Recent Advances of Cocrystals with Room Temperature Phosphorescence

2021 ◽  
pp. 2002197
Author(s):  
Manjeet Singh ◽  
Kun Liu ◽  
Shuli Qu ◽  
Huili Ma ◽  
Huifang Shi ◽  
...  
2021 ◽  
Author(s):  
Rui Gao ◽  
Mohamad S. Kodaimati ◽  
Dongpeng Yan

In this review, we summarize recent advances in establishing persistently luminescent materials from the view of examining experimental and theoretical approaches to room-temperature phosphorescence and thermally-activated delayed fluorescence.


Talanta ◽  
2021 ◽  
pp. 122350
Author(s):  
Jing Jia ◽  
Wenjing Lu ◽  
Yifang Gao ◽  
Lin Li ◽  
Chuan Dong ◽  
...  

Small ◽  
2021 ◽  
pp. 2104073
Author(s):  
Xi Yan ◽  
Hao Peng ◽  
Yuan Xiang ◽  
Juan Wang ◽  
Lan Yu ◽  
...  

2020 ◽  
Author(s):  
Yunzhong Wang ◽  
Saixing Tang ◽  
Yating Wen ◽  
Shuyuan Zheng ◽  
Bing Yang ◽  
...  

<div>Persistent room-temperature phosphorescence (p-RTP) from pure organics is attractive </div><div>due to its fundamental importance and potential applications in molecular imaging, </div><div>sensing, encryption, anticounterfeiting, etc.1-4 Recently, efforts have been also made in </div><div>obtaining color-tunable p-RTP in aromatic phosphors5 and nonconjugated polymers6,7. </div><div>The origin of color-tunable p-RTP and the rational design of such luminogens, </div><div>particularly those with explicit structure and molecular packing, remain challenging. </div><div>Noteworthily, nonconventional luminophores without significant conjugations generally </div><div>possess excitation-dependent photoluminescence (PL) because of the coexistence of </div><div>diverse clustered chromophores6,8, which strongly implicates the possibility to achieve </div><div>color-tunable p-RTP from their molecular crystals assisted by effective intermolecular </div><div>interactions. Here, inspirited by the highly stable double-helix structure and multiple </div><div>hydrogen bonds in DNA, we reported a series of nonconventional luminophores based on </div><div>hydantoin (HA), which demonstrate excitation-dependent PL and color-tunable p-RTP </div><div>from sky-blue to yellowish-green, accompanying unprecedentedly high PL and p-RTP </div><div>efficiencies of up to 87.5% and 21.8%, respectively. Meanwhile, the p-RTP emissions are </div><div>resistant to vigorous mechanical grinding, with lifetimes of up to 1.74 s. Such robust, </div><div>color-tunable and highly efficient p-RTP render the luminophores promising for varying </div><div>applications. These findings provide mechanism insights into the origin of color-tunable </div><div>p-RTP, and surely advance the exploitation of efficient nonconventional luminophores.</div>


Sign in / Sign up

Export Citation Format

Share Document