Novel Reactions of Phosphorus Ylides with Carbonyl(cyclopentadienyl)metal Complexes: Preparative Access toμ-Alkylidene Complexes and Unexpected Acylations

1981 ◽  
Vol 20 (12) ◽  
pp. 1049-1051 ◽  
Author(s):  
Richard Korswagen ◽  
Reinhold Alt ◽  
Dieter Speth ◽  
Manfred L. Ziegler
Keyword(s):  
Metal Complexes ◽  
Phosphorus Ylides ◽  
Cyclopentadienyl Metal ◽  
Alkylidene Complexes

Chemistry of Phosphorus Ylides. Part 27. Metal Complexes of 4-hydroxyquinaldine, its Mannich Base and Phosphonium Ylide

2009 ◽  
Vol 2009 (5) ◽  
pp. 277-282 ◽  
Author(s):  
Fouad Soliman ◽  
Ibrahim Abd-Ellah ◽  
Soher Maigali ◽  
Gamal Abd-El-Naim
Keyword(s):  
Nitrogen Atom ◽  
Metal Complexes ◽  
Mannich Base ◽  
Phosphorus Ylides ◽  
Physicochemical Data

The reaction of Hg2+,Cd2+,Co2+, and Ni2+ ions with 1 mol of the ligands 2-methylquinoline-4-ol,3[(diethylamino)methyl]-2-methylquinoline-4-ol, and methyl-3-(4-hyrdoxy-2-methylquinoline-3-yl)-2-(triphenylphosphoranylidene)propanoate, has been investigated to give the corresponding 1:1 metal:ligand complexes. Reaction of 2 mol of the ligand gave the corresponding 1:2 metal:ligand complexes. The coordination takes place only through the quinoline nitrogen atom. The spectroscopic and the physicochemical data of the new metal complexes are discussed.

Simple and conjugated phosphorus ylides as ligands in zero-valent metal complexes

1972 ◽  
Vol 42 (1) ◽  
pp. C35-C38 ◽  
Author(s):  
K.A. Ostoja Starzewski ◽  
H.Tom Dieck ◽  
K.D. Franz ◽  
F. Hohmann
Keyword(s):  
Metal Complexes ◽  
Phosphorus Ylides

DNA Cleavage by the Photolysis of Cyclopentadienyl Metal Complexes:  Mechanistic Studies and Sequence Selectivity of Strand Scission by CpW(CO)3CH3

2005 ◽  
Vol 70 (23) ◽  
pp. 9093-9102 ◽  
Author(s):  
Debra L. Mohler ◽  
Jennifer R. Downs ◽  
Allison L. Hurley-Predecki ◽  
Jennifer R. Sallman ◽  
Peter M. Gannett ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Dna Cleavage ◽  
Mechanistic Studies ◽  
Strand Scission ◽  
Sequence Selectivity ◽  
Cyclopentadienyl Metal

Photoinduced DNA Cleavage by Cyclopentadienyl Metal Complexes Conjugated to DNA Recognition Elements

2001 ◽  
Vol 3 (17) ◽  
pp. 2761-2764 ◽  
Author(s):  
Allison L. Hurley ◽  
Mitchell P. Maddox ◽  
Tricia L. Scott ◽  
Mark R. Flood ◽  
Debra L. Mohler
Keyword(s):  
Metal Complexes ◽  
Dna Cleavage ◽  
Dna Recognition ◽  
Recognition Elements ◽  
Cyclopentadienyl Metal
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