scholarly journals Visible‐Light‐Induced Palladium‐Catalyzed Generation of Aryl Radicals from Aryl Triflates

2020 ◽  
Vol 132 (26) ◽  
pp. 10402-10406
Author(s):  
Maxim Ratushnyy ◽  
Nikita Kvasovs ◽  
Sumon Sarkar ◽  
Vladimir Gevorgyan
Keyword(s):  
Visible Light ◽  
Aryl Radicals ◽  
Palladium Catalyzed

scholarly journals Visible‐Light‐Induced Palladium‐Catalyzed Generation of Aryl Radicals from Aryl Triflates

2020 ◽  
Vol 59 (26) ◽  
pp. 10316-10320 ◽  
Author(s):  
Maxim Ratushnyy ◽  
Nikita Kvasovs ◽  
Sumon Sarkar ◽  
Vladimir Gevorgyan
Keyword(s):  
Visible Light ◽  
Aryl Radicals ◽  
Palladium Catalyzed

Visible-Light Photocatalytic Reduction of Sulfonium Salts as a Source of Aryl Radicals

2013 ◽  
Vol 355 (8) ◽  
pp. 1477-1482 ◽  
Author(s):  
Simon Donck ◽  
Abdulkader Baroudi ◽  
Louis Fensterbank ◽  
Jean-Philippe Goddard ◽  
Cyril Ollivier
Keyword(s):  
Visible Light ◽  
Photocatalytic Reduction ◽  
Sulfonium Salts ◽  
Aryl Radicals ◽  
Visible Light Photocatalytic

Visible-light-mediated borylation of aryl and alkyl halides with a palladium complex

2020 ◽  
Vol 18 (23) ◽  
pp. 4390-4394
Author(s):  
Jia-Hui Zhao ◽  
Zhao-Zhao Zhou ◽  
Yue Zhang ◽  
Xuan Su ◽  
Xi-Meng Chen ◽  
...  
Keyword(s):  
Visible Light ◽  
Functional Group ◽  
Palladium Complex ◽  
Alkyl Halides ◽  
Palladium Catalyzed ◽  
High Yields

Palladium catalyzed visible-light-mediated borylation of inactivated aryl and alkyl halides is reported; the method provided high yields and excellent functional group compatibility.

scholarly journals Intermolecular oxyarylation of olefins with aryl halides and TEMPOH catalyzed by the phenolate anion under visible light

2020 ◽  
Vol 11 (27) ◽  
pp. 6996-7002
Author(s):  
Kangjiang Liang ◽  
Qian Liu ◽  
Lei Shen ◽  
Xipan Li ◽  
Delian Wei ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Visible Light ◽  
Aryl Halides ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Strong Reduction ◽  
Aryl Radicals ◽  
Reduction Potentials

The phenolate anion was developed as a new photocatalyst with strong reduction potentials (−3.16 V vs. SCE) to reduction of aryl halides to aryl radicals through single electron transfer.

Palladium‐Catalyzed Decarboxylative Heck‐Type Coupling of Activated Aliphatic Carboxylic Acids Enabled by Visible Light

2018 ◽  
Vol 24 (18) ◽  
pp. 4552-4555 ◽  
Author(s):  
Maximilian Koy ◽  
Frederik Sandfort ◽  
Adrian Tlahuext‐Aca ◽  
Linda Quach ◽  
Constantin G. Daniliuc ◽  
...  
Keyword(s):  
Visible Light ◽  
Carboxylic Acids ◽  
Palladium Catalyzed ◽  
Type Coupling ◽  
Aliphatic Carboxylic Acids

Visible-Light-Driven Palladium-Catalyzed Radical Alkylation of C−H Bonds with Unactivated Alkyl Bromides

2017 ◽  
Vol 56 (49) ◽  
pp. 15683-15687 ◽  
Author(s):  
Wen-Jun Zhou ◽  
Guang-Mei Cao ◽  
Guo Shen ◽  
Xing-Yong Zhu ◽  
Yong-Yuan Gui ◽  
...  
Keyword(s):  
Visible Light ◽  
Alkyl Bromides ◽  
Visible Light Driven ◽  
Palladium Catalyzed

scholarly journals Radical Carbonylative Synthesis of Heterocycles by Visible Light Photoredox Catalysis

Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1054
Author(s):  
Xiao-Qiang Hu ◽  
Zi-Kui Liu ◽  
Wen-Jing Xiao
Keyword(s):  
Visible Light ◽  
Efficient Synthesis ◽  
Acyl Radical ◽  
Acyl Chlorides ◽  
Aryl Radicals ◽  
Keto Acids ◽  
Acyl Radicals ◽  
Different Types ◽  
The Impact ◽  
Visible Light Photocatalytic

Visible light photocatalytic radical carbonylation has been established as a robust tool for the efficient synthesis of carbonyl-containing compounds. Acyl radicals serve as the key intermediates in these useful transformations and can be generated from the addition of alkyl or aryl radicals to carbon monoxide (CO) or various acyl radical precursors such as aldehydes, carboxylic acids, anhydrides, acyl chlorides or α-keto acids. In this review, we aim to summarize the impact of visible light-induced acyl radical carbonylation reactions on the synthesis of oxygen and nitrogen heterocycles. The discussion is mainly categorized based on different types of acyl radical precursors.

Three-Component Visible-Light-Induced Palladium-Catalyzed 1,2-Alkyl Carbamoylation/Cyanation of Alkenes

ACS Catalysis ◽  
2021 ◽  
pp. 13217-13222
Author(s):  
Xiangqing Jia ◽  
Ziyan Zhang ◽  
Vladimir Gevorgyan
Keyword(s):  
Visible Light ◽  
Palladium Catalyzed
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