scholarly journals Controlled and Reversible Stepwise Growth of Linear Copper(I) Chains Enabled by Dynamic Ligand Scaffolds

2017 ◽  
Vol 56 (51) ◽  
pp. 16267-16271 ◽  
Author(s):  
Orestes Rivada-Wheelaghan ◽  
Sandra L. Aristizábal ◽  
Joaquín López-Serrano ◽  
Robert R. Fayzullin ◽  
Julia R. Khusnutdinova
Keyword(s):  
Ligand Scaffolds

1,3-Dioxoindan-2-carboxamides as Bioactive Ligand Scaffolds for the Development of Novel Organometallic Anticancer Drugs

2015 ◽  
Vol 34 (5) ◽  
pp. 848-857 ◽  
Author(s):  
Stephan Mokesch ◽  
Maria S. Novak ◽  
Alexander Roller ◽  
Michael A. Jakupec ◽  
Wolfgang Kandioller ◽  
...  
Keyword(s):  
Anticancer Drugs ◽  
Ligand Scaffolds ◽  
Bioactive Ligand

Highly versatile heteroditopic ligand scaffolds for accommodating group 8, 9 & 11 heterobimetallic complexes

2017 ◽  
Vol 46 (41) ◽  
pp. 14406-14419 ◽  
Author(s):  
Mark R. D. Gatus ◽  
Mohan Bhadbhade ◽  
Barbara A. Messerle
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Transition Metal Ions ◽  
Heterobimetallic Complexes ◽  
Ligand Scaffolds

Two highly versatile xanthene scaffolds containing pairs of heteroditopic ligands were found to be capable of accommodating a range of transition metal ions, including Au(i), Ir(i), Ir(iii), Rh(i), and Ru(ii) to generate an array of heterobimetallic complexes.

Supramolecular bidentate phosphine ligand scaffolds from deconstructed Hamilton receptors

2017 ◽  
Vol 53 (3) ◽  
pp. 561-564 ◽  
Author(s):  
Daniel T. Seidenkranz ◽  
Jacqueline M. McGrath ◽  
Lev N. Zakharov ◽  
Michael D. Pluth
Keyword(s):  
Self Assembly ◽  
Phosphine Ligand ◽  
Bidentate Phosphine ◽  
Ligand Scaffolds ◽  
Bidentate Phosphine Ligand

The metal-assisted self-assembly of a phosphine-modified, deconstructed Hamilton receptor is reported as a new supramolecular ligand scaffold.

scholarly journals Front Cover: Bond Activations Assisted by Redox Active Ligand Scaffolds (Eur. J. Inorg. Chem. 13/2020)

2020 ◽  
Vol 2020 (13) ◽  
pp. 1135-1135
Author(s):  
Farheen Fatima Khan ◽  
Abhishek Dutta Chowdhury ◽  
Goutam Kumar Lahiri
Keyword(s):  
Front Cover ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active ◽  
Ligand Scaffolds ◽  
Bond Activations

Bond Activations Assisted by Redox Active Ligand Scaffolds

2020 ◽  
Vol 2020 (13) ◽  
pp. 1136-1136 ◽  
Author(s):  
Farheen Fatima Khan ◽  
Abhishek Dutta Chowdhury ◽  
Goutam Kumar Lahiri
Keyword(s):  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active ◽  
Ligand Scaffolds ◽  
Bond Activations

A Nano-Scale Barrel and Cube:  Transition Metal-Mediated Self-Assembly of CpCoCb-Derived Ligand Scaffolds

2001 ◽  
Vol 123 (16) ◽  
pp. 3818-3819 ◽  
Author(s):  
Sarah C. Johannessen ◽  
Ronald G. Brisbois ◽  
John P. Fischer ◽  
Paul A. Grieco ◽  
Anne E. Counterman ◽  
...  
Keyword(s):  
Transition Metal ◽  
Self Assembly ◽  
Nano Scale ◽  
Ligand Scaffolds

3d Element Complexes of Pentadentate Bipyridine-Pyridine-Based Ligand Scaffolds: Structures and Photocatalytic Activities

2013 ◽  
Vol 52 (10) ◽  
pp. 6055-6061 ◽  
Author(s):  
Cyril Bachmann ◽  
Miguel Guttentag ◽  
Bernhard Spingler ◽  
Roger Alberto
Keyword(s):  
Photocatalytic Activities ◽  
Ligand Scaffolds

Taming Nitrene Reactivity with Silver Catalysts

Synlett ◽  
2020 ◽  
Vol 32 (01) ◽  
pp. 30-44
Author(s):  
Jennifer M. Schomaker ◽  
Logan E. Vine ◽  
Emily E. Zerull
Keyword(s):  
Noncovalent Interactions ◽  
Coordination Environment ◽  
Nitrene Transfer ◽  
Silver Catalysts ◽  
Stereoselective Reactions ◽  
Ligand Scaffolds ◽  
Site Selective ◽  
Unique Ability

Nitrene transfer (NT) is a convenient strategy to directly transform C–H bonds into more valuable C–N bonds and exciting advances have been made to improve selectivity. Our work in silver-based NT has shown the unique ability of this metal to enable tunable chemo-, site-, and stereoselective reactions using simple N-dentate ligand scaffolds. Manipulation of the coordination environment and noncovalent interactions around the silver center furnish unprecedented catalyst control in selective NT and provide insights for further improvements in the field.1 Introduction1.1 Strategies for Nitrene Transfer1.2 Brief Summary of Chemocatalyzed Nitrene Transfer1.3 Focus of this Account2 Challenges in Chemocatalyzed Nitrene Transfer2.1 Reactivity Challenges2.2 Selectivity Challenges2.3 Chemoselective Nitrene Transfer2.4 Site-Selective Nitrene Transfer2.5 Enantioselective Nitrene Transfer3 Summary and Perspective3.1 Future Opportunities and Challenges3.2 Conclusion

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