Propargyl-Allenyl Isomerizations and Electrocyclizations for the Functionalization of Phosphonium Salts: One-Pot Synthesis of Polysubstituted Vinylbenzenes and Naphthalenes

2013 ◽  
Vol 355 (17) ◽  
pp. 3492-3496 ◽  
Author(s):  
Guoqing Zhao ◽  
Qianyun Zhang ◽  
Hongwei Zhou
2001 ◽  
Vol 2001 (5) ◽  
pp. 192-194 ◽  
Author(s):  
Ahmad Shaabani ◽  
Hamid Reza Safaei ◽  
Kiana Hemyari ◽  
Abolghasem Moghimi

The title compounds were prepared in high yield by protonation of the reactive 1:1 intermediates produced in the reaction between triphenylphosphine and dialkyl acetylenedicarboxylate by phthalimide, followed by nucleophilic addition of the imidic nitrogen anion to the vinyl phosphonium salts. A dynamic NMR study was also performed.


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