A Two-in-one Pincer Ligand and its Diiron(II) Complex Showing Spin State Switching in Solution through Reversible Ligand Exchange

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The synthesis of the NH2-MIL-101(Al) Metal–Organic Framework (MOF) with bis(hydrotris(pyrazolyl)borato)iron(ii), [Fe(HB(pz)3)2], added to the reaction medium yielded [Fe(HB(pz)3)2]@NH2-MIL101(Al) encapsulation products, denoted as S@Ms, in the course of a ‘bottle-around-the-ship’ assembly.


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