Regio‐ and Stereoselective Synthesis of 3‐Pyrazolylidene‐2‐oxindole Compounds by Nucleophilic Vinylic Substitution of (
            E
            )‐3‐(Nitromethylene)indolin‐2‐one

Carlos Vila; Sophie Slack; Gonzalo Blay; M. Carmen Muñoz; José R. Pedro

doi:10.1002/adsc.201900048

Regio‐ and Stereoselective Synthesis of 3‐Pyrazolylidene‐2‐oxindole Compounds by Nucleophilic Vinylic Substitution of ( E )‐3‐(Nitromethylene)indolin‐2‐one

Advanced Synthesis & Catalysis ◽

10.1002/adsc.201900048 ◽

2019 ◽

Vol 361 (8) ◽

pp. 1902-1907 ◽

Cited By ~ 3

Author(s):

Carlos Vila ◽

Sophie Slack ◽

Gonzalo Blay ◽

M. Carmen Muñoz ◽

José R. Pedro

Keyword(s):

Stereoselective Synthesis ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text

Nucleophilic vinylic substitution in bicyclic methyleneaziridines: SNVπ or SNVσ?

New Journal of Chemistry ◽

10.1039/d1nj01458g ◽

2021 ◽

Author(s):

Vitalii Palchykov ◽

Peter C. Dale ◽

Jeremy Robertson

Keyword(s):

Ring Opening ◽

Stereoselective Synthesis ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

A stereoselective synthesis of the monodeuterated methyleneaziridine shown allowed the stereochemical course of formal SNV-mode ring-opening with copper-based organometallics to be assigned.

Download Full-text

Nucleophilic Vinylic Substitution in Perfluoroacylchromenes. Diastereoselective Synthesis of Push–Pull Enamino Ketones

Russian Journal of Organic Chemistry ◽

10.1134/s1070428021070046 ◽

2021 ◽

Vol 57 (7) ◽

pp. 1053-1062

Author(s):

V. A. Osyanin ◽

K. S. Korzhenko ◽

D. A. Rashchepkina ◽

D. V. Osipov ◽

Yu. N. Klimochkin

Keyword(s):

Diastereoselective Synthesis ◽

Enamino Ketones ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text

ChemInform Abstract: Synthesis and Reactivity of 3-Chloro-3-trifluoromethylacroleins: Stabilisation of the Tetrahedral Intermediate in a Nucleophilic Vinylic “Substitution”.

ChemInform ◽

10.1002/chin.199438050 ◽

2010 ◽

Vol 25 (38) ◽

pp. no-no

Author(s):

G. ALVERNHE ◽

D. GREIF ◽

B. LANGLOIS ◽

A. LAURENT ◽

I. LE DREAN ◽

...

Keyword(s):

Tetrahedral Intermediate ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text

Organocatalytic Enantioselective Nucleophilic Vinylic Substitution by α-Substituted-α-Cyanoacetates under Phase-Transfer Conditions

The Journal of Organic Chemistry ◽

10.1021/jo070024p ◽

2007 ◽

Vol 72 (8) ◽

pp. 3053-3056 ◽

Cited By ~ 30

Author(s):

Mark Bell ◽

Thomas B. Poulsen ◽

Karl Anker Jørgensen

Keyword(s):

Phase Transfer ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text

Kinetic Analysis of Elementary Steps in Nucleophilic Vinylic Substitution Reactions of .alpha.-Nitro-.beta.-X-stilbenes (X = OCH2CF3, OCH3, NO2) with Various Nucleophiles. Detection of the Intermediate in the Reaction of .alpha.-Nitro-.beta.-(2,2,2-trifluoroethoxy)stilbene with HOCH2CH2S- and of .beta.-Methoxy-.alpha.-nitrostilbene with CF3CH2O-

Journal of the American Chemical Society ◽

10.1021/ja00105a017 ◽

1994 ◽

Vol 116 (26) ◽

pp. 11764-11774 ◽

Cited By ~ 8

Author(s):

Claude F. Bernasconi ◽

David F. Schuck ◽

Rodney J. Ketner ◽

Minda Weiss ◽

Zvi Rappoport

Keyword(s):

Kinetic Analysis ◽

Substitution Reactions ◽

Elementary Steps ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text

Nucleophilic vinylic substitution. I. Synthesis and reactions of 2-substituted 3,3-dichloroacrylonitriles

The Journal of Organic Chemistry ◽

10.1021/jo00821a026 ◽

1971 ◽

Vol 36 (22) ◽

pp. 3386-3391 ◽

Cited By ~ 12

Author(s):

Robert L. Soulen ◽

David B. Clifford ◽

F. Fleming Crim ◽

Joann A. Johnston

Keyword(s):

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text

Nucleophilic vinylic substitution. A single- or a multi-step process?

Accounts of Chemical Research ◽

10.1021/ar00061a002 ◽

1981 ◽

Vol 14 (1) ◽

pp. 7-15 ◽

Cited By ~ 116

Author(s):

Zvi Rappoport

Keyword(s):

Step Process ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text

Organocatalytic Enantioselective Nucleophilic Vinylic Substitution by α-Substituted-α-cyanoacetates under Phase-Transfer Conditions.

ChemInform ◽

10.1002/chin.200735092 ◽

2007 ◽

Vol 38 (35) ◽

Author(s):

Mark Bell ◽

Thomas B. Poulsen ◽

Karl Anker Joergensen

Keyword(s):

Phase Transfer ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text

Synthesis of Functionalized β-Amino α,β-Unsaturated Esters and Nitriles by Nucleophilic Vinylic Substitution

Synthesis ◽

10.1055/s-1988-27491 ◽

1988 ◽

Vol 1988 (02) ◽

pp. 136-138 ◽

Cited By ~ 13

Author(s):

Begoña de Ancos ◽

M. Carmen Maestro ◽

M. Rosario Martín ◽

Francisco Fariña

Keyword(s):

Unsaturated Esters ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text

Halogenophilic and classical Ad N E mechanisms in nucleophilic vinylic substitution reactions involving the anions of transition metal carbonyls

Theoretical and Experimental Chemistry ◽

10.1007/s11237-011-9165-2 ◽

2011 ◽

Vol 46 (6) ◽

pp. 350-358 ◽

Cited By ~ 5

Author(s):

P. K. Sazonov ◽

G. A. Artamkina ◽

I. P. Beletskaya

Keyword(s):

Transition Metal ◽

Metal Carbonyls ◽

Substitution Reactions ◽

Transition Metal Carbonyls ◽

Nucleophilic Vinylic Substitution ◽

Vinylic Substitution

Download Full-text