Autoamplification of Molecular Chirality through the Induction of Supramolecular Chirality

2014 ◽  
Vol 126 (20) ◽  
pp. 5173-5177 ◽  
Author(s):  
Derk Jan van Dijken ◽  
John M. Beierle ◽  
Marc C. A. Stuart ◽  
Wiktor Szymański ◽  
Wesley R. Browne ◽  
...  
Keyword(s):  
Molecular Chirality ◽  
Supramolecular Chirality

scholarly journals Advances in Chirality Sensing with Macrocyclic Molecules

Chemosensors ◽  
2021 ◽  
Vol 9 (10) ◽  
pp. 279
Author(s):  
Xiaotong Liang ◽  
Wenting Liang ◽  
Pengyue Jin ◽  
Hongtao Wang ◽  
Wanhua Wu ◽  
...  
Keyword(s):  
High Throughput ◽  
Absolute Configuration ◽  
Chemical Sensors ◽  
Organic Molecules ◽  
Macrocyclic Compounds ◽  
Rapid Progress ◽  
Molecular Chirality ◽  
Supramolecular Chirality ◽  
Signal Output ◽  
Macrocyclic Molecules

The construction of chemical sensors that can distinguish molecular chirality has attracted increasing attention in recent years due to the significance of chiral organic molecules and the importance of detecting their absolute configuration and chiroptical purity. The supramolecular chirality sensing strategy has shown promising potential due to its advantages of high throughput, sensitivity, and fast chirality detection. This review focuses on chirality sensors based on macrocyclic compounds. Macrocyclic chirality sensors usually have inherent complexing ability towards certain chiral guests, which combined with the signal output components, could offer many unique advantages/properties compared to traditional chiral sensors. Chirality sensing based on macrocyclic sensors has shown rapid progress in recent years. This review summarizes recent advances in chirality sensing based on both achiral and chiral macrocyclic compounds, especially newly emerged macrocyclic molecules.

Enantiomeric guests with the same signs of chiral optical responses

2014 ◽  
Vol 50 (60) ◽  
pp. 8185-8188 ◽  
Author(s):  
Paola Rizzo ◽  
Eugenia Lepera ◽  
Gaetano Guerra
Keyword(s):  
Molecular Chirality ◽  
Supramolecular Chirality ◽  
Optical Responses ◽  
Crystalline Films ◽  
Polymer Host

The chiral response of non-racemic molecules, being guests of s-PS co-crystalline films, does not depend on their R or S molecular chirality but essentially only on the polymer host supramolecular chirality.

Chiral signs of TPPS co-assemblies with chiral gelators: role of molecular and supramolecular chirality

2016 ◽  
Vol 52 (84) ◽  
pp. 12434-12437 ◽  
Author(s):  
Qiuling Wang ◽  
Li Zhang ◽  
Dong Yang ◽  
Tiesheng Li ◽  
Minghua Liu
Keyword(s):  
Chiral Molecules ◽  
Molecular Chirality ◽  
Supramolecular Chirality ◽  
J Aggregates

The chirality of TPPS J aggregates followed the supramolecular chirality of assemblies from chiral molecules rather than the molecular chirality.

Autoamplification of Molecular Chirality through the Induction of Supramolecular Chirality

2014 ◽  
pp. n/a-n/a ◽  
Author(s):  
Derk Jan van Dijken ◽  
John M. Beierle ◽  
Marc C. A. Stuart ◽  
Wiktor Szymański ◽  
Wesley R. Browne ◽  
...  
Keyword(s):  
Molecular Chirality ◽  
Supramolecular Chirality

Is Molecular Chirality Connected to Supramolecular Chirality? The Particular Case of Chiral 2-Pyridyl Alcohols

2015 ◽  
Vol 15 (2) ◽  
pp. 935-945 ◽  
Author(s):  
Min Ying Tsang ◽  
Florencia Di Salvo ◽  
Francesc Teixidor ◽  
Clara Viñas ◽  
José Giner Planas ◽  
...  
Keyword(s):  
Molecular Chirality ◽  
Supramolecular Chirality ◽  
Pyridyl Alcohols

Self-Assembly of a Chiral Cubic Three-Connected Net from the High Symmetry Molecules C60 and SnI4

2020 ◽  
Author(s):  
Daniel B. Straus ◽  
Robert J. Cava
Keyword(s):  
Organic Synthesis ◽  
Self Assembly ◽  
Van Der Waals ◽  
Van Der Waals Forces ◽  
High Symmetry ◽  
Molecular Chirality ◽  
Chiral Materials ◽  
Self Assembled ◽  
Chiral Centers

The design of new chiral materials usually requires stereoselective organic synthesis to create molecules with chiral centers. Less commonly, achiral molecules can self-assemble into chiral materials, despite the absence of intrinsic molecular chirality. Here, we demonstrate the assembly of high-symmetry molecules into a chiral van der Waals structure by synthesizing crystals of C<sub>60</sub>(SnI<sub>4</sub>)<sub>2</sub> from icosahedral buckminsterfullerene (C<sub>60</sub>) and tetrahedral SnI4 molecules through spontaneous self-assembly. The SnI<sub>4</sub> tetrahedra template the Sn atoms into a chiral cubic three-connected net of the SrSi<sub>2</sub> type that is held together by van der Waals forces. Our results represent the remarkable emergence of a self-assembled chiral material from two of the most highly symmetric molecules, demonstrating that almost any molecular, nanocrystalline, or engineered precursor can be considered when designing chiral assemblies.

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