Selective hydrogenation of nitroarenes under mild conditions by the optimization of active sites in a well defined Co@NC catalyst

2020 ◽  
Vol 22 (17) ◽  
pp. 5730-5741
Author(s):  
Shuo Chen ◽  
Li-Li Ling ◽  
Shun-Feng Jiang ◽  
Hong Jiang
Keyword(s):  
Particle Size ◽  
Catalytic Hydrogenation ◽  
Selective Hydrogenation ◽  
Active Sites ◽  
Metal Organic Framework ◽  
Nitro Compounds ◽  
Active Species ◽  
Mild Conditions ◽  
Metal Organic ◽  
Aromatic Nitro

The defined catalyst (Co@NC) is prepared through the pyrolysis of the Co-centered metal–organic framework (MOF), in which Co active species (Co–Nx, surface Co NPs) and particle size play important roles in the catalytic hydrogenation of aromatic nitro compounds.

One-pot synthesis of Ni–NiFe2O4/carbon nanofiber composites from biomass for selective hydrogenation of aromatic nitro compounds

2015 ◽  
Vol 17 (2) ◽  
pp. 821-826 ◽  
Author(s):  
Wu-Jun Liu ◽  
Ke Tian ◽  
Hong Jiang
Keyword(s):  
Catalytic Hydrogenation ◽  
Selective Hydrogenation ◽  
Carbon Nanofiber ◽  
Fast Pyrolysis ◽  
Nitro Compounds ◽  
One Pot ◽  
Aromatic Nitro Compounds ◽  
One Pot Synthesis ◽  
Aromatic Nitro

Ni–NiFe2O4/carbon nanofiber composites with a favourable performance in catalytic hydrogenation were synthesized by fast pyrolysis of FeCl3 and NiCl2 preloaded biomass.

The ionic liquid microphase enhances the catalytic activity of Pd nanoparticles supported by a metal–organic framework

2015 ◽  
Vol 17 (8) ◽  
pp. 4178-4182 ◽  
Author(s):  
Li Peng ◽  
Jianling Zhang ◽  
Shuliang Yang ◽  
Buxing Han ◽  
Xinxin Sang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Liquid Metal ◽  
Selective Hydrogenation ◽  
Metal Organic Framework ◽  
Pd Nanoparticles ◽  
Mild Conditions ◽  
Metal Organic ◽  
Organic Framework

Here a Pd/ionic liquid/metal–organic framework catalyst is developed, which shows high activities in catalyzing the selective hydrogenation of alkynes under mild conditions.

Highly Efficient Hydrogenation Reduction of Aromatic Nitro Compounds using MOF Derivative Co-N/C Catalyst

2021 ◽  
Author(s):  
Yuyu Dai ◽  
Xiaoqing Li ◽  
Likai Wang ◽  
Xiangsheng Xu
Keyword(s):  
Aromatic Amines ◽  
Noble Metals ◽  
Metal Organic Framework ◽  
Nitro Compounds ◽  
Highly Efficient ◽  
Aromatic Nitro Compounds ◽  
Metal Organic ◽  
Aromatic Nitro ◽  
Direct Hydrogenation ◽  
Organic Framework

The direct hydrogenation reduction of aromatic nitro compounds to aromatic amines with the non-noble metals is an attractive area. Herein, the pyrolysis of Co(2-methylimidazole)2 metal-organic framework successfully produces a magnetic...

Immobilization of Rh(i) precursor in a porphyrin metal–organic framework – turning on the catalytic activity

2021 ◽  
Author(s):  
Anna M. Szczepkowska ◽  
Mateusz Janeta ◽  
Miłosz Siczek ◽  
Włodzimierz Tylus ◽  
Anna M. Trzeciak ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Catalytic Hydrogenation ◽  
Metal Organic Framework ◽  
Unsaturated Hydrocarbons ◽  
Mild Conditions ◽  
Metal Organic ◽  
Organic Framework

Installation of rhodium centers in a stable porphyrin-based ZrMOF platform for catalytic hydrogenation of unsaturated hydrocarbons under mild conditions.

A metal–organic framework-templated synthesis of γ-Fe2O3 nanoparticles encapsulated in porous carbon for efficient and chemoselective hydrogenation of nitro compounds

2016 ◽  
Vol 52 (22) ◽  
pp. 4199-4202 ◽  
Author(s):  
Yang Li ◽  
Yu-Xiao Zhou ◽  
Xiao Ma ◽  
Hai-Long Jiang
Keyword(s):  
Catalytic Activity ◽  
Porous Carbon ◽  
Metal Organic Framework ◽  
Nitro Compounds ◽  
Fe2o3 Nanoparticles ◽  
Templated Synthesis ◽  
Mild Conditions ◽  
Chemoselective Hydrogenation ◽  
Metal Organic ◽  
Organic Framework

The pyrolysis of metal–organic framework affords γ-Fe2O3 nanoparticles well dispersed inside porous carbon, exhibiting excellent catalytic activity, chemoselectivity and recyclability in the hydrogenation of diverse nitro compounds under mild conditions.

Metal-organic-framework derived hollow manganese nickel selenide spheres confined with nanosheets on nickel foam for hybrid supercapacitors

2021 ◽  
Author(s):  
Bahareh ameri ◽  
Akbar Mohammadi Zardkhoshoui ◽  
Saied Saeed Hosseiny Davarani
Keyword(s):  
Active Sites ◽  
Nickel Foam ◽  
Metal Organic Framework ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Supercapacitive Performance ◽  
Hybrid Supercapacitors ◽  
Porous Networks ◽  
Metal Organic

Metal-organic frameworks (MOFs) derived nanoarchitectures have special features, such as high surface area (SA), abundant active sites, exclusive porous networks, and remarkable supercapacitive performance when compared to traditional nanoarchitectures. Herein,...

A small molecular, a big scissoring effect: sodium dodecyl sulfate working on two-dimensional metal organic frameworks

CrystEngComm ◽  
2021 ◽  
Author(s):  
Qing Luo ◽  
Zhen Ding ◽  
Huamin Sun ◽  
Zhen Cheng ◽  
Naien SHI ◽  
...  
Keyword(s):  
Sodium Dodecyl Sulfate ◽  
Active Sites ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Sodium Dodecyl ◽  
Advanced Materials ◽  
Controlled Synthesis ◽  
Two Dimensional ◽  
Dodecyl Sulfate ◽  
Metal Organic

Ultrathin two-dimensional (2D) metal-organic framework (MOF) nanosheets are prosperous advanced materials due to their particularly thin thickness and exposed active sites. The difficulty in the controlled synthesis of 2D MOF...

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