Reversible Opening of a Trinuclear Heterometal Cluster

1979 ◽  
Vol 18 (1) ◽  
pp. 76-77 ◽  
Author(s):  
Gottfried Huttner ◽  
Josef Schneider ◽  
Hans-Dieter Müller ◽  
Gerhard Mohr ◽  
Joachim von Seyerl ◽  
...  
Keyword(s):  
Heterometal Cluster

Bilayer architecture based on hexanuclear heterometal cluster units

CrystEngComm ◽  
2014 ◽  
Vol 16 (29) ◽  
pp. 6790-6796 ◽  
Author(s):  
Wei-Hui Fang ◽  
Guo-Yu Yang
Keyword(s):  
Heterometal Cluster

An unprecedented bilayer architecture based on “head-to-head” hexanuclear heterometal clusters and linked by parallel [CuIL2] motifs has been hydrothermally made.

ChemInform Abstract: REVERSIBLE OPENING OF A TRINUCLEAR HETEROMETAL CLUSTER

1979 ◽  
Vol 10 (15) ◽  
Author(s):  
G. HUTTNER ◽  
J. SCHNEIDER ◽  
H.-D. MUELLER ◽  
G. MOHR ◽  
J. VON SEYERL ◽  
...  
Keyword(s):  
Heterometal Cluster

scholarly journals Neue mehrkernige Pd-Komplexe mit S, Se und PPh3 als Liganden. Die Kristallstrukturen von [Pd5Se4Cl2(PPh3)6], [Pd4NiS4Cl2(PPh3)6], [Pd5Se5(PPh3)5], [Pd6Se4Cl4(PPh3)6], [Pd7Se6(SeH)Cl(PPh3)7], [Pd8Se8(PPh3)8] und [Pd8Se8Cl(PPh3)8] + [CpCrCl3]- / New Multinuclear Pd Complexes with S, Se and PPh3 as Ligands. The Crystal Structures of [Pd5Se4Cl2(PPh3)6], [Pd4NiS4Cl2(PPh3)6], [Pd5Se5(PPh3)5], [Pd6Se4Cl4(PPh3)6], [Pd7Se6(SeH)Cl(PPh3)7], [Pd8Se8(PPh3)8] and [Pd8Se8Cl(PPh3)8]+[CpCrCl3]-

1991 ◽  
Vol 46 (10) ◽  
pp. 1384-1394 ◽  
Author(s):  
Dieter Fenske ◽  
Holm Fleischer ◽  
Harald Krautscheid ◽  
Jörg Magull ◽  
Christopher Oliver ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Molecular Structures ◽  
Starting Material ◽  
Pd Clusters ◽  
Pd Complexes ◽  
Heterometal Cluster

[PdCl2(PPh3)2] reacts with Se(SiMe3)2 to form a mixture of multinuclear Pd complexes, [Pd3Se2(SeSiMe3)2(PPh3)4] (1), [Pd5Se5(PPh3)5] (2) and [Pd8Se8(PPh3)8] (3). 1 can be used as starting material for the synthesis of further Pd clusters. Reactions of 1 with [CpCrCl2(THF)], [PdCl2(PPh3)2] and [NiCl2(PPh3)2] lead to the formation of [Pd6Se4Cl4(PPh3)6] (4), [Pd8Se8Cl(PPh3)8]+[CpCrCl3]- (5), [Pd5Se4Cl2(PPh3)6] (6) and [Pd7Se6(SeH)Cl(PPh3)7] (7). The complexes [Pd6Se4(SeH)2Cl2(PPh3)6] and [Pd6Se4(SeH)4(PPh3)6] have structures similar to 4, and are formed by reaction of [PdCl2(NBD)] or [PdCl(COD)]2(BF4)2 with PPh3 and Se(SiMe3)2.Reaction of [(C3H5)PdCl]2 with [NiCl2(PPh3)2] and S(SiMe3)2 leads to the formation of the heterometal cluster [Pd4NiS4Cl2(PPh3)6] (8).The molecular structures of 2-8 show quite clearly that these compounds may be considered as intermediates on the route towards multinuclear Pd complexes.

Synthesis of Heterometal Cluster Complexes by the Reaction of Cobaltadichalcogenolato Complexes with Groups 6 and 8 Metal Carbonyls

2006 ◽  
Vol 45 (3) ◽  
pp. 1108-1116 ◽  
Author(s):  
Masaki Murata ◽  
Satoru Habe ◽  
Shingo Araki ◽  
Kosuke Namiki ◽  
Teppei Yamada ◽  
...  
Keyword(s):  
Metal Carbonyls ◽  
Cluster Complexes ◽  
Heterometal Cluster

Synthesis and X-ray structure of (η5-C5H5)2W2Ir2(CO)7(CHCO2Et)2, a tetrahedral heterometal cluster with two different environments for ethylcarboxylatocarbene ligands

1985 ◽  
Vol 280 (3) ◽  
pp. c63-c66 ◽  
Author(s):  
Melvyn Rowen Churchill ◽  
Linda Vollaro Biondi ◽  
John R. Shapley ◽  
Colin H. McAteer
Keyword(s):  
X Ray ◽  
Heterometal Cluster

Pillar-Assisted Construction of a Three-Dimensional Framework from a Two-Dimensional Bilayer Based on a Zn/Cd Heterometal Cluster: Pore Tuning and Gas Adsorption

2018 ◽  
Vol 18 (3) ◽  
pp. 1826-1833 ◽  
Author(s):  
Danhua Song ◽  
Haiyang Hou ◽  
Yu-Jie Gao ◽  
Feilong Jiang ◽  
Daqiang Yuan ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Heterometal Cluster
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