scholarly journals Relation between Interfacial Band-Bending and Electronic Properties in Organic Semiconductor Pentacene

2017 ◽  
Vol 3 (11) ◽  
pp. 1700136 ◽  
Author(s):  
Panlong Zhang ◽  
Shuai Zhao ◽  
Haibo Wang ◽  
Jidong Zhang ◽  
Jianwu Shi ◽  
...  
1992 ◽  
Vol 260 ◽  
Author(s):  
L. J. Brillson ◽  
I. M. Vitomirov ◽  
A. Raisanen ◽  
S. Chang ◽  
R. E. Viturro ◽  
...  

ABSTRACTThe influence of metallization and processing on Schottky barrier formation provides the basis for one of several fruitful approaches for controlling junction electronic properties. Interface cathodo-and photoluminescence measurements reveal that electrically-active deep levels form on GaAs(100) surfaces and metal interfaces which depend on thermally-driven surface stoichiometry and reconstruction, chemical interaction, as well as surface misorientation and bulk crystal quality. These interface states are discrete and occur at multiple gap energies which can account for observed band bending. Characteristic trends in such deep level emission with interface processing provide guides for optimizing interface electronic behavior. Correspondingly, photoemission and internal photoemission spectroscopy measurements indicate self-consistent changes in barrier heights which may be heterogeneous and attributable to interface chemical reactions observed on a monolayer scale. These results highlight the multiple roles of atomic-scale structure in forming macroscopic electronic properties of compound semiconductor-metal junctions.


2005 ◽  
Vol 252 (1) ◽  
pp. 143-147 ◽  
Author(s):  
O.V. Molodtsova ◽  
T. Schwieger ◽  
M. Knupfer

2001 ◽  
Vol 668 ◽  
Author(s):  
D. Kraft ◽  
A. Thiβen ◽  
M. Campo ◽  
M. Beerbom ◽  
T. Mayer ◽  
...  

ABSTRACTImprovement of electric back contact formation is one of the major issues of the CdTe thin film solar cell research. Chemical etching of CdTe before metallization is accepted to improve contact formation. It is believed that a CdTe/Te contact is formed by this procedure leading to a Fermi level position in the CdTe close to the valence band maximum for low contact resistance. We have studied the electronic properties of chemically etched CdTe surfaces with photoelectron spectroscopy. Etching of the samples was performed in air (“ex-situ“) as well as in an electrochemical setup directly attached to the UHV system (“in-situ“). The formation of a Te layer is clearly shown by (S)XPS. In contrast to previous studies we could not detect the formation of a p-CdTe surface for different experimental conditions. The detected Fermi level position indicates still band bending and hence a blocking Schottky barrier.


1996 ◽  
Vol 54 (19) ◽  
pp. 13748-13758 ◽  
Author(s):  
Y. Hirose ◽  
A. Kahn ◽  
V. Aristov ◽  
P. Soukiassian ◽  
V. Bulovic ◽  
...  

2007 ◽  
Vol 90 (21) ◽  
pp. 212112 ◽  
Author(s):  
Andreas Opitz ◽  
Markus Bronner ◽  
Wolfgang Brütting ◽  
Marcel Himmerlich ◽  
Juergen A. Schaefer ◽  
...  

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Teng-Xiang Huang ◽  
Xin Cong ◽  
Si-Si Wu ◽  
Kai-Qiang Lin ◽  
Xu Yao ◽  
...  

AbstractDefects can induce drastic changes of the electronic properties of two-dimensional transition metal dichalcogenides and influence their applications. It is still a great challenge to characterize small defects and correlate their structures with properties. Here, we show that tip-enhanced Raman spectroscopy (TERS) can obtain distinctly different Raman features of edge defects in atomically thin MoS2, which allows us to probe their unique electronic properties and identify defect types (e.g., armchair and zigzag edges) in ambient. We observed an edge-induced Raman peak (396 cm−1) activated by the double resonance Raman scattering (DRRS) process and revealed electron–phonon interaction in edges. We further visualize the edge-induced band bending region by using this DRRS peak and electronic transition region using the electron density-sensitive Raman peak at 406 cm−1. The power of TERS demonstrated in MoS2 can also be extended to other 2D materials, which may guide the defect engineering for desired properties.


2019 ◽  
Vol 94 (8) ◽  
pp. 1153-1167 ◽  
Author(s):  
K Eswar Srikanth ◽  
K Ramaiah ◽  
D Jagadeeswara Rao ◽  
K. Prabhakara Rao ◽  
J Laxman Naik ◽  
...  

1998 ◽  
Vol 73 (8) ◽  
pp. 1026-1028 ◽  
Author(s):  
R. Schlaf ◽  
B. A. Parkinson ◽  
P. A. Lee ◽  
K. W. Nebesny ◽  
N. R. Armstrong

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