Catalytically Active Rh Sub-Nanoclusters on TiO2 for CO Oxidation at Cryogenic Temperatures

2016 ◽  
Vol 55 (8) ◽  
pp. 2820-2824 ◽  
Author(s):  
Hongling Guan ◽  
Jian Lin ◽  
Botao Qiao ◽  
Xiaofeng Yang ◽  
Lin Li ◽  
...  
2016 ◽  
Vol 128 (8) ◽  
pp. 2870-2874 ◽  
Author(s):  
Hongling Guan ◽  
Jian Lin ◽  
Botao Qiao ◽  
Xiaofeng Yang ◽  
Lin Li ◽  
...  

2016 ◽  
Vol 55 (8) ◽  
pp. 2946-2946
Author(s):  
Hongling Guan ◽  
Jian Lin ◽  
Botao Qiao ◽  
Xiaofeng Yang ◽  
Lin Li ◽  
...  

2016 ◽  
Vol 128 (8) ◽  
pp. 2998-2998
Author(s):  
Hongling Guan ◽  
Jian Lin ◽  
Botao Qiao ◽  
Xiaofeng Yang ◽  
Lin Li ◽  
...  

2019 ◽  
Vol 150 (3) ◽  
pp. 605-612 ◽  
Author(s):  
Y. Suchorski ◽  
I. Bespalov ◽  
J. Zeininger ◽  
M. Raab ◽  
M. Datler ◽  
...  

Abstract The catalytic CO oxidation reaction on stepped Rh surfaces in the 10−6 mbar pressure range was studied in situ on individual μm-sized high-Miller-index domains of a polycrystalline Rh foil and on nm-sized facets of a Rh tip, employing photoemission electron microscopy (PEEM) and field-ion/field-emission microscopy (FIM/FEM), respectively. Such approach permits a direct comparison of the reaction kinetics for crystallographically different regions under identical reaction conditions. The catalytic activity of the different Rh surfaces, particularly their tolerance towards poisoning by CO, was found to be strongly dependent on the density of steps and defects, as well as on the size (µm vs. nm) of the respective catalytically active surface. Graphic Abstract


2016 ◽  
Vol 260 ◽  
pp. 14-20 ◽  
Author(s):  
Hiroshi Kondoh ◽  
Ryo Toyoshima ◽  
Yuji Monya ◽  
Masaaki Yoshida ◽  
Kazuhiko Mase ◽  
...  

2002 ◽  
Vol 4 (10) ◽  
pp. 1707-1709 ◽  
Author(s):  
Jan Hagen ◽  
Liana D. Socaciu ◽  
Maryam Elijazyfer ◽  
Ueli Heiz ◽  
Thorsten M. Bernhardt ◽  
...  

2021 ◽  
Author(s):  
Zhiming Li ◽  
Xinyu Zhang ◽  
Quanquan Shi ◽  
Xia Gong ◽  
Hui Xu ◽  
...  

Interfacial perimeter is generally viewed as the catalytically active sites for a number of chemical reactions over the oxide-supported nanogold catalysts. Here, the well-defined CeO2 of nanocube, nanorod and nanopolyhedra...


2018 ◽  
Vol 917 ◽  
pp. 152-156
Author(s):  
Elena Krivoshapkina ◽  
Pavel Krivoshapkin ◽  
Aleksey Vedyagin

In present work, a new technique to prepare alumina nanoparticles and nanofibers using a sol-gel method was proposed. A solution combustion method was applied to form a nanostructured catalytically active layer of CuO–Co3O4–CeO2 on the surface of the alumina. The uniform distribution and fine dispersion of active components provide the appropriate activity of the catalysts obtained in a model reaction of CO oxidation. The morphology of nanostructured alumina was found to affect the catalytic behavior. Carbon monoxide conversion was observed at lower temperatures when alumina nanofibers were used as a catalyst support.


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