Decrease in solvent evaporation rate due to phase separation in polymer films

AIChE Journal ◽  
2002 ◽  
Vol 48 (11) ◽  
pp. 2711-2714 ◽  
Author(s):  
Masato Yamamura ◽  
Kouhei Horiuchi ◽  
Toshihisa Kajiwara ◽  
Kitaro Adachi
Keyword(s):  
Phase Separation ◽  
Polymer Films ◽  
Evaporation Rate ◽  
Solvent Evaporation

The Influence of the Solvent Evaporation Rate on the Phase Separation and Electrical Performances of Soluble Acene-Polymer Blend Semiconductors

2011 ◽  
Vol 22 (2) ◽  
pp. 267-281 ◽  
Author(s):  
Wi Hyoung Lee ◽  
Donghoon Kwak ◽  
John E. Anthony ◽  
Hwa Sung Lee ◽  
Hyun Ho Choi ◽  
...  
Keyword(s):  
Phase Separation ◽  
Polymer Blend ◽  
Evaporation Rate ◽  
Solvent Evaporation

Force modulation microscopy study of phase separation on blend polymer films

1999 ◽  
Vol 74 (19) ◽  
pp. 2785-2787 ◽  
Author(s):  
Heh-Nan Lin ◽  
Tien-Tsan Hung ◽  
En-Chung Chang ◽  
Show-An Chen
Keyword(s):  
Phase Separation ◽  
Polymer Films ◽  
Microscopy Study ◽  
Force Modulation ◽  
Blend Polymer

scholarly journals Evaporation-Induced Crystal Nucleation and Morphology of Dried Poly(Vinylidene Fluoride) Droplets

Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1442
Author(s):  
Yongri Liang ◽  
Susu Wang
Keyword(s):  
Droplet Size ◽  
Evaporation Rate ◽  
Vinylidene Fluoride ◽  
Grazing Incidence ◽  
Solvent Evaporation ◽  
Crystal Nucleation ◽  
Coffee Ring ◽  
Poly Vinylidene Fluoride ◽  
Coffee Ring Effect ◽  
Ring Effect

The evaporation of a polymer solution droplet is important in solution-based polymer film fabrications, such as inkjet printing, spray coatings, and droplet casting, etc. In this work, we investigated the effect of droplet size, solvent evaporation rate, and concentration on the “coffee-ring” effect, crystal nucleation, polymorphism, and morphology of dried poly (vinylidene fluoride) (PVDF) solution droplets with the atomic force microscopy (AFM) and two-dimensional grazing incidence wide angle X-ray scattering (2D GIWAXS) method. We found that the crystal structure, morphology and crystal distribution in the center and edge regions of dried PVDF droplets were different due to the “coffee-ring” effect. The “coffee-ring” effect of dried PVDF droplets was mainly composited of accumulated crystals at the edge region of a droplet, which was mainly made by the crystallization of migrated chains. The interplay between the migration of chains and the crystallization and solidification of PVDF droplets significantly influenced the formation of the “coffee-ring”. In addition, our results showed that the decrease in droplet size and the controlling solvent evaporation rate were effective ways to improve the electroactive crystalline phases (β and γ-phases) nucleation and decrease the crystal size.

Evaporation-induced pattern formation in polymer films via secondary phase separation

2002 ◽  
Vol 57 (15) ◽  
pp. 2901-2905 ◽  
Author(s):  
Masato Yamamura ◽  
Takatoshi Nishio ◽  
Toshihisa Kajiwara ◽  
Kitaro Adachi
Keyword(s):  
Phase Separation ◽  
Pattern Formation ◽  
Polymer Films ◽  
Secondary Phase ◽  
Secondary Phase Separation

Preparation of porous polylactide microspheres by emulsion-solvent evaporation based on solution induced phase separation

2005 ◽  
Vol 16 (8) ◽  
pp. 622-627 ◽  
Author(s):  
Yi Hong ◽  
Changyou Gao ◽  
Yanchao Shi ◽  
Jiacong Shen
Keyword(s):  
Phase Separation ◽  
Solvent Evaporation

Manufacturing of Porous Polydimethylsiloxane (PDMS) Plates Using Solvent Evaporation Induced Phase Separation Technique

2021 ◽  
Author(s):  
Mohammad Abshirini ◽  
M. Cengiz Altan ◽  
Yingtao Liu ◽  
Mrinal Saha ◽  
Laura Cummings ◽  
...  
Keyword(s):  
Phase Separation ◽  
Solvent Evaporation ◽  
Separation Technique

scholarly journals Tailoring pore distribution in polymer films via evaporation induced phase separation

RSC Advances ◽  
2019 ◽  
Vol 9 (27) ◽  
pp. 15593-15605 ◽  
Author(s):  
Rumiaya Pervin ◽  
Pijush Ghosh ◽  
Madivala G. Basavaraj
Keyword(s):  
Phase Separation ◽  
Polymer Films ◽  
Pore Distribution ◽  
Porous Polymer ◽  
Fundamental Understanding

The work contributes to a fundamental understanding of how to regulate the microstructure of porous polymer films fabricated via evaporation induced phase separation (EIPS).

Controlling Ordered Structures of PS-b-P2VP Block Copolymer Thin Film by Tuning Solvent Evaporation Rate

2017 ◽  
Vol 371 (1) ◽  
pp. 75-83 ◽  
Author(s):  
Siti Aisyah Shamsudin ◽  
Takenaka Mikihito ◽  
Hasegawa Hirokazu
Keyword(s):  
Thin Film ◽  
Block Copolymer ◽  
Evaporation Rate ◽  
Solvent Evaporation ◽  
Ordered Structures
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