Palladium-Catalyzed Selective CH Activation: A Simple Method to Synthesize C-3 Site Arylated Quinoline Derivatives

2016 ◽  
Vol 358 (3) ◽  
pp. 375-379 ◽  
Author(s):  
Yongqin He ◽  
Zhaoyang Wu ◽  
Chaowei Ma ◽  
Xiaoqiang Zhou ◽  
Xingxing Liu ◽  
...  
Keyword(s):  
Quinoline Derivatives ◽  
Simple Method ◽  
Palladium Catalyzed

ChemInform Abstract: Palladium-Catalyzed Selective C-H Activation: A Simple Method to Synthesize C-3 Site Arylated Quinoline Derivatives.

ChemInform ◽  
2016 ◽  
Vol 47 (24) ◽  
Author(s):  
Yongqin He ◽  
Zhaoyang Wu ◽  
Chaowei Ma ◽  
Xiaoqiang Zhou ◽  
Xingxing Liu ◽  
...  
Keyword(s):  
Quinoline Derivatives ◽  
Simple Method ◽  
Palladium Catalyzed

Palladium-catalyzed double coupling reaction of terminal alkynes with isocyanides: a direct approach to symmetrical N-aryl dialkynylimines

2020 ◽  
Vol 18 (40) ◽  
pp. 8089-8093
Author(s):  
Zhi-Wei Xi ◽  
Yan He ◽  
Li-Qiu Liu ◽  
Ying-Chun Wang
Keyword(s):  
Coupling Reaction ◽  
Direct Approach ◽  
Quinoline Derivatives ◽  
Terminal Alkynes ◽  
Palladium Catalyzed ◽  
Double Coupling

We have synthesized symmetrical N-aryl dialkynylimines via the palladium-catalyzed double coupling reaction of terminal alkynes with isonitriles, and the obtained dialkynylimines could be readily converted into 2-iodobenzo[f]quinoline derivatives.

Short and Simple Method of Synthesis of Some Pyrrolo[3,2-b]quinoline Derivatives from Easily Available Nitrobenzene Derivatives

Synlett ◽  
2010 ◽  
Vol 2010 (16) ◽  
pp. 2435-2438 ◽  
Author(s):  
Zbigniew Wróbel ◽  
Krzysztof Wojciechowski ◽  
Andrzej Kwast ◽  
Norbert Gajda
Keyword(s):  
Quinoline Derivatives ◽  
Simple Method

Ethynylation of Isoquinoline and Quinoline Derivatives with Calcium Carbide

Synlett ◽  
2017 ◽  
Vol 28 (16) ◽  
pp. 2126-2130 ◽  
Author(s):  
Alireza Samzadeh-Kermani
Keyword(s):  
Calcium Carbide ◽  
Quinoline Derivatives ◽  
Electronic Effects ◽  
Simple Method ◽  
Tetrabutylammonium Fluoride

An operatically simple method for the ethynylation of isoquinolines and quinolines is described. The ionic adduct derived from an alkynoic ester and the N-heterocycle was attacked by calcium carbide to give the ethynylation product. The procedure uses tetrabutylammonium fluoride trihydrate as a catalyst in aqueous N,N-dimethylacetamide. Steric and electronic effects of various substituents on the outcome of the reaction were examined.

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