Kinetic Studies on Substitution Reactions of Carbonylmetal Complexes

H. Werner

doi:10.1002/anie.196809301

ChemInform Abstract: Kinetic Studies on Substitution Reactions of Delepine′s Triangular Mixed-Valence Iridium(III,IV,IV) Complex (Ir3(μ3-N)(μ-SO4)6(H2O)3)4-.

ChemInform ◽

10.1002/chin.198701027 ◽

1987 ◽

Vol 18 (1) ◽

Author(s):

E. F. HILLS ◽

D. T. RICHENS ◽

A. G. SYKES

Keyword(s):

Mixed Valence ◽

Kinetic Studies ◽

Substitution Reactions

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Kinetic studies on substitution reactions of Delepine's triangular mixed-valence iridium(III, IV, IV) complex triaqua(.mu.3-nitrido)(hexa-.mu.-sulfato)triiridate(4-)

Inorganic Chemistry ◽

10.1021/ic00238a010 ◽

1986 ◽

Vol 25 (18) ◽

pp. 3144-3148 ◽

Cited By ~ 7

Author(s):

Elaine F. Hills ◽

David T. Richens ◽

A. Geoffrey Sykes

Keyword(s):

Mixed Valence ◽

Kinetic Studies ◽

Substitution Reactions

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Kinetic studies of Group VI metal carbonyl complexes. VI. Substitution reactions of the Group VI metal hexacarbonyls

Inorganic Chemistry ◽

10.1021/ic50057a034 ◽

1967 ◽

Vol 6 (11) ◽

pp. 2082-2085 ◽

Cited By ~ 85

Author(s):

James R. Graham ◽

Robert J. Angelici

Keyword(s):

Metal Carbonyl ◽

Kinetic Studies ◽

Carbonyl Complexes ◽

Substitution Reactions ◽

Group Vi ◽

Metal Carbonyl Complexes ◽

Metal Hexacarbonyls

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Kinetic studies of nucleophilic substitution Reactions of ?- and ?-Naphthacyl Bromides with Sodium Benzoates in 50% aqueous ethanol

Journal für Praktische Chemie ◽

10.1002/prac.19783200122 ◽

1978 ◽

Vol 320 (1) ◽

pp. 166-168 ◽

Cited By ~ 2

Author(s):

N. R. Naik ◽

B. P. Suthar ◽

T. B. Shah ◽

S. R. Patei

Keyword(s):

Nucleophilic Substitution ◽

Aqueous Ethanol ◽

Kinetic Studies ◽

Substitution Reactions ◽

Nucleophilic Substitution Reactions

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Kinetic studies on thiolato-ligand substitution reactions with halide ions of square-planar palladium(II) complex with bis(2-(diphenylphosphino)ethyl)phenylphosphine

Inorganica Chimica Acta ◽

10.1016/s0020-1693(02)00981-7 ◽

2002 ◽

Vol 338 ◽

pp. 235-239 ◽

Cited By ~ 10

Author(s):

Sen-ichi Aizawa ◽

Yasushi Sone ◽

Tatsuya Kawamoto ◽

Shinkichi Yamada ◽

Motoshi Nakamura

Keyword(s):

Kinetic Studies ◽

Ligand Substitution ◽

Halide Ions ◽

Substitution Reactions ◽

Square Planar ◽

Ligand Substitution Reactions

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Kinetic Studies of Substitution Reactions of Uranyl(VI) Schiff Base Complexes with Tributylphosphine

International Journal of Chemical Kinetics ◽

10.1002/kin.20753 ◽

2013 ◽

Vol 45 (3) ◽

pp. 168-174 ◽

Cited By ~ 1

Author(s):

Zahra Asadi ◽

Mohammad Ranjkesh Shorkaei

Keyword(s):

Schiff Base ◽

Kinetic Studies ◽

Schiff Base Complexes ◽

Substitution Reactions

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Exploring the acid-catalyzed substitution mechanism of [Fe4S4Cl4]2−

Dalton Transactions ◽

10.1039/c5dt04008f ◽

2016 ◽

Vol 45 (1) ◽

pp. 307-314 ◽

Cited By ~ 3

Author(s):

Thaer M. M. Al-Rammahi ◽

Richard A. Henderson

Keyword(s):

Bond Cleavage ◽

Kinetic Studies ◽

Substitution Reactions ◽

Substitution Mechanism ◽

Acid Catalyzed

Kinetic studies focussing on either the protonation or substitution step of the acid catalyzed substitution reactions of [Fe4S4Cl4]2− support a mechanism involving concomitant cluster protonation and Fe–(μ3-SH) bond cleavage.

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Kinetic studies of ligand substitution reactions and general-base catalysis in amine-ligand exchange processes for Group 6B metal carbonyl amine derivatives. Kinetic and spectroscopic evidence for hydrogen-bonded intermediates

Inorganic Chemistry ◽

10.1021/ic50226a029 ◽

1981 ◽

Vol 20 (12) ◽

pp. 4168-4177 ◽

Cited By ~ 8

Author(s):

Donald J. Darensbourg ◽

John A. Ewen

Keyword(s):

Ligand Exchange ◽

Metal Carbonyl ◽

Kinetic Studies ◽

Ligand Substitution ◽

Base Catalysis ◽

Substitution Reactions ◽

Spectroscopic Evidence ◽

General Base ◽

Exchange Processes ◽

Amine Ligand

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Kinetic studies of thermal decomposition and substitution reactions of cis-Mo(CO)4[P(C6H5)3](amine) compounds. Competitive study of Lewis bases for the intermediate [Mo(CO)4P(C6H5)3]

Inorganic Chemistry ◽

10.1021/ic50124a015 ◽

1973 ◽

Vol 12 (6) ◽

pp. 1286-1291 ◽

Cited By ~ 44

Author(s):

Carol L. Hyde ◽

Donald J. Darensbourg

Keyword(s):

Thermal Decomposition ◽

Kinetic Studies ◽

Substitution Reactions ◽

Lewis Bases ◽

Amine Compounds

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Kinetic Studies on the Reactions of [(TLtBu)PtCl]+ and [Pt(tpdm)Cl]+ Complexes with Some Thiols and Thioethers

Australian Journal of Chemistry ◽

10.1071/ch12218 ◽

2013 ◽

Vol 66 (5) ◽

pp. 534 ◽

Cited By ~ 4

Author(s):

Enisa Selimović ◽

Biljana Petrović ◽

Dragan Čcanović ◽

Živadin D. Bugarčić ◽

Jovana Bogojeski

Keyword(s):

Variable Temperature ◽

Kinetic Studies ◽

Substitution Reactions ◽

Tert Butyl ◽

Naclo4 Solution ◽

Entropy Of Activation ◽

Methyl Pyridine

Substitution reactions of the complexes [(TLtBu)PtCl]+ and [Pt(tpdm)Cl]+, where TLtBu = 2,6-bis[(1,3-di-tert-butylimidazolin-2-imino)methyl]pyridine and tpdm = terpyridinedimethane, with nucleophiles: S-methyl-L-cysteine (S-Met-L-Cys), L-cysteine (L-Cys), glutathione (GSH) and L-methionine (L-Met) were studied in aqueous 0.1 M NaClO4 solution in the presence of 10 mM NaCl using variable-temperature UV-vis spectrophotometry. The higher reactivity of the complex with the tpdm ligand could be attributed to the influence of the bulkiness of the tert-butyl-groups from the [(TLtBu)PtCl]+ complex. The order of reactivity of the studied ligands is: S-Met-L-Cys > L-Met > GSH > L-Cys. The thioethers (S-Met-L-Cys and L-Met) are more reactive than the thiols (GSH and L-Cys). This order of reactivity is in relation with their electron properties and structures. The negative values reported for the entropy of activation confirmed the associative mode.

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