Restricting Lattice Flexibility in Polycrystalline Metal–Organic Framework Membranes for Carbon Capture

2019 ◽  
Vol 31 (28) ◽  
pp. 1900855 ◽  
Author(s):  
Deepu J. Babu ◽  
Guangwei He ◽  
Jian Hao ◽  
Mohammad Tohidi Vahdat ◽  
Pascal Alexander Schouwink ◽  
...  
Keyword(s):  
Carbon Capture ◽  
Metal Organic Framework ◽  
Polycrystalline Metal ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Kinetics of cooperative CO2 adsorption in diamine-appended variants of the metal–organic framework Mg2(dobpdc)

2020 ◽  
Vol 11 (25) ◽  
pp. 6457-6471 ◽  
Author(s):  
Jeffrey D. Martell ◽  
Phillip J. Milner ◽  
Rebecca L. Siegelman ◽  
Jeffrey R. Long
Keyword(s):  
Adsorption Kinetics ◽  
Carbon Capture ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Performance Properties ◽  
Metal Organic ◽  
Kinetics Of ◽  
Insight Into ◽  
Organic Framework

An in-depth investigation of the CO2 adsorption kinetics of a promising class of cooperative carbon capture materials offers new insight into their structure-performance properties.

scholarly journals Rational Design of a Low-Cost, High-Performance Metal–Organic Framework for Hydrogen Storage and Carbon Capture

2017 ◽  
Vol 121 (2) ◽  
pp. 1171-1181 ◽  
Author(s):  
Matthew Witman ◽  
Sanliang Ling ◽  
Andrzej Gladysiak ◽  
Kyriakos C. Stylianou ◽  
Berend Smit ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Carbon Capture ◽  
High Performance ◽  
Rational Design ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Multivariate Polycrystalline Metal–Organic Framework Membranes for CO2/CH4 Separation

2021 ◽  
Author(s):  
Weidong Fan ◽  
Yunpan Ying ◽  
Shing Bo Peh ◽  
Hongye Yuan ◽  
Ziqi Yang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Polycrystalline Metal ◽  
Metal Organic ◽  
Organic Framework

Polycrystalline metal-organic framework (MOF) membranes for molecular separations: Engineering prospects and challenges

2021 ◽  
Vol 640 ◽  
pp. 119802
Author(s):  
Mohamad Rezi Abdul Hamid ◽  
Yutian Qian ◽  
Ruicong Wei ◽  
Zhen Li ◽  
Yichang Pan ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Polycrystalline Metal ◽  
Metal Organic ◽  
Molecular Separations ◽  
Organic Framework

scholarly journals Synthesis of FeCo-MIL-88B and Investigate Its Potential for CO2 Capture

2019 ◽  
Vol 35 (1) ◽  
Author(s):  
Le Minh Cam ◽  
Le Van Khu ◽  
Nguyen Thi Thu Ha ◽  
Nguyen Ngoc Ha
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Mesoporous Materials ◽  
Co2 Capture ◽  
Carbon Capture ◽  
Co2 Adsorption ◽  
Carbon Dioxide Capture ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Cobalt dopping Fe-MIL-88B were successfully synthesized -in solvothermal procedure using DMF as solvent and with/without NaOH. The samples were characterized using SEM, BET and TGA techniques. The partly substitution of Fe by Co does not change the octahedral shape of their parent Fe-MIL-88B. Crystallizations conducted in NaOH medium, however, results in rod like with 2-end octahedral shape crystals. The BET specific surface area is 139cm2/g. The TGA data indicated that the presence of Co resulted in an increase in thermal stability of synthesized samples compared to parent Fe-MIL-88B. The CO2 adsorption isotherms in Fe-MIL-88B-Co samples were measured volumetrically at five temperatures:278K, 288K, 298K, 308K, 318K. The obtained results showed that Fe-MIL-88B-Co is a potential adsorbent with a maximum adsortption capacity of 1.2312 mmol/g (at T= 278K). The sample synthesized in alkali medium exhibited a better adsorbent for CO2 storage. Keywords MIL, adsorption, CO2 References [1] S. Chu, Carbon Capture and Sequestration, Science325(2009)1599 [2] R.S. Haszeldine,Carbon Capture and Storage: How Green Can Black Be?, Science325(2009) 1647[3] D.M. D’Alessandro, B. Smit, J.R. Long,Carbon Dioxide Capture: Prospects for New Materials, Angewandte Chemie International Edition. 49(2010) 6058[4] S. Bai, J. Liu, J. Gao, Q. Yang Can Li,Hydrolysis controlled synthesis of amine-functionalized hollow ethane–silica nanospheres as adsorbents for CO2 capture, Microporous and Mesoporous Materials151(2012) 474[5] K. Sumida, D.L. Rogow, J.A. Mason, T.M. McDonald, E.D. Bloch, Z.R. Herm, T.H. Bae, J.R.[6] Long,Carbon Dioxide Capture in Metal–Organic Frameworks, Chemical Reviews, 112(2012) 724[7] J.D. Carruthers, M.A. Petruska, E.A. Sturm, S.M. Wilson,Molecular sieve carbons for CO2 capture, Microporous and Mesoporous Materials,154 (2012) 62[8] X. Yan, L. Zhang, Y. Zhang, K. Qiao, Z. Yan, S. Komarneni,Amine-modified mesocellular silica foams for CO2 capture, Chemical Engineering Journal,168 (2011), 918[9] A. Zukal, C.O. Arean, M.R. Delgado, P. Nachtigall, A. Pulido, J. Mayerova, J. Cˇejka,Combined volumetric, infrared spectroscopic and theoretical investigation of CO2 adsorption on Na-A zeolite,Microporous and Mesoporous Materials 146 (2011) 97[10] S. Keskin, T.M. van Heest, D.S. Sholl, Can Metal–Organic Framework Materials Play a Useful Role in Large‐Scale Carbon Dioxide Separations?, ChemSusChem3 (2010) 879[11] T.M. McDonald, W.R. Lee, J.A. Mason, B.M. Wiers, C.S. Hong, J.R. Long, Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc), Journal of the American Chemical Society134 (2012) 7056[12] X. Yan, S. Komarneni, Z. Zhang, Z. Yan(2014),Extremely enhanced CO2 uptake by HKUST-1 metal–organic framework via a simple chemical treatment, Microporous and Mesoporous Materials183 (2014) 69–73[13] Gia-Thanh Vuong, Minh-Hao Pham and Trong-On Do*, Direct synthesis and mechanism of the formation of mixed metal Fe2Ni-MIL-88B†, CrystEngComm, DOI: 10.1039/c3ce41453a[14] Lê Văn Khu, Nguyễn Quốc Anh, Nguyễn Ngọc Hà, Lê Minh Cầm, Tổng hợp, đặc trưng và khảo sát khả năng hấp phụ CO2 của Fe-MIL-88B, Tạp chí xúc tác và hấp phụ 4 (1) (2015) 52[15] K. S. W. Sing, D. H. Everett, R. A. W. Hau et.al, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity, Pure and Applied Chemistry 57 (1985) 603

Centimetre-scale micropore alignment in oriented polycrystalline metal–organic framework films via heteroepitaxial growth

2016 ◽  
Vol 16 (3) ◽  
pp. 342-348 ◽  
Author(s):  
Paolo Falcaro ◽  
Kenji Okada ◽  
Takaaki Hara ◽  
Ken Ikigaki ◽  
Yasuaki Tokudome ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Heteroepitaxial Growth ◽  
Polycrystalline Metal ◽  
Metal Organic ◽  
Oriented Polycrystalline ◽  
Organic Framework
Sign in / Sign up

Export Citation Format

Share Document