Reduction of Amides to Amines under Mild Conditions via Catalytic Hydrogenation of Amide Acetals and Imidates

2018 ◽  
Vol 361 (1) ◽  
pp. 185-191 ◽  
Author(s):  
Renat Kadyrov
Keyword(s):  
Catalytic Hydrogenation ◽  
Mild Conditions ◽  
Amide Acetals

Selective hydrogenation of nitroarenes under mild conditions by the optimization of active sites in a well defined Co@NC catalyst

2020 ◽  
Vol 22 (17) ◽  
pp. 5730-5741
Author(s):  
Shuo Chen ◽  
Li-Li Ling ◽  
Shun-Feng Jiang ◽  
Hong Jiang
Keyword(s):  
Particle Size ◽  
Catalytic Hydrogenation ◽  
Selective Hydrogenation ◽  
Active Sites ◽  
Metal Organic Framework ◽  
Nitro Compounds ◽  
Active Species ◽  
Mild Conditions ◽  
Metal Organic ◽  
Aromatic Nitro

The defined catalyst (Co@NC) is prepared through the pyrolysis of the Co-centered metal–organic framework (MOF), in which Co active species (Co–Nx, surface Co NPs) and particle size play important roles in the catalytic hydrogenation of aromatic nitro compounds.

scholarly journals Two-step conversion of Kraft lignin to nylon precursors under mild conditions

2020 ◽  
Vol 22 (14) ◽  
pp. 4676-4682 ◽  
Author(s):  
Hui Zhou ◽  
Hsin Wang ◽  
Frédéric A. Perras ◽  
Pranjali Naik ◽  
Marek Pruski ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Ambient Pressure ◽  
Kraft Lignin ◽  
High Demand ◽  
Mild Conditions ◽  
Aqueous Base

Treatment of Kraft lignin, massive byproduct of pulping industry, with dilute aqueous base followed by catalytic hydrogenation of the extracted monomers at ambient pressure yields KA oil, the precursor of high demand nylon polymer.

Selective catalytic hydrogenation of polycyclic aromatic hydrocarbons promoted by ruthenium nanoparticles

2015 ◽  
Vol 5 (5) ◽  
pp. 2741-2751 ◽  
Author(s):  
Emma Bresó-Femenia ◽  
Bruno Chaudret ◽  
Sergio Castillón
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Catalytic Hydrogenation ◽  
Ruthenium Nanoparticles ◽  
Mild Conditions ◽  
Polycyclic Aromatic

Naphthalene, anthracene, triphenylene and pyrene were partially hydrogenated with selectivities between 80% and 100% under mild conditions using ruthenium NPs.

Notizen: Homogene katalytische Hydrierung ungesättigter Carbonsäureester mit H2PtCl6 + SnCl2 in iso-Butanol / Homogeneous Catalytic Hydrogenation of Unsaturated Carboxylic Acid Esters with H2PtCl6 + SnCl2 in iso-Butanol

1977 ◽  
Vol 32 (5) ◽  
pp. 597-598 ◽  
Author(s):  
Walter Strohmeier ◽  
Luise Weigelt
Keyword(s):  
Carboxylic Acid ◽  
Catalytic Hydrogenation ◽  
Reaction Rates ◽  
Homogeneous Hydrogenation ◽  
Unsaturated Esters ◽  
Mild Conditions ◽  
Unsaturated Carboxylic Acid ◽  
Acid Esters

The catalytical system, prepared from H2PtCl6 + SnCl2 · 2 H2O and the additives HBr and H2O in iso-butanol is very efficient for homogeneous hydrogenation of unsaturated esters under mild conditions. Reaction rates r up to 40 mMol · 1-1 · min-1 and turnover numbers UZ higher than 1.600 are observed.

Titanium-Mediated Catalytic Hydrogenation of Monocyclic and Polycyclic Arenes

2019 ◽  
Author(s):  
Alejandra Gomez-Torres ◽  
J. Rolando Aguilar-Calderón ◽  
Angela M. Encerrado-Manriquez ◽  
Maren Pink ◽  
Alejandro J. Metta-Magaña ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Group Iv ◽  
Mild Conditions ◽  
Arene Hydrogenation ◽  
Electron Reduction

<p>Two electron-reduction of the Ti(IV) guanidinate complex (Im<sup>Dipp</sup>N)(<sup>Xyket</sup>guan)TiCl<sub>2</sub> gives (η<sup>6</sup>-Im<sup>Dipp</sup>N)(<sup>xyket</sup>guan)Ti (1<sup>intra</sup>) and (Im<sup>Dipp</sup>N)(<sup>Xyket</sup>guan)Ti(η<sup>6</sup>-C<sub>6</sub>H<sub>6</sub>) (1<sup>inter</sup>) (<sup>xyket</sup>guan = [(<sup>t</sup>BuC=N)C(NXylyl)<sub>2</sub>]<sup>-</sup>, Xylyl = 2,5-dimethylphenyl) in the absence or presence of benzene, respectively. These complexes have been found to hydrogenate monocyclic and polycyclic arenes under relatively mild conditions (150 psi, 80 °C) – the first example of catalytic, homogeneous arene hydrogenation with TON > 1 by a Group IV system.</p>

ChemInform Abstract: A Highly Efficient Pd—C Catalytic Hydrogenation of Pyridine Nucleus under Mild Conditions.

ChemInform ◽  
2010 ◽  
Vol 41 (5) ◽  
Author(s):  
Chuanjie Cheng ◽  
Jimin Xu ◽  
Rui Zhu ◽  
Lixin Xing ◽  
Xinyan Wang ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Mild Conditions ◽  
Highly Efficient

Catalytic Hydrogenation of Amides to Amines under Mild Conditions

2012 ◽  
Vol 125 (8) ◽  
pp. 2287-2290 ◽  
Author(s):  
Mario Stein ◽  
Bernhard Breit
Keyword(s):  
Catalytic Hydrogenation ◽  
Mild Conditions
Sign in / Sign up

Export Citation Format

Share Document