Salicylate‐Directed C−O Bond Cleavage: Iron‐Catalyzed Allylic Substitution with Grignard Reagents

2018 ◽  
Vol 7 (5) ◽  
pp. 914-917 ◽  
Author(s):  
Enlu Ma ◽  
Yifan Jiang ◽  
Yuanjin Chen ◽  
Longying Qi ◽  
Xiaoyu Yan ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Grignard Reagents ◽  
Allylic Substitution

ChemInform Abstract: Fe-Promoted Cross Coupling of Homobenzylic Methyl Ethers with Grignard Reagents via sp3C-O Bond Cleavage.

ChemInform ◽  
2013 ◽  
Vol 44 (52) ◽  
pp. no-no
Author(s):  
Shuang Luo ◽  
Da-Gang Yu ◽  
Ru-Yi Zhu ◽  
Xin Wang ◽  
Lei Wang ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Cross Coupling ◽  
Grignard Reagents

ChemInform Abstract: Nickel-Catalyzed Cross-Coupling of Anisoles with Alkyl Grignard Reagents via C-O Bond Cleavage.

ChemInform ◽  
2016 ◽  
Vol 47 (4) ◽  
pp. no-no
Author(s):  
Mamoru Tobisu ◽  
Tsuyoshi Takahira ◽  
Naoto Chatani
Keyword(s):  
Bond Cleavage ◽  
Cross Coupling ◽  
Grignard Reagents

Sequential Copper-Catalyzed Rearrangement-Allylic Substitution of Bicyclic Hydrazines with Grignard Reagents

2009 ◽  
Vol 351 (6) ◽  
pp. 869-873 ◽  
Author(s):  
Stefano Crotti ◽  
Ferruccio Bertolini ◽  
Franco Macchia ◽  
Mauro Pineschi
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution

scholarly journals Allylic Substitution Reactions with Grignard Reagents Catalyzed by Imidazolium and 4,5-Dihydroimidazolium Carbene—CuCl Complexes.

ChemInform ◽  
2006 ◽  
Vol 37 (29) ◽  
Author(s):  
Sentaro Okamoto ◽  
Satoshi Tominaga ◽  
Naoko Saino ◽  
Kouki Kase ◽  
Kentaro Shimoda
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution ◽  
Substitution Reactions

Chemoselective Synthesis of Aryl Ketones from Amides and Grignard Reagents via C(O)–N Bond Cleavage under Catalyst-Free Conditions

2019 ◽  
Vol 84 (18) ◽  
pp. 11823-11838 ◽  
Author(s):  
Popuri Sureshbabu ◽  
Sadaf Azeez ◽  
Nalluchamy Muniyappan ◽  
Shahulhameed Sabiah ◽  
Jeyakumar Kandasamy
Keyword(s):  
Bond Cleavage ◽  
Grignard Reagents ◽  
Catalyst Free ◽  
Chemoselective Synthesis ◽  
Aryl Ketones

Carbon–Carbon Bond Formation of Trifluoroacetyl Amides with Grignard Reagents via C(O)–CF3 Bond Cleavage

2019 ◽  
Vol 84 (9) ◽  
pp. 5635-5644 ◽  
Author(s):  
Longzhi Zhu ◽  
Liyuan Le ◽  
Mingpan Yan ◽  
Chak-Tong Au ◽  
Renhua Qiu ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Bond Formation ◽  
Grignard Reagents ◽  
Carbon Bond ◽  
Carbon Carbon Bond

Iron-Catalyzed Grignard Cross-Couplings with Allylic Methyl Ethers or Allylic Trimethylsilyl Ethers

Synlett ◽  
2018 ◽  
Vol 29 (09) ◽  
pp. 1211-1214 ◽  
Author(s):  
Chika Seto ◽  
Takeshi Otsuka ◽  
Yoshiki Takeuchi ◽  
Daichi Tabuchi ◽  
Takashi Nagano
Keyword(s):  
Cross Coupling ◽  
Grignard Reagents ◽  
Allylic Substitution ◽  
Trimethylsilyl Ethers

We have found that cross-coupling between aryl Grignard reagents and allylic methyl ethers proceeded well in the presence of a catalytic amounts of Fe(acac)3 to afford the corresponding allylic substitution products in good yields. Under the same conditions, allylic trimethylsilyl ethers also reacted with Grignard reagents to give the corresponding cross-coupling products.

scholarly journals Intramolecular C–F and C–H bond cleavage promoted by butadienyl heavy Grignard reagents

2014 ◽  
Vol 5 (1) ◽  
Author(s):  
Heng Li ◽  
Xiao-Ye Wang ◽  
Baosheng Wei ◽  
Ling Xu ◽  
Wen-Xiong Zhang ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Grignard Reagents

New General Method for Regio- and Stereoselective Allylic Substitution with Aryl and Alkenyl Coppers Derived from Grignard Reagents

2009 ◽  
Vol 74 (5) ◽  
pp. 1939-1951 ◽  
Author(s):  
Yohei Kiyotsuka ◽  
Yuji Katayama ◽  
Hukum P. Acharya ◽  
Tomonori Hyodo ◽  
Yuichi Kobayashi
Keyword(s):  
Grignard Reagents ◽  
Allylic Substitution ◽  
General Method
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