Broadband Near‐Infrared Garnet Phosphors with Near‐Unity Internal Quantum Efficiency

2020 ◽  
Vol 8 (12) ◽  
pp. 2000296 ◽  
Author(s):  
Endale T. Basore ◽  
Wenge Xiao ◽  
Xiaofeng Liu ◽  
Jianhong Wu ◽  
Jianrong Qiu
2019 ◽  
Vol 131 (41) ◽  
pp. 14802-14807 ◽  
Author(s):  
Jia‐Xiong Chen ◽  
Wen‐Wen Tao ◽  
Wen‐Cheng Chen ◽  
Ya‐Fang Xiao ◽  
Kai Wang ◽  
...  

2019 ◽  
Vol 58 (41) ◽  
pp. 14660-14665 ◽  
Author(s):  
Jia‐Xiong Chen ◽  
Wen‐Wen Tao ◽  
Wen‐Cheng Chen ◽  
Ya‐Fang Xiao ◽  
Kai Wang ◽  
...  

Author(s):  
Laurentiu Fara ◽  
Mihai Razvan Mitroi

In this chapter, the authors present the modelling and simulation of the multi-layered quantum well solar cells as well as the simulated results of this model. The quantum confinement of a semiconductor induces new energy levels, located in the band gap, as well as resonant levels located in the conduction and valence bands. These levels allow supplementary absorption in the visible and near infrared range. The quantum efficiency of the supplementary absorption is calculated within the infinite rectangular quantum well approximation. As the absorption excites carriers in the gap of each layer, even a small absorption significantly increases the photocurrent (by photoassisted tunneling) and, therefore, the cell efficiency. The results of the simulation are presented for the internal quantum efficiency of the transitions between the resonant levels of GaAs, as well as the internal quantum efficiency of the transitions between the confinement levels for GaAs and AlxGa1-xAs. New directions for the research of quantum well solar cells are indicated.


Sensors ◽  
2019 ◽  
Vol 19 (12) ◽  
pp. 2755 ◽  
Author(s):  
Yhang Ricardo Sipauba Carvalho da Silva ◽  
Rihito Kuroda ◽  
Shigetoshi Sugawa

This paper presents a silicon ultraviolet radiation sensor with over 90% UV internal quantum efficiency (QE) and high selectivity to the UV waveband without using optical filters. The sensor was developed for applications that require UV measurement under strong background visible and near-infrared (NIR) lights, such as solar UV measurement, UV-C monitoring in greenhouses or automated factories, and so on. The developed sensor is composed of monolithically formed silicon photodiodes with different spectral sensitivities: a highly UV responsive photodiode with internal quantum efficiency (QE) of nearly 100% for UV light, and a lowly UV responsive photodiode with UV internal QE lower than 10%. The photodiodes were optimized to match their visible and NIR light responsivity, and the UV signal is extracted from the background radiation by using the differential spectral response method. With this approach, an internal QE of over 90% for UV light was obtained, with a residual internal QE to non-UV light lower than 20% for 400 nm, 5% for 500 nm, 2% for 600 nm and 0.6% to NIR light. The developed sensor showed no responsivity degradation after exposure towards strong UV light. It was confirmed by the simulation results that the residual responsivity is further suppressed by employing an on-chip band-rejection optical layer consisting of several layers of silicon oxide and silicon nitride films.


2014 ◽  
pp. 731-741
Author(s):  
Laurentiu Fara ◽  
Mihai Razvan Mitroi

In this chapter, the authors present the modelling and simulation of the multi-layered quantum well solar cells as well as the simulated results of this model. The quantum confinement of a semiconductor induces new energy levels, located in the band gap, as well as resonant levels located in the conduction and valence bands. These levels allow supplementary absorption in the visible and near infrared range. The quantum efficiency of the supplementary absorption is calculated within the infinite rectangular quantum well approximation. As the absorption excites carriers in the gap of each layer, even a small absorption significantly increases the photocurrent (by photoassisted tunneling) and, therefore, the cell efficiency. The results of the simulation are presented for the internal quantum efficiency of the transitions between the resonant levels of GaAs, as well as the internal quantum efficiency of the transitions between the confinement levels for GaAs and AlxGa1-xAs. New directions for the research of quantum well solar cells are indicated.


2008 ◽  
Author(s):  
Ana Luz Muñoz Zurita ◽  
Joaquin Campos Acosta ◽  
Alexandre S. Shcherbakov ◽  
Alicia Pons Aglio

2021 ◽  
Vol 10 (1) ◽  
Author(s):  
Alessandro Minotto ◽  
Ibrahim Bulut ◽  
Alexandros G. Rapidis ◽  
Giuseppe Carnicella ◽  
Maddalena Patrini ◽  
...  

AbstractThe energy gap law (EG-law) and aggregation quenching are the main limitations to overcome in the design of near-infrared (NIR) organic emitters. Here, we achieve unprecedented results by synergistically addressing both of these limitations. First, we propose porphyrin oligomers with increasing length to attenuate the effects of the EG -law by suppressing the non-radiative rate growth, and to increase the radiative rate via enhancement of the oscillator strength. Second, we design side chains to suppress aggregation quenching. We find that the logarithmic rate of variation in the non-radiative rate vs. EG is suppressed by an order of magnitude with respect to previous studies, and we complement this breakthrough by demonstrating organic light-emitting diodes with an average external quantum efficiency of ~1.1%, which is very promising for a heavy-metal-free 850 nm emitter. We also present a novel quantitative model of the internal quantum efficiency for active layers supporting triplet-to-singlet conversion. These results provide a general strategy for designing high-luminance NIR emitters.


Photonics ◽  
2021 ◽  
Vol 8 (6) ◽  
pp. 196
Author(s):  
Tsung-Chi Hsu ◽  
Yu-Tsai Teng ◽  
Yen-Wei Yeh ◽  
Xiaotong Fan ◽  
Kuo-Hsiung Chu ◽  
...  

High-quality epitaxial layers are directly related to internal quantum efficiency. The methods used to design such epitaxial layers are reviewed in this article. The ultraviolet C (UVC) light-emitting diode (LED) epitaxial layer structure exhibits electron leakage; therefore, many research groups have proposed the design of blocking layers and carrier transportation to generate high electron–hole recombination rates. This also aids in increasing the internal quantum efficiency. The cap layer, p-GaN, exhibits high absorption in deep UV radiation; thus, a small thickness is usually chosen. Flip chip design is more popular for such devices in the UV band, and the main factors for consideration are light extraction and heat transportation. However, the choice of encapsulation materials is important, because unsuitable encapsulation materials will be degraded by ultraviolet light irradiation. A suitable package design can account for light extraction and heat transportation. Finally, an atomic layer deposition Al2O3 film has been proposed as a mesa passivation layer. It can provide a low reverse current leakage. Moreover, it can help increase the quantum efficiency, enhance the moisture resistance, and improve reliability. UVC LED applications can be used in sterilization, water purification, air purification, and medical and military fields.


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