Tuning the gate-opening pressure and particle size distribution of the switchable metal–organic framework DUT-8(Ni) by controlled nucleation in a micromixer

2017 ◽  
Vol 46 (40) ◽  
pp. 14002-14011 ◽  
Author(s):  
Hiroki Miura ◽  
Volodymyr Bon ◽  
Irena Senkovska ◽  
Sebastian Ehrling ◽  
Satoshi Watanabe ◽  
...  
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Metal Organic Framework ◽  
Narrow Particle Size Distribution ◽  
Opening Pressure ◽  
Gate Opening ◽  
Metal Organic ◽  
Controlled Nucleation ◽  
Organic Framework

Controlled nucleation in a micromixer was used to synthesize DUT-8(Ni) with narrow particle size distribution in a range from few nm to several μm.

scholarly journals Role of particle size and surface functionalisation on the flexibility behaviour of switchable metal–organic framework DUT-8(Ni)

2020 ◽  
Vol 8 (43) ◽  
pp. 22703-22711
Author(s):  
Megan J. Thompson ◽  
Claire L. Hobday ◽  
Irena Senkovska ◽  
Volodymyr Bon ◽  
Sebastian Ehrling ◽  
...  
Keyword(s):  
Particle Size ◽  
External Surface ◽  
Metal Organic Framework ◽  
Gate Opening ◽  
Metal Organic ◽  
Surface Functionalisation ◽  
Closing Pressure ◽  
Organic Framework

Functionalising the external surface of flexible MOF nanoparticles allows manipulating the gate opening/closing pressure.

Tuning the gate opening pressure of a flexible doubly interpenetrated metal–organic framework through ligand functionalization

2018 ◽  
Vol 47 (37) ◽  
pp. 13158-13163 ◽  
Author(s):  
Xiaodong Sun ◽  
Yali Ma ◽  
Jun Zhao ◽  
Dong-Sheng Li ◽  
Guanghua Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Opening Pressure ◽  
Gate Opening ◽  
Metal Organic ◽  
Organic Framework

JLU-Liu33F has been solvothermally synthesized by utilizing the ligand functionalization strategy. Compared with JLU-Liu33, JLU-Liu33F exhibits a completely different breathing behavior.

scholarly journals Corrigendum: Tuning Gate‐Opening of a Flexible Metal–Organic Framework for Ternary Gas Sieving Separation

2021 ◽  
Vol 60 (8) ◽  
pp. 3850-3850
Author(s):  
Qiubing Dong ◽  
Xin Zhang ◽  
Shuang Liu ◽  
Rui‐Biao Lin ◽  
Yanan Guo ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Gate Opening ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

Selective adsorption and separation of C2 hydrocarbons in a “flexible-robust” metal–organic framework based on a guest-dependent gate-opening effect

2020 ◽  
Vol 56 (41) ◽  
pp. 5520-5523
Author(s):  
Peng-Dan Zhang ◽  
Xue-Qian Wu ◽  
Tao He ◽  
Lin-Hua Xie ◽  
Qiang Chen ◽  
...  
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Gate Opening ◽  
Metal Organic ◽  
C2 Hydrocarbons ◽  
Organic Framework

The selective adsorption and separation of C2 hydrocarbons have been achieved in a “flexible-robust” MOF based on a guest-dependent gate-opening effect.

scholarly journals Exceptional adsorption-induced cluster and network deformation in the flexible metal–organic framework DUT-8(Ni) observed by in situ X-ray diffraction and EXAFS

2015 ◽  
Vol 17 (26) ◽  
pp. 17471-17479 ◽  
Author(s):  
Volodymyr Bon ◽  
Nicole Klein ◽  
Irena Senkovska ◽  
Andreas Heerwig ◽  
Jürgen Getzschmann ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Gate Opening ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

The “gate opening” mechanism in flexible MOF Ni2(2,6-ndc)2dabco was elucidated in detail.

Green synthesis of submicron copper powder with narrow particle size distribution via a simple methanol thermal reduction

2021 ◽  
Author(s):  
Xiaoping Chen ◽  
Jiaqi Fu ◽  
Jiangang Li ◽  
Bohong Chen ◽  
Lei Yang ◽  
...  
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Green Synthesis ◽  
Size Distribution ◽  
Copper Powder ◽  
Reduction Method ◽  
Particle Distribution ◽  
Thermal Reduction ◽  
Narrow Particle Size Distribution

In this work, submicron copper powder with narrow particle distribution was synthesized via a simple methanol thermal reduction method without using any surfactants. Smaller copper powder with narrower particle size...

Organosilicon Comb-Shaped Surfactants for the Synthesis of Polymer Suspensions with a Narrow Particle Size Distribution

2021 ◽  
Vol 63 (3) ◽  
pp. 209-217
Author(s):  
A. A. Ezhova ◽  
I. A. Gritskova ◽  
S. A. Gusev ◽  
S. A. Milenin ◽  
V. V. Gorodov ◽  
...  
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Narrow Particle Size Distribution

scholarly journals Particle size studies to reveal crystallization mechanisms of the metal organic framework HKUST-1 during sonochemical synthesis

2017 ◽  
Vol 34 ◽  
pp. 365-370 ◽  
Author(s):  
Mitchell R. Armstrong ◽  
Sethuraman Senthilnathan ◽  
Christopher J. Balzer ◽  
Bohan Shan ◽  
Liang Chen ◽  
...  
Keyword(s):  
Particle Size ◽  
Metal Organic Framework ◽  
Sonochemical Synthesis ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Particle size effects in the kinetic trapping of a structurally-locked form of a flexible MOF

CrystEngComm ◽  
2016 ◽  
Vol 18 (22) ◽  
pp. 4172-4179 ◽  
Author(s):  
Oliver M. Linder-Patton ◽  
Witold M. Bloch ◽  
Campbell J. Coghlan ◽  
Kenji Sumida ◽  
Susumu Kitagawa ◽  
...  
Keyword(s):  
Particle Size ◽  
Size Effects ◽  
Metal Organic Framework ◽  
Particle Size Effects ◽  
Metal Organic ◽  
Flexible Metal ◽  
Kinetic Trapping ◽  
2D To 3D ◽  
Organic Framework

Controlling the particle size of a flexible metal–organic framework demonstrates that a 2D to 3D transformation gives a kinetically-trapped, structurally-locked form.

scholarly journals Polymer-Assisted Modification of Metal-Organic Framework MIL-96 (Al): Influence on Particle Size, Crystal Morphology and Perfluorooctanoic Acid (PFOA) Removal

2020 ◽  
Author(s):  
Luqman Hakim Mohd Azmi ◽  
Daryl R. Williams ◽  
Bradley P. Ladewig
Keyword(s):  
Particle Size ◽  
Crystal Morphology ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Synthesis Method ◽  
Perfluorooctanoic Acid ◽  
Water Soluble ◽  
Water Soluble Polymer ◽  
Metal Organic ◽  
Organic Framework

<div><b>Abstract</b></div><div>A new synthesis method was developed to prepare an aluminum-based metal organic framework (MIL-96) with a larger particle size and different crystal habits. A low cost and water-soluble polymer, hydrolyzed polyacrylamide (HPAM), was added in varying quantities into the synthesis reaction to achieve >200% particle size enlargement with controlled crystal morphology. The modified adsorbent, MIL-96-RHPAM2, was systematically characterized by SEM, XRD, FTIR, BET and TGA-MS. Using activated carbon (AC) as a reference adsorbent, the effectiveness of MIL-96-RHPAM2 for perfluorooctanoic acid (PFOA) removal from water was examined. The study confirms stable morphology of hydrated MIL-96-RHPAM2 particles as well as a superior PFOA adsorption capacity (340 mg/g) despite its lower surface area, relative to standard MIL-96. MIL-96-RHPAM2 suffers from slow adsorption kinetics as the modification significantly blocks pore access. The strong adsorption of PFOA by MIL-96-RHPAM2 was associated with the formation of electrostatic bonds between the anionic carboxylate of PFOA and the amine functionality present in the HPAM backbone. Thus, the strongly held PFOA molecules in the pores of MIL-96-RHPAM2 were not easily desorbed even after eluted with a high ionic strength solvent (500 mM NaCl). Nevertheless, this simple HPAM addition strategy can still chart promising pathways to impart judicious control over adsorbent particle size and crystal shapes while the introduction of amine functionality onto the surface chemistry is simultaneously useful for enhanced PFOA removal from contaminated aqueous systems.<br></div>

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