scholarly journals Highly Efficient Electrocatalytic N 2 Reduction to Ammonia over Metallic 1T Phase of MoS 2 Enabled by Active Sites Separation Mechanism

2021 ◽  
pp. 2103583
Author(s):  
Ruoqi Liu ◽  
Ting Guo ◽  
Hao Fei ◽  
Zhuangzhi Wu ◽  
Dezhi Wang ◽  
...  
2021 ◽  
Vol 9 (1) ◽  
pp. 482-491
Author(s):  
Jiakun Wu ◽  
Bowen Sun ◽  
Hui Wang ◽  
Yanyan Li ◽  
Ying Zuo ◽  
...  

Unique 2D heterostructures CdxZn1−xIn2S4–CdS–MoS2 with effective charge separation, excellent light-harvest, and abundant active sites are highly-efficient for photocatalytic H2 evolution.


2020 ◽  
Vol 59 (51) ◽  
pp. 22040-22048
Author(s):  
Xiaoqian Wan ◽  
Dandan Qian ◽  
Lunhong Ai ◽  
Jing Jiang

2021 ◽  
pp. 313-319
Author(s):  
Amir A. Rezaie ◽  
Eunsoo Lee ◽  
Diana Luong ◽  
Johan A. Yapo ◽  
Boniface P. T. Fokwa

Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 717
Author(s):  
Hassan Algadi ◽  
Ahmad Umar ◽  
Hasan Albargi ◽  
Turki Alsuwian ◽  
Sotirios Baskoutas

A low-cost and simple drop-casting method was used to fabricate a carbon nanodot (C-dot)/all-inorganic perovskite (CsPbBr3) nanosheet bilayer heterojunction photodetector on a SiO2/Si substrate. The C-dot/perovskite bilayer heterojunction photodetector shows a high performance with a responsivity (R) of 1.09 A/W, almost five times higher than that of a CsPbBr3-based photodetector (0.21 A/W). In addition, the hybrid photodetector exhibits a fast response speed of 1.318/1.342 µs and a highly stable photocurrent of 6.97 µA at 10 V bias voltage. These figures of merits are comparable with, or much better than, most reported perovskite heterojunction photodetectors. UV–Vis absorption and photoluminescent spectra measurements reveal that the C-dot/perovskite bilayer heterojunction has a band gap similar to the pure perovskite layer, confirming that the absorption and emission in the bilayer heterojunction is dominated by the top layer of the perovskite. Moreover, the emission intensity of the C-dot/perovskite bilayer heterojunction is less than that of the pure perovskite layer, indicating that a significant number of charges were extracted by the C-dot layer. The studied band alignment of the C-dots and perovskites in the dark and under emission reveals that the photodetector has a highly efficient charge separation mechanism at the C-dot/perovskite interface, where the recombination rate between photogenerated electrons and holes is significantly reduced. This highly efficient charge separation mechanism is the main reason behind the enhanced performance of the C-dot/perovskite bilayer heterojunction photodetector.


Author(s):  
Duc-Trung Nguyen ◽  
Anis Chouat ◽  
Trong-On Do

Herein, we demonstrate that 3-mercaptopropionate capping agents on CdS quantum dots' surface could serve as proton shutters and localize protons near the active sites toward an efficient photocatalytic CO2 reduction....


Nanoscale ◽  
2018 ◽  
Vol 10 (46) ◽  
pp. 21671-21680 ◽  
Author(s):  
Wenbin Li ◽  
Jianfeng Huang ◽  
Liangliang Feng ◽  
Liyun Cao ◽  
Shuwei He

The decreasing crystallinity of VS4 microspheres greatly increases the surface active sites, and then promotes the pseudocapacitive behavior, and finally leads to the high capacity, long cycling life and high rate capability.


2019 ◽  
Vol 131 (34) ◽  
pp. 11994-11999 ◽  
Author(s):  
Wei‐Hong Lai ◽  
Li‐Fu Zhang ◽  
Wei‐Bo Hua ◽  
Sylvio Indris ◽  
Zi‐Chao Yan ◽  
...  

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