Palladium-Catalyzed Allylic Alkylation of Simple Ketones with Allylic Alcohols and Its Mechanistic Study

2014 ◽  
Vol 53 (26) ◽  
pp. 6776-6780 ◽  
Author(s):  
Xiaohong Huo ◽  
Guoqiang Yang ◽  
Delong Liu ◽  
Yangang Liu ◽  
Ilya D. Gridnev ◽  
...  
Keyword(s):  
Mechanistic Study ◽  
Allylic Alcohols ◽  
Allylic Alkylation ◽  
Palladium Catalyzed

Palladium-Catalyzed Allylic Alkylation of Simple Ketones with Allylic Alcohols and Its Mechanistic Study

2014 ◽  
Vol 126 (26) ◽  
pp. 6894-6898 ◽  
Author(s):  
Xiaohong Huo ◽  
Guoqiang Yang ◽  
Delong Liu ◽  
Yangang Liu ◽  
Ilya D. Gridnev ◽  
...  
Keyword(s):  
Mechanistic Study ◽  
Allylic Alcohols ◽  
Allylic Alkylation ◽  
Palladium Catalyzed

ChemInform Abstract: Palladium-Catalyzed Allylic Alkylation of Simple Ketones with Allylic Alcohols and Its Mechanistic Study.

ChemInform ◽  
2015 ◽  
Vol 46 (1) ◽  
Author(s):  
Xiaohong Huo ◽  
Guoqiang Yang ◽  
Delong Liu ◽  
Yangang Liu ◽  
Ilya D. Gridnev ◽  
...  
Keyword(s):  
Mechanistic Study ◽  
Allylic Alcohols ◽  
Allylic Alkylation ◽  
Palladium Catalyzed

Palladium catalyzed direct allylation of azlactones with simple allylic alcohols in the absence of any activators

RSC Advances ◽  
2014 ◽  
Vol 4 (49) ◽  
pp. 25596-25599 ◽  
Author(s):  
Hui Zhou ◽  
Huameng Yang ◽  
Hongyu Yin ◽  
Muwen Liu ◽  
Chungu Xia ◽  
...  
Keyword(s):  
Allylic Alcohols ◽  
Allylic Alkylation ◽  
Palladium Catalyzed ◽  
Neutral Conditions

The first example of the readily scalable direct allylic alkylation of azlactones with simple allylic alcohols has been developed, which is catalyzed by Pd(PPh3)4 alone in the absence of any activators under neutral conditions.

A mechanistic study on multifunctional Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions

RSC Advances ◽  
2016 ◽  
Vol 6 (74) ◽  
pp. 70624-70631 ◽  
Author(s):  
Jian-Xing Xu ◽  
Fei Ye ◽  
Xing-Feng Bai ◽  
Yu-Ming Cui ◽  
Zheng Xu ◽  
...  
Keyword(s):  
Mechanistic Study ◽  
Allylic Alkylation ◽  
Allylic Substitution ◽  
Mechanistic Studies ◽  
Substitution Reactions ◽  
Asymmetric Allylic Alkylation ◽  
Allylic Substitutions ◽  
Palladium Catalyzed ◽  
Catalytic Asymmetric

Mechanistic studies were performed for the clarification of the role of multifunctional Fei-Phos in allylic substitution reactions, in which it is proved to be a diphosphine-controlled catalytic asymmetric allylic alkylation.

Novel Chiral Ligands for Palladium-catalyzed Asymmetric Allylic Alkylation/ Asymmetric Tsuji-Trost Reaction: A Review

2019 ◽  
Vol 23 (11) ◽  
pp. 1168-1213 ◽  
Author(s):  
Samar Noreen ◽  
Ameer Fawad Zahoor ◽  
Sajjad Ahmad ◽  
Irum Shahzadi ◽  
Ali Irfan ◽  
...  
Keyword(s):  
Asymmetric Catalysis ◽  
Enantioselective Synthesis ◽  
Chiral Ligands ◽  
Allylic Alkylation ◽  
Research Groups ◽  
Asymmetric Allylic Alkylation ◽  
Catalytic Potential ◽  
Long Time ◽  
Palladium Catalyzed ◽  
Alkylation Reactions

Background: Asymmetric catalysis holds a prestigious role in organic syntheses since a long time and chiral inductors such as ligands have been used to achieve the utmost desired results at this pitch. The asymmetric version of Tsuji-Trost allylation has played a crucial role in enantioselective synthesis. Various chiral ligands have been known for Pdcatalyzed Asymmetric Allylic Alkylation (AAA) reactions and exhibited excellent catalytic potential. The use of chiral ligands as asymmetric inductors has widened the scope of Tsuji-Trost allylic alkylation reactions. Conclusion: Therefore, in this review article, a variety of chiral inductors or ligands have been focused for palladium catalyzed asymmetric allylic alkylation (Tsuji-Trost allylation) and in this regard, recently reported literature (2013-2017) has been described. The use of ligands causes the induction of enantiodiscrimination to the allylated products, therefore, the syntheses of various kinds of ligands have been targeted by many research groups to employ in Pd-catalyzed AAA reactions.

Direct and Selective Synthesis of Adipic and Other Dicarboxylic Acids by Palladium‐Catalyzed Carbonylation of Allylic Alcohols

2020 ◽  
Vol 59 (46) ◽  
pp. 20394-20398
Author(s):  
Ji Yang ◽  
Jiawang Liu ◽  
Yao Ge ◽  
Weiheng Huang ◽  
Helfried Neumann ◽  
...  
Keyword(s):  
Dicarboxylic Acids ◽  
Allylic Alcohols ◽  
Selective Synthesis ◽  
Palladium Catalyzed

Palladium-catalyzed decarboxylative allylic alkylation of allylic acetates with .beta.-keto acids

1986 ◽  
Vol 51 (4) ◽  
pp. 421-426 ◽  
Author(s):  
Tetsuo Tsuda ◽  
Masahiro Okada ◽  
Seiichi Nishi ◽  
Takeo Saegusa
Keyword(s):  
Allylic Alkylation ◽  
Keto Acids ◽  
Palladium Catalyzed
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