Self-Assembly of Nanometer-Scale [Cu24I10L12]14+ Cages and Ball-Shaped Keggin Clusters into a (4,12)-Connected 3D Framework with Photoluminescent and Electrochemical Properties

2006 ◽  
Vol 45 (44) ◽  
pp. 7411-7414 ◽  
Author(s):  
Xin-Long Wang ◽  
Chao Qin ◽  
En-Bo Wang ◽  
Zhong-Min Su ◽  
Yang-Guang Li ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Self Assembly ◽  
Nanometer Scale ◽  
3D Framework

scholarly journals Electrochemical Properties of Lipid Membranes Self-Assembled from Bicelles

Membranes ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 11
Author(s):  
Damian Dziubak ◽  
Kamil Strzelak ◽  
Slawomir Sek
Keyword(s):  
Electrochemical Properties ◽  
Self Assembly ◽  
Lipid Membranes ◽  
Lipid Membrane ◽  
Membrane Resistance ◽  
Electrochemical Characteristics ◽  
Freeze Thaw ◽  
Lipid Films ◽  
Supported Lipid Membranes

Supported lipid membranes are widely used platforms which serve as simplified models of cell membranes. Among numerous methods used for preparation of planar lipid films, self-assembly of bicelles appears to be promising strategy. Therefore, in this paper we have examined the mechanism of formation and the electrochemical properties of lipid films deposited onto thioglucose-modified gold electrodes from bicellar mixtures. It was found that adsorption of the bicelles occurs by replacement of interfacial water and it leads to formation of a double bilayer structure on the electrode surface. The resulting lipid assembly contains numerous defects and pinholes which affect the permeability of the membrane for ions and water. Significant improvement in morphology and electrochemical characteristics is achieved upon freeze–thaw treatment of the deposited membrane. The lipid assembly is rearranged to single bilayer configuration with locally occurring patches of the second bilayer, and the number of pinholes is substantially decreased. Electrochemical characterization of the lipid membrane after freeze–thaw treatment demonstrated that its permeability for ions and water is significantly reduced, which was manifested by the relatively high value of the membrane resistance.

Synthesis, Characterization, Investigation of Capacitance and Redox Properties of Self-assembled Phe-Phe with Ferrocene Conjugates

2021 ◽  
Author(s):  
Om Shanker Tiwari
Keyword(s):  
Nucleic Acid ◽  
Electrochemical Properties ◽  
Self Assembly ◽  
Peptide Nucleic Acid ◽  
Redox Properties ◽  
Self Assembled ◽  
Acid Unit

The synthesis, nanostructure self-assembly and electrochemical properties of a series of ferrocene conjugated peptides derived from the dipeptide Phe-Phe, nucleoside and the peptide nucleic acid unit which are covalently attached...

Directed Self-Assembly of Silica Nanoparticles into Nanometer-Scale Patterned Surfaces Using Spin-Coating

2004 ◽  
Vol 16 (16) ◽  
pp. 1427-1432 ◽  
Author(s):  
D. Xia ◽  
A. Biswas ◽  
D. Li ◽  
S. R. J. Brueck
Keyword(s):  
Silica Nanoparticles ◽  
Self Assembly ◽  
Spin Coating ◽  
Nanometer Scale ◽  
Patterned Surfaces

Trithiazolyl-1,3,5-triazines bearing decyloxybenzene moieties: synthesis, photophysical and electrochemical properties, and self-assembly behavior

2018 ◽  
Vol 16 (19) ◽  
pp. 3584-3595 ◽  
Author(s):  
Shin-ichiro Kato ◽  
Satoshi Jin ◽  
Terutaka Kimura ◽  
Naoki Yoshikawa ◽  
Daiki Nara ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Self Assembly ◽  
Self Assembling ◽  
Assembly Behavior

We synthesized the first members of trithiazolyl-1,3,5-triazines that combine attractive photophysical and self-assembling properties.

Hydrothermal Syntheses, Crystal Structures, and Luminescent Properties of Two MnII Coordination Polymers: From Two-Fold Interpenetrated pcu Topological Net to Polycatenated 2D+2D→3D Framework

2015 ◽  
Vol 68 (2) ◽  
pp. 322 ◽  
Author(s):  
Wenlong Liu ◽  
Mengqiang Wu ◽  
Xueying Wang ◽  
Wei Wang ◽  
Dayu Liu ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Room Temperature ◽  
Luminescent Properties ◽  
The Self ◽  
X Ray Diffraction ◽  
X Ray ◽  
3D Framework ◽  
Dimethyl Benzene

Using a hydrothermal synthesis, the self-assembly of MnII ions and 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene with two dicarboxylate ligands, 2-nitrobenzene-1,4-dicarboxylic acid (2-H2ata) and 5-methylbenzene-1,3-dicarboxylic acid (5-CH3-H2ip) constructed two interesting coordination polymers: [Mn(2-ata)(bimb)]n (1) and {[Mn(5-CH3-ip)(bimb)1.5]·2H2O}n (2), where bimb refers to 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene. Their structures were determined by single-crystal X-ray diffraction, elemental analysis, and infrared spectroscopy. Complex 1 exhibits a 2-fold interpenetrated pcu net. Complex 2 shows an unusual polycatenated 2D+2D→3D framework. In addition, the solid-state photoluminescent properties of 1 and 2 were investigated at room temperature.

Self-assembly of a new class of amphiphilic poly(amidoamine) dendrimers and their electrochemical properties

2005 ◽  
Vol 43 (22) ◽  
pp. 5512-5519 ◽  
Author(s):  
Bing-Bing Wang ◽  
Xin Zhang ◽  
Xin-Ru Jia ◽  
Zi-Chen Li ◽  
Yan Ji ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Self Assembly ◽  
New Class

Lithography and self-assembly for nanometer scale magnetism

2002 ◽  
Vol 61-62 ◽  
pp. 569-575 ◽  
Author(s):  
S. Anders ◽  
S. Sun ◽  
C.B. Murray ◽  
C.T. Rettner ◽  
M.E. Best ◽  
...  
Keyword(s):  
Self Assembly ◽  
Nanometer Scale

Self-Assembly of α-MnO2 Nanorods into Spheres: Synthesis and Electrochemical Properties

2008 ◽  
Vol 8 (3) ◽  
pp. 1494-1496 ◽  
Author(s):  
Xu Chun Song ◽  
Yi Fan Zheng ◽  
E. Yang ◽  
Yun Wang
Keyword(s):  
Cyclic Voltammetry ◽  
Sodium Dodecyl Sulfate ◽  
Electrochemical Properties ◽  
Electrode Material ◽  
Self Assembly ◽  
Sodium Dodecyl ◽  
Electrochemical Characterization ◽  
Dodecyl Sulfate ◽  
Hydrothermal Approach

The α-MnO2 spherical assemblies were prepared via a facile hydrothermal approach in the presence of sodium dodecyl sulfate (SDS). The assembled nanostructures were composed of the MnO2 nanorods with 150–200 nm in width and several micrometers in length. The products were characterized by SEM, TEM and XRD. The electrochemical characterization was carried out by cyclic voltammetry, which indicated that the α-MnO2 spherical assemblies were of an excellent electrode material for supercapacitor.

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