Copper-Free Sonogashira Coupling Reaction Catalyzed by PVC-Supported Triazine Palladium(II) Complex Under Aerobic Conditions

2014 ◽  
Vol 3 (11) ◽  
pp. 1189-1192 ◽  
Author(s):  
Mohammad Bakherad ◽  
Ali Keivanloo ◽  
Amene Hadi ◽  
Maesoume Siavoshi
Keyword(s):  
Coupling Reaction ◽  
Sonogashira Coupling ◽  
Aerobic Conditions ◽  
Sonogashira Coupling Reaction

A coordination driven self-assembled Pd6L8 nanoball catalyses copper and phosphine-free Sonogashira coupling reaction in both homogeneous and heterogeneous formats

2016 ◽  
Vol 40 (8) ◽  
pp. 7140-7147 ◽  
Author(s):  
Subhashis Pradhan ◽  
Subhadip Dutta ◽  
Rohith P. John
Keyword(s):  
Aqueous Medium ◽  
Coupling Reaction ◽  
Sonogashira Reaction ◽  
Catalyst Loading ◽  
Sonogashira Coupling ◽  
Aerobic Conditions ◽  
Homogeneous Phase ◽  
Sonogashira Coupling Reaction ◽  
Self Assembled ◽  
Heterogeneous Phase

A self-assembled Pd6L8 nanocage catalysed copper free Sonogashira reaction under mild and aerobic conditions, at 100 ppm catalyst loading in aqueous medium in the homogeneous phase, and at 500 ppm in the heterogeneous phase.

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