scholarly journals A family of heterobimetallic cubes shows spin‐crossover behaviour near room temperature

2021 ◽  
Author(s):  
Matthias Hardy ◽  
Jacopo Tessarolo ◽  
Julian J. Holstein ◽  
Niklas Struch ◽  
Norbert Wagner ◽  
...  
2021 ◽  
Author(s):  
Iurii Galadzhun ◽  
Rafal Kulmaczewski ◽  
Namrah Shahid ◽  
Oscar Cespedes ◽  
Mark J Howard ◽  
...  

[Fe(bpp)2][BF4]2 (bpp = 2,6-di{pyrazol-1-yl}pyridine) derivatives bearing a bent geometry of hexadec-1-ynyl or hexadecyl substituents pyrazole are isomorphous, and high-spin at room temperature. However, only the latter compound undergoes an abrupt,...


2021 ◽  
pp. 138442
Author(s):  
Volodymyr M. Hiiuk ◽  
Karl Ridier ◽  
Il'ya A. Gural'skiy ◽  
Alexander A. Golub ◽  
Igor O. Fritsky ◽  
...  

2005 ◽  
Vol 117 (26) ◽  
pp. 4137-4141 ◽  
Author(s):  
Sébastien Bonhommeau ◽  
Gábor Molnár ◽  
Ana Galet ◽  
Antoine Zwick ◽  
José-Antonio Real ◽  
...  

2017 ◽  
Vol 53 (70) ◽  
pp. 9801-9804 ◽  
Author(s):  
Natnaree Phukkaphan ◽  
Dyanne L. Cruickshank ◽  
Keith S. Murray ◽  
Wasinee Phonsri ◽  
Phimphaka Harding ◽  
...  

An air stable FeIII complex showing a wide hysteresis near room temperature is described. The origin of the cooperativity is an unprecedented anion conformational change.


2015 ◽  
Vol 51 (45) ◽  
pp. 9346-9349 ◽  
Author(s):  
Haonan Peng ◽  
Gábor Molnár ◽  
Lionel Salmon ◽  
Azzedine Bousseksou

Acicular micro-rods of the novel [Fe(Htrz)3](CF3SO3)2 complex exhibiting large hysteretic spin crossover behavior perfectly centered at room temperature.


2013 ◽  
Vol 125 (4) ◽  
pp. 1092-1092 ◽  
Author(s):  
Tran Quang Hung ◽  
Ferial Terki ◽  
Souleymane Kamara ◽  
Mourad Dehbaoui ◽  
Salam Charar ◽  
...  

2016 ◽  
Vol 45 (43) ◽  
pp. 17132-17140 ◽  
Author(s):  
Hiroaki Hagiwara ◽  
Tomoko Tanaka ◽  
Shiori Hora

Magneto-structural relationships of mononuclear and dinuclear double helicate spin crossover (SCO) Fe(ii) complexes are reported.


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