scholarly journals H 2 ‐Free Re‐Based Catalytic Dehydroxylation of Aldaric Acid to Muconic and Adipic Acid Esters

2020 ◽  
Author(s):  
Brigita Hočevar ◽  
Anže Prašnikar ◽  
Matej Huš ◽  
Miha Grilc ◽  
Blaž Likozar
Keyword(s):  
Adipic Acid ◽  
Acid Esters

scholarly journals Designing of Green Plasticizers and Assessment of the Effectiveness of Their Use

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1761
Author(s):  
Aliya K. Mazitova ◽  
Guliya K. Aminova ◽  
Irina N. Vikhareva
Keyword(s):  
Adipic Acid ◽  
Polymer Materials ◽  
Operational Parameters ◽  
Solid Domestic Waste ◽  
Polymer Waste ◽  
Synthetic Materials ◽  
Environmental Requirements ◽  
Potential Methods ◽  
High Set ◽  
Acid Esters

The growing anthropogenic load on the lithosphere is currently characterized by the alienation of huge areas for solid domestic waste. One of the most common pollutants is traditional plastics with a degradation period of over 100 years. In connection with the increasing environmental requirements, polymer materials, along with a high set of technological and operational parameters, must be environmentally friendly and biodegradable. The development of polymer composite materials that undergo accelerated physicochemical and biological changes in the natural environment due to the introduction of biodegradable additives is one of the potential methods for processing synthetic materials and ensures the release of significant areas of fertile soils and lands from the steadily increasing amount of polymer waste. The use of adipic acid esters as PVC plasticizers contributes to the production of biodegradable composites. The article describes a method for obtaining new esters of adipic acid, presents the results of studying their properties for practical use in PVC composites, and assesses the economic efficiency of preventing damage to the environment when using them.

Direct synthesis of adipic acid esters via palladium-catalyzed carbonylation of 1,3-dienes

Science ◽  
2019 ◽  
Vol 366 (6472) ◽  
pp. 1514-1517 ◽  
Author(s):  
Ji Yang ◽  
Jiawang Liu ◽  
Helfried Neumann ◽  
Robert Franke ◽  
Ralf Jackstell ◽  
...  
Keyword(s):  
Adipic Acid ◽  
Direct Synthesis ◽  
Reaction Network ◽  
Catalyst System ◽  
Environmentally Benign ◽  
Palladium Catalyzed ◽  
Bidentate Phosphine ◽  
Cost Efficient ◽  
Bidentate Phosphine Ligand ◽  
Acid Esters

The direct carbonylation of 1,3-butadiene offers the potential for a more cost-efficient and environmentally benign route to industrially important adipic acid derivatives. However, owing to the complex reaction network of regioisomeric carbonylation and isomerization pathways, a selective practical catalyst for this process has thus far proven elusive. Here, we report the design of a pyridyl-substituted bidentate phosphine ligand (HeMaRaphos) that, upon coordination to palladium, catalyzes adipate diester formation from 1,3-butadiene, carbon monoxide, and butanol with 97% selectivity and 100% atom-economy under industrially viable and scalable conditions (turnover number > 60,000). This catalyst system also affords access to a variety of other di- and triesters from 1,2- and 1,3-dienes.

scholarly journals Activated sludge degradation of adipic acid esters.

1976 ◽  
Vol 31 (5) ◽  
pp. 746-749 ◽  
Author(s):  
V W Saeger ◽  
R G Kalley ◽  
O Hicks ◽  
E S Tucker ◽  
J P Mieure
Keyword(s):  
Activated Sludge ◽  
Adipic Acid ◽  
Acid Esters

scholarly journals H 2 ‐Free Re‐Based Catalytic Dehydroxylation of Aldaric Acid to Muconic and Adipic Acid Esters

2020 ◽  
Author(s):  
Brigita Hočevar ◽  
Anže Prašnikar ◽  
Matej Huš ◽  
Miha Grilc ◽  
Blaž Likozar
Keyword(s):  
Adipic Acid ◽  
Acid Esters

scholarly journals Investigation of the effect of the amount of additives on the properties of adipic acid esters

2019 ◽  
Vol 11 (4) ◽  
pp. 437-446 ◽  
Author(s):  
A.K. Mazitova ◽  
I.N. Vikhareva ◽  
G.K. Aminova ◽  
A.A. Timofeev ◽  
E.A. Buylova ◽  
...  
Keyword(s):  
Adipic Acid ◽  
Acid Esters

Embryonic-Fetal Toxicity and Teratogenic Effects of Adipic Acid Esters in Rats

1973 ◽  
Vol 62 (10) ◽  
pp. 1596-1600 ◽  
Author(s):  
A.R. Singh ◽  
W.H. Lawrence ◽  
J. Autian
Keyword(s):  
Adipic Acid ◽  
Teratogenic Effects ◽  
Fetal Toxicity ◽  
Acid Esters
Sign in / Sign up

Export Citation Format

Share Document