scholarly journals An Air‐Stable Heterobimetallic Si 2 M 2 Tetrahedral Cluster

2020 ◽  
Vol 132 (14) ◽  
pp. 5872-5878
Author(s):  
Gizem Dübek ◽  
Franziska Hanusch ◽  
Dominik Munz ◽  
Shigeyoshi Inoue
Keyword(s):  
Tetrahedral Cluster

Study on the local structure and EPR spectroscopy of compressed CuX4 (X = N, S, Cl and Br) tetrahedral cluster

2017 ◽  
Vol 115 (20) ◽  
pp. 2558-2564
Author(s):  
Min-Quan Kuang ◽  
Hong-Kuan Yuan ◽  
An-Long Kuang ◽  
Hong Chen ◽  
Li-Dan Wang ◽  
...  
Keyword(s):  
Epr Spectroscopy ◽  
Local Structure ◽  
Tetrahedral Cluster

scholarly journals An Air‐Stable Heterobimetallic Si 2 M 2 Tetrahedral Cluster

2020 ◽  
Vol 59 (14) ◽  
pp. 5823-5829 ◽  
Author(s):  
Gizem Dübek ◽  
Franziska Hanusch ◽  
Dominik Munz ◽  
Shigeyoshi Inoue
Keyword(s):  
Tetrahedral Cluster

scholarly journals Magnetism of a tetrahedral cluster spin chain

2001 ◽  
Vol 64 (21) ◽  
Author(s):  
Wolfram Brenig ◽  
Klaus W. Becker
Keyword(s):  
Spin Chain ◽  
Tetrahedral Cluster

nutation and Hahn-echo amplitudes in model compounds and application to the tetrahedral cluster Co4(CO)12

1997 ◽  
Vol 10 (1-2) ◽  
pp. 95-103 ◽  
Author(s):  
Pierre Kempgens ◽  
Jérôme Hirschinger ◽  
Pierre Granger ◽  
Jacky Rosé
Keyword(s):  
Model Compounds ◽  
Tetrahedral Cluster

The formation of mixed metal aminophosphinidene clusters via reactions of terminal chloroaminophosphido complexes with Co2(CO)8

2003 ◽  
Vol 81 (11) ◽  
pp. 1149-1156 ◽  
Author(s):  
Javier Sánchez-Nieves ◽  
Brian T Sterenberg ◽  
Konstantin A Udachin ◽  
Arthur J Carty
Keyword(s):  
Key Words ◽  
Tetrahedral Cluster ◽  
Mixed Metal ◽  
Cobalt Cluster ◽  
Molybdenum Cluster ◽  
Cluster 2

Reactions of terminal chloroaminophosphido complexes with Co2(CO)8 have been examined. The ruthenium phosphido complexes [Cp*Ru(CO)2{P(Cl)TMP}] (1a) and [CpRu(CO)2{P(Cl)TMP}] (1b) (TMP = 2,2,6,6-tetramethylpiperidinyl) react with Co2(CO)8 to form the cobalt cluster [Co4(CO)7(µ-CO)3{µ3-P(TMP)}] (2) with complete transfer of the phosphinidene unit to cobalt. In contrast, the phosphido complex [Cp*Ru(CO)2{P(Cl)N-i-Pr2}] (1c) affords the spiked-triangular cluster [Cp*RuCo3(CO)8(µ-CO)2(µ3-PN-i-Pr2)] (3), which retains the Cp*Ru unit upon reaction with Co2(CO)8. The molybdenum phosphido complex [CpMo(CO)2{P(Cl)TMP}] (4) reacts with Co2(CO)8 to form cluster 2, while [Cp*Mo(CO)3{P(Cl)N-i-Pr2}] (5) generates the mixed metal tetrahedral cluster [Cp*MoCo3(CO)5(µ-CO)4(µ3-PN-i-Pr2)] (6). Key words: phosphido, phosphinidene, cobalt, ruthenium, molybdenum, cluster.

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