Alkene Difunctionalization Triggered by a Stabilized Allenyl Radical: Elusively Concomitant Installation of Two Unsaturated C‐C Bonds

2021 ◽  
Author(s):  
Yunlong Wei ◽  
Hong Zhang ◽  
Xinxin Wu ◽  
Chen Zhu
Keyword(s):  
Alkene Difunctionalization

ChemInform Abstract: Rhodium-Catalyzed Alkene Difunctionalization with Nitrenes.

ChemInform ◽  
2016 ◽  
Vol 47 (46) ◽  
Author(s):  
Jennifer Ciesielski ◽  
Geoffroy Dequirez ◽  
Pascal Retailleau ◽  
Vincent Gandon ◽  
Philippe Dauban
Keyword(s):  
Alkene Difunctionalization

Synthesis of γ-Amino Esters by Copper-Catalyzed Intermolecular 1,2-Aminoalkylation of Alkenes with Amines and α-Bromoalkyl Esters

Synthesis ◽  
2018 ◽  
Vol 50 (08) ◽  
pp. 1651-1660 ◽  
Author(s):  
Ren-Jie Song ◽  
Jin-Heng Li ◽  
Gao-Hui Pan ◽  
Ye-Xiang Xie ◽  
Shenglian Luo
Keyword(s):  
Catalytic System ◽  
Chemical Bonds ◽  
Amino Esters ◽  
Three Component Reaction ◽  
Single Reaction ◽  
Alkene Difunctionalization

A new copper-catalyzed intermolecular 1,2-aminoalkylation of alkenes with α-bromoalkyl esters and amines for the synthesis of γ-amino esters is described. Employing the Cu(OTf)2 and 2,2′-bipyridine catalytic system, the three-component reaction allows the formation of two new chemical bonds, including one C–C bond and one C–N bond, in a single reaction, and represents a new alkene difunctionalization using a radical strategy.

scholarly journals Intermolecular Alkene Difunctionalization via Gold‐Catalyzed Oxyarylation

2020 ◽  
Vol 59 (46) ◽  
pp. 20470-20474 ◽  
Author(s):  
Shuyao Zhang ◽  
Chenhuan Wang ◽  
Xiaohan Ye ◽  
Xiaodong Shi
Keyword(s):  
Alkene Difunctionalization

scholarly journals Use of Aryl Chlorides as Electrophiles in Pd-Catalyzed Alkene Difunctionalization Reactions

2010 ◽  
Vol 75 (8) ◽  
pp. 2756-2759 ◽  
Author(s):  
Brandon R. Rosen ◽  
Joshua E. Ney ◽  
John P. Wolfe
Keyword(s):  
Aryl Chlorides ◽  
Alkene Difunctionalization
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