Using Conveniently Designed α-Amino Ketones in Michael Reactions under Iminium Catalysis: Enantioselective Synthesis of γ-Lactams and γ-Amino-δ-keto Esters

Garazi Talavera; Efraím Reyes; Jose L. Vicario; Luisa Carrillo; Uxue Uria

doi:10.1002/adsc.201200987

Using Conveniently Designed α-Amino Ketones in Michael Reactions under Iminium Catalysis: Enantioselective Synthesis of γ-Lactams and γ-Amino-δ-keto Esters

Advanced Synthesis & Catalysis ◽

10.1002/adsc.201200987 ◽

2013 ◽

Vol 355 (4) ◽

pp. 653-658 ◽

Cited By ~ 14

Author(s):

Garazi Talavera ◽

Efraím Reyes ◽

Jose L. Vicario ◽

Luisa Carrillo ◽

Uxue Uria

Keyword(s):

Enantioselective Synthesis ◽

Keto Esters ◽

Michael Reactions

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ChemInform Abstract: Using Conveniently Designed α-Amino Ketones in Michael Reactions under Iminium Catalysis: Enantioselective Synthesis of γ-Lactams and γ-Amino-δ-keto Esters.

ChemInform ◽

10.1002/chin.201332119 ◽

2013 ◽

Vol 44 (32) ◽

pp. no-no

Author(s):

Garazi Talavera ◽

Efraim Reyes ◽

Jose L. Vicario ◽

Luisa Carrillo ◽

Uxue Uria

Keyword(s):

Enantioselective Synthesis ◽

Keto Esters ◽

Michael Reactions

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ChemInform Abstract: Asymmetric Michael Reactions: Enantioselective Synthesis of δ- Oxo Acids.

ChemInform ◽

10.1002/chin.199242057 ◽

2010 ◽

Vol 23 (42) ◽

pp. no-no

Author(s):

F. MICHELON ◽

A. POUILHES ◽

N. VAN BAC ◽

N. LANGLOIS

Keyword(s):

Enantioselective Synthesis ◽

Michael Reactions

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ChemInform Abstract: Highly Enantioselective Synthesis of Spiro[cyclohexanone-oxindoles] and Spiro[cyclohexanone-pyrazolones] by Asymmetric Cascade [5 + 1] Double Michael Reactions.

ChemInform ◽

10.1002/chin.201228108 ◽

2012 ◽

Vol 43 (28) ◽

pp. no-no

Author(s):

Bin Wu ◽

Jian Chen ◽

Mei-Qiu Li ◽

Jin-Xin Zhang ◽

Xiao-Ping Xu ◽

...

Keyword(s):

Enantioselective Synthesis ◽

Michael Reactions

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Michael Reactions with β-Keto Esters

Asymmetric Organocatalysis 2 ◽

10.1055/sos-sd-205-00017 ◽

2012 ◽

pp. 1

Author(s):

K. Nagasawa ◽

Y. Sohtome

Keyword(s):

Keto Esters ◽

Michael Reactions

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Enantioselective synthesis of 3-substituted isoindolinones via chiral phase-transfer catalyzed intramolecular aza-Michael reactions

10.3390/ecsoc-17-a033 ◽

2013 ◽

Author(s):

Eric Deniau ◽

Stéphane Lebrun

Keyword(s):

Phase Transfer ◽

Enantioselective Synthesis ◽

Chiral Phase ◽

Michael Reactions

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ChemInform Abstract: Highly Stereoselective Oxy-Michael Additions to β,γ-Unsaturated α-Keto Esters: Rapid Enantioselective Synthesis of 3-Hydroxybutenolides.

ChemInform ◽

10.1002/chin.200830102 ◽

2008 ◽

Vol 39 (30) ◽

Author(s):

Xin Xiong ◽

Caroline Ovens ◽

Adam W. Pilling ◽

John W. Ward ◽

Darren J. Dixon

Keyword(s):

Enantioselective Synthesis ◽

Keto Esters ◽

Michael Additions

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ChemInform Abstract: Catalytic Asymmetric Roskamp Reaction of α-Alkyl-α-diazoesters with Aromatic Aldehydes: Highly Enantioselective Synthesis of α-Alkyl-β-keto Esters.

ChemInform ◽

10.1002/chin.201047050 ◽

2010 ◽

Vol 41 (47) ◽

pp. no-no

Author(s):

Wei Li ◽

Jun Wang ◽

Xiaolei Hu ◽

Ke Shen ◽

Wentao Wang ◽

...

Keyword(s):

Aromatic Aldehydes ◽

Enantioselective Synthesis ◽

Keto Esters ◽

Catalytic Asymmetric

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Diastereo- and Enantioselective Synthesis of Spiro-Pyrrolidine-Pyrazolones by Squaramide-Catalyzed Cascade Aza-Michael/Michael Reactions

European Journal of Organic Chemistry ◽

10.1002/ejoc.201600316 ◽

2016 ◽

Vol 2016 (14) ◽

pp. 2492-2499 ◽

Cited By ~ 34

Author(s):

Jun-Hua Li ◽

Hongliang Wen ◽

Lei Liu ◽

Da-Ming Du

Keyword(s):

Enantioselective Synthesis ◽

Michael Reactions

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ChemInform Abstract: Catalytic Cascade Aldol-Cyclization of Tertiary Ketone Enolates for Enantioselective Synthesis of Keto-Esters with a C-F Quaternary Stereogenic Center.

ChemInform ◽

10.1002/chin.201649072 ◽

2016 ◽

Vol 47 (49) ◽

Author(s):

Wanxing Sha ◽

Lijun Zhang ◽

Wenzhong Zhang ◽

Haibo Mei ◽

Vadim A. Soloshonok ◽

...

Keyword(s):

Enantioselective Synthesis ◽

Keto Esters ◽

Aldol Cyclization ◽

Ketone Enolates ◽

Stereogenic Center

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ChemInform Abstract: A New Enantioselective Synthesis of Glycidates via Dynamic Kinetic Resolution of Racemic 2-Chloro-3-keto Esters Using Chiral Ru(II) Complexes.

ChemInform ◽

10.1002/chin.199530111 ◽

2010 ◽

Vol 26 (30) ◽

pp. no-no

Author(s):

J.-P. GENET ◽

M. C. CANO DE ANDRADE ◽

V. RATOVELOMANANA-VIDAL

Keyword(s):

Kinetic Resolution ◽

Enantioselective Synthesis ◽

Dynamic Kinetic Resolution ◽

Keto Esters

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Using Conveniently Designed α-Amino Ketones in Michael Reactions under Iminium Catalysis: Enantioselective Synthesis of γ-Lactams and γ-Amino-δ-keto Esters

ChemInform Abstract: Using Conveniently Designed α-Amino Ketones in Michael Reactions under Iminium Catalysis: Enantioselective Synthesis of γ-Lactams and γ-Amino-δ-keto Esters.

ChemInform Abstract: Asymmetric Michael Reactions: Enantioselective Synthesis of δ- Oxo Acids.

ChemInform Abstract: Highly Enantioselective Synthesis of Spiro[cyclohexanone-oxindoles] and Spiro[cyclohexanone-pyrazolones] by Asymmetric Cascade [5 + 1] Double Michael Reactions.

Michael Reactions with β-Keto Esters

Enantioselective synthesis of 3-substituted isoindolinones via chiral phase-transfer catalyzed intramolecular aza-Michael reactions

ChemInform Abstract: Highly Stereoselective Oxy-Michael Additions to β,γ-Unsaturated α-Keto Esters: Rapid Enantioselective Synthesis of 3-Hydroxybutenolides.

ChemInform Abstract: Catalytic Asymmetric Roskamp Reaction of α-Alkyl-α-diazoesters with Aromatic Aldehydes: Highly Enantioselective Synthesis of α-Alkyl-β-keto Esters.

Diastereo- and Enantioselective Synthesis of Spiro-Pyrrolidine-Pyr­azolones by Squaramide-Catalyzed Cascade Aza-Michael/Michael Reactions

ChemInform Abstract: Catalytic Cascade Aldol-Cyclization of Tertiary Ketone Enolates for Enantioselective Synthesis of Keto-Esters with a C-F Quaternary Stereogenic Center.

ChemInform Abstract: A New Enantioselective Synthesis of Glycidates via Dynamic Kinetic Resolution of Racemic 2-Chloro-3-keto Esters Using Chiral Ru(II) Complexes.

Diastereo- and Enantioselective Synthesis of Spiro-Pyrrolidine-Pyrazolones by Squaramide-Catalyzed Cascade Aza-Michael/Michael Reactions