Two-Phase Hydroformylation of Higher Olefins Using Randomly Methylated ?-Cyclodextrin as Mass Transfer Promoter: A Smart Solution for Preserving the Intrinsic Properties of the Rhodium/Trisulfonated Triphenylphosphine Catalytic System

2005 ◽  
Vol 347 (1) ◽  
pp. 55-59 ◽  
Author(s):  
Lo�c Leclercq ◽  
Mathieu Sauthier ◽  
Yves Castanet ◽  
Andr� Mortreux ◽  
Herv� Bricout ◽  
...  
Keyword(s):  
Mass Transfer ◽  
Catalytic System ◽  
Intrinsic Properties ◽  
Two Phase ◽  
Methylated Cyclodextrin ◽  
Higher Olefins

Stability of acoustic wave in two-phase dilute flow with mass transfer

AIAA Journal ◽  
2001 ◽  
Vol 39 ◽  
pp. 2121-2130
Author(s):  
Eric Daniel ◽  
Nicolas Thevand
Keyword(s):  
Mass Transfer ◽  
Acoustic Wave ◽  
Two Phase

The effect of two-phase flow regime on hydrodynamics and mass transfer in a horizontal-tube gas-liquid reactor

1985 ◽  
Vol 50 (3) ◽  
pp. 745-757 ◽  
Author(s):  
Andreas Zahn ◽  
Lothar Ebner ◽  
Kurt Winkler ◽  
Jan Kratochvíl ◽  
Jindřich Zahradník
Keyword(s):  
Mass Transfer ◽  
Pressure Drop ◽  
Flow Regime ◽  
Liquid Flow ◽  
Horizontal Tube ◽  
Liquid Holdup ◽  
Two Phase ◽  
Flow Rates ◽  
Type Relation ◽  
Good Agreement

The effect of two-phase flow regime on decisive hydrodynamic and mass transfer characteristics of horizontal-tube gas-liquid reactors (pressure drop, liquid holdup, kLaL) was determined in a cocurrent-flow experimental unit of the length 4.15 m and diameter 0.05 m with air-water system. An adjustable-height weir was installed in the separation chamber at the reactor outlet to simulate the effect of internal baffles on reactor hydrodynamics. Flow regime maps were developed in the whole range of experimental gas and liquid flow rates both for the weirless arrangement and for the weir height 0.05 m, the former being in good agreement with flow-pattern boundaries presented by Mandhane. In the whole range of experi-mental conditions pressure drop data could be well correlated as a function of gas and liquid flow rates by an empirical exponential-type relation with specific sets of coefficients obtained for individual flow regimes from experimental data. Good agreement was observed between values of pressure drop obtained for weirless arrangement and data calculated from the Lockhart-Martinelli correlation while the contribution of weir to the overall pressure drop was well described by a relation proposed for the pressure loss in closed-end tubes. In the region of negligible weir influence values of liquid holdup were again succesfully correlated by the Lockhart-Martinelli relation while the dependence of liquid holdup data on gas and liquid flow rates obtained under conditions of significant weir effect (i.e. at low flow rates of both phases) could be well described by an empirical exponential-type relation. Results of preliminary kLaL measurements confirmed the decisive effect of the rate of energy dissipation on the intensity of interfacial mass transfer in gas-liquid dispersions.

scholarly journals Numerical Study of a Cooling System Using Phase Change of a Refrigerant in a Thermosyphon

Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3634
Author(s):  
Grzegorz Czerwiński ◽  
Jerzy Wołoszyn
Keyword(s):  
Mass Transfer ◽  
Phase Change ◽  
Heat Dissipation ◽  
Cooling System ◽  
Numerical Study ◽  
Relaxation Parameter ◽  
Phase Changes ◽  
Transfer Time ◽  
Two Phase ◽  
Time Relaxation

With the increasing trend toward the miniaturization of electronic devices, the issue of heat dissipation becomes essential. The use of phase changes in a two-phase closed thermosyphon (TPCT) enables a significant reduction in the heat generated even at high temperatures. In this paper, we propose a modification of the evaporation–condensation model implemented in ANSYS Fluent. The modification was to manipulate the value of the mass transfer time relaxation parameter for evaporation and condensation. The developed model in the form of a UDF script allowed the introduction of additional source equations, and the obtained solution is compared with the results available in the literature. The variable value of the mass transfer time relaxation parameter during condensation rc depending on the density of the liquid and vapour phase was taken into account in the calculations. However, compared to previous numerical studies, more accurate modelling of the phase change phenomenon of the medium in the thermosyphon was possible by adopting a mass transfer time relaxation parameter during evaporation re = 1. The assumption of ten-fold higher values resulted in overestimated temperature values in all sections of the thermosyphon. Hence, the coefficient re should be selected individually depending on the case under study. A too large value may cause difficulties in obtaining the convergence of solutions, which, in the case of numerical grids with many elements (especially three-dimensional), significantly increases the computation time.

scholarly journals Two-Phase Flow Mass Transfer Analysis of Airlift Pump for Aquaculture Applications

Fluids ◽  
2021 ◽  
Vol 6 (6) ◽  
pp. 226
Author(s):  
Rashal Abed ◽  
Mohamed M. Hussein ◽  
Wael H. Ahmed ◽  
Sherif Abdou
Keyword(s):  
Mass Transfer ◽  
Oxygen Transfer ◽  
Transfer Rate ◽  
Two Phase Flow ◽  
Oxygen Transfer Rate ◽  
Flow Patterns ◽  
Oxygen Mass Transfer ◽  
Phase Flow ◽  
Two Phase ◽  
Airlift Pump

Airlift pumps can be used in the aquaculture industry to provide aeration while concurrently moving water utilizing the dynamics of two-phase flow in the pump riser. The oxygen mass transfer that occurs from the injected compressed air to the water in the aquaculture systems can be experimentally investigated to determine the pump aeration capabilities. The objective of this study is to evaluate the effects of various airflow rates as well as the injection methods on the oxygen transfer rate within a dual injector airlift pump system. Experiments were conducted using an airlift pump connected to a vertical pump riser within a recirculating system. Both two-phase flow patterns and the void fraction measurements were used to evaluate the dissolved oxygen mass transfer mechanism through the airlift pump. A dissolved oxygen (DO) sensor was used to determine the DO levels within the airlift pumping system at different operating conditions required by the pump. Flow visualization imaging and particle image velocimetry (PIV) measurements were performed in order to better understand the effects of the two-phase flow patterns on the aeration performance. It was found that the radial injection method reached the saturation point faster at lower airflow rates, whereas the axial method performed better as the airflow rates were increased. The standard oxygen transfer rate (SOTR) and standard aeration efficiency (SAE) were calculated and were found to strongly depend on the injection method as well as the two-phase flow patterns in the pump riser.

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