Visible‐Light‐Enabled Stereodivergent Synthesis of E ‐ and Z ‐Configured 1,4‐Dienes by Photoredox/Nickel Dual Catalysis

2019 ◽  
Vol 59 (1) ◽  
pp. 177-181 ◽  
Author(s):  
Fan Song ◽  
Fang Wang ◽  
Lei Guo ◽  
Xiaoliang Feng ◽  
Yanyan Zhang ◽  
...  
Keyword(s):  
Visible Light ◽  
Dual Catalysis

Accessing Aliphatic Amines in C–C Cross-Couplings by Visible Light/Nickel Dual Catalysis

2021 ◽  
Author(s):  
Weizhe Dong ◽  
Shorouk O. Badir ◽  
Xuange Zhang ◽  
Gary A. Molander
Keyword(s):  
Visible Light ◽  
Aliphatic Amines ◽  
Dual Catalysis

Photoredox/Cobalt Dual Catalysis for Visible-Light-Mediated Alkene–Alkyne Coupling

2019 ◽  
Vol 21 (10) ◽  
pp. 3755-3759 ◽  
Author(s):  
Pramod Rai ◽  
Kakoli Maji ◽  
Biplab Maji
Keyword(s):  
Visible Light ◽  
Dual Catalysis ◽  
Alkyne Coupling

scholarly journals Photoredox mediated nickel catalyzed C(sp3)–H thiocarbonylation of ethers

2017 ◽  
Vol 8 (9) ◽  
pp. 6613-6618 ◽  
Author(s):  
Byungjoon Kang ◽  
Soon Hyeok Hong
Keyword(s):  
Visible Light ◽  
Dual Catalysis

The first C(sp3)–H thiocarbonylation is achieved by visible light photoredox/Ni dual catalysis using thiobenzoates as the thioester group source.

Visible-Light-Driven Alkyne Hydro-/Carbocarboxylation Using CO2 via Iridium/Cobalt Dual Catalysis for Divergent Heterocycle Synthesis

2018 ◽  
Vol 140 (15) ◽  
pp. 5257-5263 ◽  
Author(s):  
Jing Hou ◽  
Aloysius Ee ◽  
Wei Feng ◽  
Jin-Hui Xu ◽  
Yu Zhao ◽  
...  
Keyword(s):  
Visible Light ◽  
Heterocycle Synthesis ◽  
Visible Light Driven ◽  
Dual Catalysis

scholarly journals Visible-Light Photoredox and Palladium Dual Catalysis in Organic Synthesis

2020 ◽  
Vol 40 (11) ◽  
pp. 3697
Author(s):  
Wenjun Zhou ◽  
Yuanxu Jiang ◽  
Liang Chen ◽  
Kaixing Liu ◽  
Dagang Yu
Keyword(s):  
Visible Light ◽  
Organic Synthesis ◽  
Dual Catalysis

scholarly journals Relay Dual Catalysis: Photoredox and NHC-Catalyzed Cross-Double C-H Functionalizations of Aldehydes and Alkenes

2021 ◽  
Author(s):  
MIng-Shang Liu ◽  
Lin Min ◽  
Bi-Hong Chen ◽  
Wei Shu
Keyword(s):  
Visible Light ◽  
Electron Acceptor ◽  
Direct Coupling ◽  
Coupling Mechanism ◽  
Forming Process ◽  
Radical Coupling ◽  
Dehydrogenative Coupling ◽  
Dual Catalysis

Direct functionalizations of two distinct inert C-H bonds represent the most ideal ways to construct C-C bonds. Herein, we report an intermolecular vinylation of aldehydes using alkenes as the vinylating reagents through sequential two-fold C-H functionalizations. The merging of visible light and NHC-catalysis allows for the direct coupling of alkenes with aldehydes through an unprecedented relay dual catalysis enabled cross-dehydrogenative coupling mechanism. The use of diphenoquinone is essential for the success of this reaction, which plays an intriguing two-fold role in the reaction, as both an electron acceptor as well as a radical reservoir for the radical coupling enabling C-C forming-process.

Synthesis of unsymmetrical ketones by applying visible-light benzophenone/nickel dual catalysis for direct benzylic acylation

2020 ◽  
Vol 56 (45) ◽  
pp. 6082-6085 ◽  
Author(s):  
Patricia E. Krach ◽  
Abhishek Dewanji ◽  
Tingting Yuan ◽  
Magnus Rueping
Keyword(s):  
Visible Light ◽  
Acid Chlorides ◽  
Robust Method ◽  
Photochemical Reactivity ◽  
Dual Catalysis

The photochemical reactivity of benzophenone is utilized for direct benzylic C–H bond acylation of methylbenzenes via H-atom abstraction as a key step. The reaction offers a robust method for synthesizing ketones using acid chlorides and anhydrides.

scholarly journals Visible-light-driven spirocyclization of epoxides via dual titanocene and photoredox catalysis

2020 ◽  
Vol 11 (3) ◽  
pp. 839-844 ◽  
Author(s):  
Shuangjie Lin ◽  
Yuqing Chen ◽  
Fusheng Li ◽  
Caizhe Shi ◽  
Lei Shi
Keyword(s):  
Visible Light ◽  
Photoredox Catalysis ◽  
Visible Light Driven ◽  
Dual Catalysis

We describe the synergistic utilization of titanocene/photoredox dual catalysis driven by visible light for radical opening/spirocyclization of easily accessible epoxyalkynes.

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