Cooperative Bond Activation and Catalytic Reduction of Carbon Dioxide at a Group 13 Metal Center

2015 ◽  
Vol 127 (17) ◽  
pp. 5187-5191 ◽  
Author(s):  
Joseph A. B. Abdalla ◽  
Ian M. Riddlestone ◽  
Rémi Tirfoin ◽  
Simon Aldridge
Keyword(s):  
Carbon Dioxide ◽  
Bond Activation ◽  
Catalytic Reduction ◽  
Metal Center ◽  
Group 13

Cooperative Bond Activation and Catalytic Reduction of Carbon Dioxide at a Group 13 Metal Center

2015 ◽  
Vol 54 (17) ◽  
pp. 5098-5102 ◽  
Author(s):  
Joseph A. B. Abdalla ◽  
Ian M. Riddlestone ◽  
Rémi Tirfoin ◽  
Simon Aldridge
Keyword(s):  
Carbon Dioxide ◽  
Bond Activation ◽  
Catalytic Reduction ◽  
Metal Center ◽  
Group 13

Carbon Dioxide-Mediated C(sp2)–H Arylation of Primary and Secondary Benzylamines

2018 ◽  
Author(s):  
Mohit Kapoor ◽  
Pratibha Chand-Thakuri ◽  
Michael Young
Keyword(s):  
Carbon Dioxide ◽  
Transition Metal ◽  
Bond Activation ◽  
Bond Formation ◽  
Carbon Bond ◽  
Chelate Effect ◽  
Free Amine ◽  
Carbon Carbon Bond ◽  
New Strategy ◽  
Metal Catalyzed

Carbon-carbon bond formation by transition metal-catalyzed C–H activation has become an important strategy to fabricate new bonds in a rapid fashion. Despite the pharmacological importance of <i>ortho</i>-arylbenzylamines, however, effective <i>ortho</i>-C–C bond formation from C–H bond activation of free primary and secondary benzylamines using Pd<sup>II</sup> remains an outstanding challenge. Presented herein is a new strategy for constructing <i>ortho</i>-arylated primary and secondary benzylamines mediated by carbon dioxide (CO<sub>2</sub>). The use of CO<sub>2</sub> is critical to allowing this transformation to proceed under milder conditions than previously reported, and that are necessary to furnish free amine products that can be directly used or elaborated without the need for deprotection. In cases where diarylation is possible, a chelate effect is demonstrated to facilitate selective monoarylation.

Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide

2021 ◽  
Author(s):  
Zuozhong Liang ◽  
Hong-Yan Wang ◽  
Haoquan Zheng ◽  
Wei Zhang ◽  
Rui Cao
Keyword(s):  
Carbon Dioxide ◽  
Recent Progress ◽  
Catalytic Reduction ◽  
Storage Technologies ◽  
Conversion Technologies ◽  
And Storage

The recent progress made on porphyrin-based frameworks and their applications in energy-related conversion technologies (e.g., ORR, OER and CO2RR) and storage technologies (e.g., Zn–air batteries).

The catalytic reduction of carbon dioxide to carbon onion particles by platinum catalysts

Carbon ◽  
2005 ◽  
Vol 43 (12) ◽  
pp. 2621-2624 ◽  
Author(s):  
Marco G. Crestani ◽  
Ivan Puente-Lee ◽  
Luis Rendón-Vazquez ◽  
Patricia Santiago ◽  
Federico del Rio ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Reduction ◽  
Platinum Catalysts ◽  
Carbon Onion

Catalytic Reduction of Carbon Dioxide by Lower Alkanes

1994 ◽  
pp. 74-81
Author(s):  
T. Hattori ◽  
S. Yamauchi ◽  
M. Endo ◽  
S. Komai ◽  
A. Satsuma ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Reduction

Fixation of Carbon Dioxide to Carbon by Catalytic Reduction over Metal Oxides

1991 ◽  
Vol 20 (12) ◽  
pp. 2237-2240 ◽  
Author(s):  
Tatsumi Ishihara ◽  
Takanori Fujita ◽  
Yukako Mizuhara ◽  
Yusaku Takita
Keyword(s):  
Carbon Dioxide ◽  
Metal Oxides ◽  
Catalytic Reduction ◽  
Fixation Of Carbon Dioxide

Trapping Formaldehyde in the Homogeneous Catalytic Reduction of Carbon Dioxide

2013 ◽  
Vol 52 (39) ◽  
pp. 10253-10255 ◽  
Author(s):  
Sébastien Bontemps ◽  
Sylviane Sabo-Etienne
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Reduction

Oxide-Zeolite Composite Catalyst for Catalytic Reduction of Carbon Dioxide by Propane

Ecomaterials ◽  
1994 ◽  
pp. 341-344
Author(s):  
Syoichi Yamauchi ◽  
Shin'ichi Komai ◽  
Atsushi Satsuma ◽  
Tadashi Hattori ◽  
Yuichi Murakami
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Reduction ◽  
Composite Catalyst ◽  
Zeolite Composite
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