scholarly journals In Situ RheoNMR Correlation of Polymer Segmental Mobility with Mechanical Properties during Hydrogel Synthesis

2021 ◽  
pp. 2104231
Author(s):  
Christian Fengler ◽  
Jonas Keller ◽  
Karl‐Friedrich Ratzsch ◽  
Manfred Wilhelm
Keyword(s):  
Mechanical Properties ◽  
Segmental Mobility ◽  
Hydrogel Synthesis

Dynamics of Nanoparticle Chain Aggregates of Carbon Under Tension

2003 ◽  
Vol 778 ◽  
Author(s):  
Rajdip Bandyopadhyaya ◽  
Weizhi Rong ◽  
Yong J. Suh ◽  
Sheldon K. Friedlander
Keyword(s):  
Mechanical Properties ◽  
Carbon Black ◽  
Polymer Film ◽  
Elastic Behavior ◽  
Small Strains ◽  
Transmission Electron ◽  
Chain Aggregates ◽  
Nanoparticle Chains ◽  
Reinforcing Filler

AbstractCarbon black in the form of nanoparticle chains is used as a reinforcing filler in elastomers. However, the dynamics of the filler particles under tension and their role in the improvement of the mechanical properties of rubber are not well understood. We have studied experimentally the dynamics of isolated nanoparticle chain aggregates (NCAs) of carbon made by laser ablation, and also that of carbon black embedded in a polymer film. In situ studies of stretching and contraction of such chains in the transmission electron microscope (TEM) were conducted under different maximum values of strain. Stretching causes initially folded NCA to reorganize into a straight, taut configuration. Further stretching leads to either plastic deformation and breakage (at 37.4% strain) or to a partial elastic behavior of the chain at small strains (e.g. 2.3% strain). For all cases the chains were very flexible under tension. Similar reorientation and stretching was observed for carbon black chains embedded in a polymer film. Such flexible and elastic nature of NCAs point towards a possible mechanism of reinforcement of rubber by carbon black fillers.

Effect of TiB2 particle addition on the mechanical properties of Al/TiB2 in situ formed metal matrix composites

2018 ◽  
Vol 60 (12) ◽  
pp. 1221-1224 ◽  
Author(s):  
Balachandran Gobalakrishnan ◽  
P. Ramadoss Lakshminarayanan ◽  
Raju Varahamoorthi
Keyword(s):  
Mechanical Properties ◽  
Metal Matrix Composites ◽  
Metal Matrix ◽  
Tib2 Particle ◽  
Matrix Composites ◽  
Particle Addition

A novel in-situ exothermic assisted sintering high entropy Al2O3/(NbTaMoW)C composites: Microstructure and mechanical properties

2021 ◽  
Vol 212 ◽  
pp. 108681
Author(s):  
Diqiang Liu ◽  
Aijun Zhang ◽  
Jiangang Jia ◽  
Jiesheng Han ◽  
Junyan Zhang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
High Entropy ◽  
Microstructure And Mechanical Properties

Tailoring martensitic transformation and mechanical properties of Ti–Ni composite reinforced by network structure of in-situ TiB and La2O3 phase

Vacuum ◽  
2021 ◽  
Vol 184 ◽  
pp. 109894 ◽  
Author(s):  
Xiaoyang Yi ◽  
Haizhen Wang ◽  
Kuishan Sun ◽  
Guijuan Shen ◽  
Xianglong Meng ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Martensitic Transformation ◽  
Network Structure
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