The formation of mixed metal aminophosphinidene clusters via reactions of terminal chloroaminophosphido complexes with Co2(CO)8

2003 ◽  
Vol 81 (11) ◽  
pp. 1149-1156 ◽  
Author(s):  
Javier Sánchez-Nieves ◽  
Brian T Sterenberg ◽  
Konstantin A Udachin ◽  
Arthur J Carty
Keyword(s):  
Key Words ◽  
Tetrahedral Cluster ◽  
Mixed Metal ◽  
Cobalt Cluster ◽  
Molybdenum Cluster ◽  
Cluster 2

Reactions of terminal chloroaminophosphido complexes with Co2(CO)8 have been examined. The ruthenium phosphido complexes [Cp*Ru(CO)2{P(Cl)TMP}] (1a) and [CpRu(CO)2{P(Cl)TMP}] (1b) (TMP = 2,2,6,6-tetramethylpiperidinyl) react with Co2(CO)8 to form the cobalt cluster [Co4(CO)7(µ-CO)3{µ3-P(TMP)}] (2) with complete transfer of the phosphinidene unit to cobalt. In contrast, the phosphido complex [Cp*Ru(CO)2{P(Cl)N-i-Pr2}] (1c) affords the spiked-triangular cluster [Cp*RuCo3(CO)8(µ-CO)2(µ3-PN-i-Pr2)] (3), which retains the Cp*Ru unit upon reaction with Co2(CO)8. The molybdenum phosphido complex [CpMo(CO)2{P(Cl)TMP}] (4) reacts with Co2(CO)8 to form cluster 2, while [Cp*Mo(CO)3{P(Cl)N-i-Pr2}] (5) generates the mixed metal tetrahedral cluster [Cp*MoCo3(CO)5(µ-CO)4(µ3-PN-i-Pr2)] (6). Key words: phosphido, phosphinidene, cobalt, ruthenium, molybdenum, cluster.

Synthesis and Structure of [Cp*Ru(CO)2(μ-H){RuFe3(CO)9}]: An Unusual Mixed-Metal Tetrahedral Cluster with an Exopolyhedral Metal Fragment

2011 ◽  
Vol 30 (1) ◽  
pp. 191-194 ◽  
Author(s):  
K. Geetharani ◽  
Shubhankar Kumar Bose ◽  
Sundargopal Ghosh
Keyword(s):  
Tetrahedral Cluster ◽  
Mixed Metal ◽  
Metal Fragment

Heuristische Typologien von Alkoholabhängigen

2011 ◽  
Vol 30 (07) ◽  
pp. 509-516
Author(s):  
K. Bühler
Keyword(s):  
Cluster 2

ZusammenfassungTrotz der Bedeutung biografischer Faktoren für die Alkoholabhängigkeit und Behandlung von Alkoholabhängigen haben wenige Studien biografische Daten von Alkoholabhängigen untersucht. Deshalb wurden in unserer Studie biografische Variablen zusätzlich zu Persönlichkeitsvariablen berücksichtigt. Die Personen wurden clusteranalysiert. Eine 5-Clusterlösung ergab eine gut interpretierbare Klassifikation. Das hinsichtlich des Schweregrades der Störung am wenigsten gestörte Cluster 2 (normovalenter Typ) wurde gefolgt von Cluster 4 (zielgerichtet neurotischer Typ), Cluster 1 (sozionoxischer Typ), Cluster 5 (desorganisiert neurotischer Typ) und Cluster 3 (neurosozionoxischer Typ). Der normovalente Typ ist der signifikant älteste und der neurosozionoxische Typ der signifikant jüngste Typ. Frauen überwiegen in den Typen mit der stärksten Beeinträchtigung, das heißt, im Cluster 3 und 5. Patienten des Clusters 2 entstammen signifikant seltener, Patienten des Clusters 3 hingegen signifikant häufiger unvollständigen Familien. Patienten des Clusters 2 wuchsen signifikant häufiger bei ihren Eltern auf, Patienten des Clusters 3 und 5 hingegen signifikant weniger. Patienten des Clusters 2 und 4 lebten signifikant häufiger in Partnerschaften als die restlichen Cluster. Den entdeckten Typen von Alkoholabhängigen kommt nicht nur eine deskriptive Bedeutung zu, sondern in Anbetracht des unterschiedlichen Schweregrades der Störung auch eine differenzialtherapeutische. Daher wird entsprechend des Schweregrades der Störung eine Differenzialtherapie vorgeschlagen.

Multislice imaging of gastrointestinal stromal tumors

2018 ◽  
pp. 3-14
Keyword(s):  
Computed Tomography ◽  
Key Words ◽  
Gold Standard ◽  
Gastrointestinal Stromal Tumors ◽  
Mesenchymal Tumors ◽  
Stromal Tumors ◽  
Preferential Localization ◽  
Multislice Imaging ◽  
Computed Tomography Diagnosis

Gastrointestinal stromal tumors (GIST) are the most common mesenchymal tumors of the digestive tract (1%). These tumors express the CD 117 in 95% of cases. The stomach is the preferential localization (70%). Diagnosis is difficult and sometimes late. Progress of imaging has greatly improved the management and the prognosis. Computed tomography (CT) is the gold standard for diagnosis, staging, and treatment follow-up. The increasing recognition of GIST’s histopathology and the prolonged survival revealed some suggestive imaging aspects. Key words: gastro-intestinal stromal tumors; computed tomography; diagnosis

METHODS OF CONSULTING ON STUDYING THE DEGREE OF MOISTURE SUPPLY OF SLOPE LANDS FOR AGRICULTURAL PRODUCTION IN AZERBAIJAN

2018 ◽  
Author(s):  
Prof.RAE Aliev Z.H.
Keyword(s):  
Key Words ◽  
Agricultural Production ◽  
Soil Ecology ◽  
Arable Soil ◽  
Clean Technology ◽  
Agricultural Product ◽  
Current Information ◽  
Moisture Supply ◽  
Managerial System

The current information on moisture and the temperature of the ground in managerial system by production to agricultural product necessary, in the first place, for taking the operative decisions at development ecological clean technology irrigation under growing agricultural cultures to achieve the maximum harvest. Key words: aerospace methods, COW, moisture, moisture test, arable, soil, ecology, vafer humidity, drill, graduation, tool, etc.

Penerapan Data Mining Untuk Prediksi Penjualan Mobil Menggunakan Metode K-Means Clustering

2020 ◽  
Vol 3 (3) ◽  
pp. 187-201
Author(s):  
Sufajar Butsianto ◽  
Nindi Tya Mayangwulan
Keyword(s):  
Data Mining ◽  
Clustering Data ◽  
Cluster 2

Penggunaan mobil di Indonesia setiap tahunnya selalu meningkat dan membuat perusahaan otomotif berlomba-lomba dalam peningkatan penjualannya. Tujuan dari penelitian ini untuk mengelompokan data penjualan kedalam sebuah cluster dengan metode Data Mining Algoritma K-Means Clustering. Data Penjualan nantinya akan dikelompokan berdasarkan kemiripan data tersebut sehingga data dengan karakteristik yang sama akan berada dalam satu cluster. Atribut yang digunakan adalah brand dan penjualan. Cluster yang terbentuk setelah dilakukan proses K-Means Clustering terbagi menjadi tiga cluster yaitu Cluster 0 jumlah anggota 235 dengan presentase 26% dikategorikan Laris, Cluster 1 jumlah anggota 604 dengan presentase 67% dikategorikan Kurang Laris, dan Cluster 2 jumlah angota 61 dengan presentase 7% dikategorikan Paling Laris, dari proses clustering diatas dapat diperoleh validasi DBI (Davies Bouldin Index) dengan nilai 0,341

PELAKSANAAN HUKUM KEWARISAN ISLAM DI PENGADILAN AGAMA BANTEN

ALQALAM ◽  
2013 ◽  
Vol 30 (1) ◽  
pp. 158
Author(s):  
Yusuf Somawinata
Keyword(s):  
Key Words ◽  
Islamic Law ◽  
Survey Methods ◽  
Adopted Children ◽  
Inheritance Law ◽  
Library Research ◽  
The Ideal

This article aims at describing the obseroance of wasiat wajibah (compulsory bequeathment) in the Islamic court of Banten, analyzing the provision of the substitute heir and adopted children in the Compilation of  Islamic Law (KHI). In addition, the ideal laws to manage the innheritance rules in Indonesia. This article is library research by using doctrinal approach and using case study and survey methods. The data was, then, analyzed by using analytical descriptive and analytical correlative methods. The result showed that the observance of wasiat wajibah in the Islamic court of  Banten employed by judges is by using the Mawali Hazairin’s Doctrine. The criteria of the adoption of substitute heir and adopted children in the KHI is the attempts of Ulama and many judgees junst in giving legal justice and certainty to the society.   Key Words: Islamic Inheritance Law, Compilation of Islamic Law, Islamic court of  Banten

Phosphorus fertilization in inbred and hybrid rice

1970 ◽  
Vol 19 (2) ◽  
pp. 181-187
Author(s):  
MR Islam ◽  
PK Saha ◽  
SK Zaman ◽  
MJ Uddin
Keyword(s):  
Grain Yield ◽  
Key Words ◽  
Hybrid Rice ◽  
Phosphorus Fertilization ◽  
Phosphorus Fertilizer ◽  
Yield Difference ◽  
P Balance ◽  
Rice Genotypes ◽  
Boro Rice

Five phosphorus rates (0, 5, 10, 20 and 30 kg P/ha) were tested with four rice genotypes in Boro (BRRI dhan36, BRRI dhan45, EH1 and EH2) and T. Aman (BRRI dhan30, BRRI dhan49, EH1 and EH2) season. Phosphorus rates did not influence grain yield irrespective of varieties in T. Aman season while in Boro season P response was observed among the P rates. Application of P @ 10 kg/ha significantly increased the grain yield. But when P was applied @ 20 and 30 kg P/ha, the grain yield difference was not significant. The optimum and economic rate of P for T. Aman was 20 kg P/ha but in Boro rice the optimum and economic doses of P were 22 and 30 kg/ha, respectively. Hybrid entries (EH1 and EH2) used P more efficiently than inbred varieties. A negative P balance was observed up to 10 kg P/ha. Key words: Response; Phosphorus fertilizer; Inbred; Hybrid rice DOI: http://dx.doi.org/10.3329/dujbs.v19i2.8962 DUJBS 2010; 19(2): 181-187

Laparoscopic adrenal cystectomy - report of two cases

1970 ◽  
Vol 19 (1) ◽  
pp. 50-53
Author(s):  
GM Zakir Hossain ◽  
Mofizur Rahman ◽  
Mohammad Rashedul Hasan
Keyword(s):  
Key Words ◽  
College Teachers ◽  
Medical College

Key words: laparoscopic; adrenal cystectomydoi: 10.3329/jcmcta.v19i1.3854Journal of Chittagong Medical College Teachers' Association 2008: 19(1):50-53

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