in aqueous medium as an efficient catalyst for Suzuki cross-coupling reaction

2018 ◽  
Vol 36 (5-6) ◽  
pp. 1352-1365 ◽  
Author(s):  
Hany A Elazab ◽  
M.A. Sadek ◽  
Tamer T El-Idreesy
Keyword(s):  
Catalytic Activity ◽  
Copper Oxide ◽  
Palladium Nanoparticles ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Microwave Assisted Synthesis ◽  
Synthetic Approach ◽  
Efficient Catalyst ◽  
Microwave Assisted ◽  
Cross Coupling Reaction

We report here a reliable green method for the synthesis of palladium nanoparticles supported on copper oxide as a highly active and efficient catalyst for Suzuki cross-coupling reaction. The experimental synthetic approach is based on microwave-assisted chemical reduction of an aqueous mixture of palladium and copper salt simultaneously using hydrazine hydrate as reducing agent. The catalyst was fully characterized using various techniques showing well-dispersed palladium nanoparticles. The catalytic activity and recyclability of the prepared catalyst were experimentally explored in the ligand-free Suzuki cross-coupling reaction with a diverse series of functionalized substrates. The synthesized Pd/CuO catalyst shows many advantages beside its high catalytic efficiency such as the recyclability of up to five times with negligible loss of catalytic activity, short reaction times, use of environmentally benign solvent systems, and mild reaction conditions.

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