Palladium‐Catalyzed Carbonylative Synthesis of Phthalimides from 1,2‐Dibromoarenes with Molybdenum Hexacarbonyl as Carbon Monoxide Source

2013 ◽  
Vol 355 (18) ◽  
pp. 3581-3585 ◽  
Author(s):  
Xiao‐Feng Wu ◽  
Stefan Oschatz ◽  
Muhammad Sharif ◽  
Anika Flader ◽  
Lisa Krey ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Molybdenum Hexacarbonyl ◽  
Palladium Catalyzed

Microwave-assisted, palladium-catalyzed carbonylative cyclization — Rapid synthesis of 2-quinolones from unprotected 2-iodoanilines and terminal alkynes

2010 ◽  
Vol 88 (4) ◽  
pp. 331-337 ◽  
Author(s):  
Jia-Rong Chen ◽  
Jie Liao ◽  
Wen-Jing Xiao
Keyword(s):  
Carbon Monoxide ◽  
Microwave Irradiation ◽  
Molybdenum Hexacarbonyl ◽  
Terminal Alkynes ◽  
Solid Carbon ◽  
Rapid Synthesis ◽  
Microwave Assisted ◽  
Palladium Catalyzed ◽  
Quinolone Derivatives

Palladium-catalyzed cyclocarbonylations of 2-iodoanilines with various terminal alkynes have been carried out by the use of commercially available molybdenum hexacarbonyl as a convenient and solid carbon monoxide source. The reactions were conducted at 160 °C for 30 min under microwave irradiation and in the presence of Et3N in THF, affording the corresponding 2-quinolone derivatives in good regioselectivities and yields.

ChemInform Abstract: Palladium-Catalyzed Carbonylative Synthesis of Phthalimides from 1,2-Dibromoarenes with Molybdenum Hexacarbonyl as Carbon Monoxide Source.

ChemInform ◽  
2014 ◽  
Vol 45 (21) ◽  
pp. no-no
Author(s):  
Xiao-Feng Wu ◽  
Stefan Oschatz ◽  
Muhammad Sharif ◽  
Anika Flader ◽  
Lisa Krey ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Molybdenum Hexacarbonyl ◽  
Palladium Catalyzed

Microwave-accelerated, palladium-catalyzed carbonylative cyclization reactions of 2-iodophenol with alkynes — Rapid and efficient synthesis of chromen-2-one derivatives

2005 ◽  
Vol 83 (6-7) ◽  
pp. 826-831 ◽  
Author(s):  
Hong Cao ◽  
Wen-Jing Xiao
Keyword(s):  
Carbon Monoxide ◽  
Microwave Heating ◽  
Molybdenum Hexacarbonyl ◽  
Solid Carbon ◽  
Efficient Synthesis ◽  
Cyclization Reactions ◽  
Palladium Catalyzed

Rapid palladium-catalyzed carbonylative cyclization reactions of 2-iodophenol with various alkynes have been carried out by the use of commercially available molybdenum hexacarbonyl as a convenient and solid carbon monoxide source. The reactions were conducted at 160 °C for 30 min with microwave heating in the presence of DIEA and DMAP in 1,4-dioxane, and afford the corresponding chromen-2-one derivatives in good yields.Key words: microwave, palladium, carbonylation, 2-iodophenol, chromen-2-one.

Palladium-catalyzed carbonylation of 1,5-cyclooctadiene. Effects of temperature and pressure

1991 ◽  
Vol 56 (3) ◽  
pp. 663-672 ◽  
Author(s):  
Curtis B. Anderson ◽  
Rade Marković
Keyword(s):  
Carbon Monoxide ◽  
Oxidative Carbonylation ◽  
Influence Of Temperature ◽  
Carbonylation Reaction ◽  
Palladium Catalyzed ◽  
Effects Of Temperature ◽  
Temperature And Pressure

The influence of temperature and carbon monoxide pressure on the course of oxidative carbonylation reaction of 1,5-cyclooctadiene in the presence of the palladium(II) salts as a catalyst, was investigated.

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