scholarly journals Tuning the Gate‐Opening Pressure in a Switching pcu Coordination Network, X‐pcu‐5‐Zn, by Pillar‐Ligand Substitution

2019 ◽  
Vol 131 (50) ◽  
pp. 18380-18385 ◽  
Author(s):  
Ai‐Xin Zhu ◽  
Qing‐Yuan Yang ◽  
Soumya Mukherjee ◽  
Amrit Kumar ◽  
Cheng‐Hua Deng ◽  
...  
Keyword(s):  
Ligand Substitution ◽  
Opening Pressure ◽  
Coordination Network ◽  
Gate Opening

scholarly journals Tuning the Gate‐Opening Pressure in a Switching pcu Coordination Network, X‐pcu‐5‐Zn, by Pillar‐Ligand Substitution

2019 ◽  
Vol 58 (50) ◽  
pp. 18212-18217 ◽  
Author(s):  
Ai‐Xin Zhu ◽  
Qing‐Yuan Yang ◽  
Soumya Mukherjee ◽  
Amrit Kumar ◽  
Cheng‐Hua Deng ◽  
...  
Keyword(s):  
Ligand Substitution ◽  
Opening Pressure ◽  
Coordination Network ◽  
Gate Opening

scholarly journals Reversible Switching between Highly Porous and Nonporous Phases of an Interpenetrated Diamondoid Coordination Network That Exhibits Gate-Opening at Methane Storage Pressures

2018 ◽  
Vol 130 (20) ◽  
pp. 5786-5791 ◽  
Author(s):  
Qing-Yuan Yang ◽  
Prem Lama ◽  
Susan Sen ◽  
Matteo Lusi ◽  
Kai-Jie Chen ◽  
...  
Keyword(s):  
Methane Storage ◽  
Coordination Network ◽  
Gate Opening ◽  
Highly Porous

Nano-gate opening pressures for the adsorption of isobutane, n-butane, propane, and propylene gases on bimetallic Co–Zn based zeolitic imidazolate frameworks

2019 ◽  
Vol 48 (14) ◽  
pp. 4685-4695 ◽  
Author(s):  
Ahmed Awadallah-F ◽  
Febrian Hillman ◽  
Shaheen A. Al-Muhtaseb ◽  
Hae-Kwon Jeong
Keyword(s):  
Microwave Method ◽  
Zeolitic Imidazolate Frameworks ◽  
Opening Pressure ◽  
Zeolitic Imidazolate Framework ◽  
Mixed Metal ◽  
Gate Opening ◽  
Pressure Threshold

In this article, zeolitic-imidazolate framework-8 (ZIF-8) and its mixed metal CoZn-ZIF-8 were synthesized via a rapid microwave method. They exhibited a nanogate opening pressure threshold for the adsorption of C3 and C4 compounds.

Tuning the gate-opening pressure and particle size distribution of the switchable metal–organic framework DUT-8(Ni) by controlled nucleation in a micromixer

2017 ◽  
Vol 46 (40) ◽  
pp. 14002-14011 ◽  
Author(s):  
Hiroki Miura ◽  
Volodymyr Bon ◽  
Irena Senkovska ◽  
Sebastian Ehrling ◽  
Satoshi Watanabe ◽  
...  
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Metal Organic Framework ◽  
Narrow Particle Size Distribution ◽  
Opening Pressure ◽  
Gate Opening ◽  
Metal Organic ◽  
Controlled Nucleation ◽  
Organic Framework

Controlled nucleation in a micromixer was used to synthesize DUT-8(Ni) with narrow particle size distribution in a range from few nm to several μm.

scholarly journals Tuning the Gate Opening Pressure of Metal–Organic Frameworks (MOFs) for the Selective Separation of Hydrocarbons

2012 ◽  
Vol 134 (37) ◽  
pp. 15201-15204 ◽  
Author(s):  
Nour Nijem ◽  
Haohan Wu ◽  
Pieremanuele Canepa ◽  
Anne Marti ◽  
Kenneth J. Balkus ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Selective Separation ◽  
Opening Pressure ◽  
Gate Opening ◽  
Metal Organic

Tuning the gate opening pressure of a flexible doubly interpenetrated metal–organic framework through ligand functionalization

2018 ◽  
Vol 47 (37) ◽  
pp. 13158-13163 ◽  
Author(s):  
Xiaodong Sun ◽  
Yali Ma ◽  
Jun Zhao ◽  
Dong-Sheng Li ◽  
Guanghua Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Opening Pressure ◽  
Gate Opening ◽  
Metal Organic ◽  
Organic Framework

JLU-Liu33F has been solvothermally synthesized by utilizing the ligand functionalization strategy. Compared with JLU-Liu33, JLU-Liu33F exhibits a completely different breathing behavior.

How do we sedate children undergoing CSF opening pressure measurement? Results of a Germany-wide survey

2011 ◽  
Vol 42 (S 01) ◽  
Author(s):  
D Tibussek ◽  
F Distelmaier ◽  
S Kummer ◽  
E Mayatepek
Keyword(s):  
Pressure Measurement ◽  
Opening Pressure ◽  
Measurement Results

Synthesis and Photochemical Properties of Re(I) Tricarbonyl Complexes Bound to Thione and Thiazole-2-ylidene Ligands

2020 ◽  
Author(s):  
Matthew Stout ◽  
Brian Skelton ◽  
Alexandre N. Sobolev ◽  
Paolo Raiteri ◽  
Massimiliano Massi ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Excited States ◽  
Ligand Exchange ◽  
Ligand Substitution ◽  
Bidentate Ligand ◽  
The Other ◽  
Ligand Exchange Reaction ◽  
Multiple Products ◽  
Ligand Charge Transfer ◽  
Photochemical Properties

<p>Three Re(I) tricarbonyl complexes, with general formulation Re(N^L)(CO)<sub>3</sub>X (where N^L is a bidentate ligand containing a pyridine functionalized in the position 2 with a thione or a thiazol-2-ylidene group and X is either chloro or bromo) were synthesized and their reactivity explored in terms of solvent-dependent ligand substitution, both in the ground and excited states. When dissolved in acetonitrile, the complexes bound to the thione ligand underwent ligand exchange with the solvent resulting in the formation of Re(NCMe)<sub>2</sub>(CO)<sub>3</sub>X. The exchange was found to be reversible, and the starting complex was reformed upon removal of the solvent. On the other hand, the complexes appeared inert in dichloromethane or acetone. Conversely, the complex bound to the thiazole-2-ylidene ligand did not display any ligand exchange reaction in the dark, but underwent photoactivated ligand substitution when excited to its lowest metal-to-ligand charge transfer manifold. Photolysis of this complex in acetonitrile generated multiple products, including Re(I) tricarbonyl and dicarbonyl solvato-complexes as well as free thiazole-2-ylidene ligand.</p>

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