Computational Design of a Photoresponsive Metal–Organic Framework for Post Combustion Carbon Capture

2020 ◽  
Vol 124 (24) ◽  
pp. 13162-13167 ◽  
Author(s):  
Junkil Park ◽  
Bong Lim Suh ◽  
Jihan Kim
Keyword(s):  
Carbon Capture ◽  
Metal Organic Framework ◽  
Computational Design ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Kinetics of cooperative CO2 adsorption in diamine-appended variants of the metal–organic framework Mg2(dobpdc)

2020 ◽  
Vol 11 (25) ◽  
pp. 6457-6471 ◽  
Author(s):  
Jeffrey D. Martell ◽  
Phillip J. Milner ◽  
Rebecca L. Siegelman ◽  
Jeffrey R. Long
Keyword(s):  
Adsorption Kinetics ◽  
Carbon Capture ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Performance Properties ◽  
Metal Organic ◽  
Kinetics Of ◽  
Insight Into ◽  
Organic Framework

An in-depth investigation of the CO2 adsorption kinetics of a promising class of cooperative carbon capture materials offers new insight into their structure-performance properties.

scholarly journals Rational Design of a Low-Cost, High-Performance Metal–Organic Framework for Hydrogen Storage and Carbon Capture

2017 ◽  
Vol 121 (2) ◽  
pp. 1171-1181 ◽  
Author(s):  
Matthew Witman ◽  
Sanliang Ling ◽  
Andrzej Gladysiak ◽  
Kyriakos C. Stylianou ◽  
Berend Smit ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Carbon Capture ◽  
High Performance ◽  
Rational Design ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Synthesis of FeCo-MIL-88B and Investigate Its Potential for CO2 Capture

2019 ◽  
Vol 35 (1) ◽  
Author(s):  
Le Minh Cam ◽  
Le Van Khu ◽  
Nguyen Thi Thu Ha ◽  
Nguyen Ngoc Ha
Keyword(s):  
Carbon Dioxide ◽  
Surface Area ◽  
Mesoporous Materials ◽  
Co2 Capture ◽  
Carbon Capture ◽  
Co2 Adsorption ◽  
Carbon Dioxide Capture ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Cobalt dopping Fe-MIL-88B were successfully synthesized -in solvothermal procedure using DMF as solvent and with/without NaOH. The samples were characterized using SEM, BET and TGA techniques. The partly substitution of Fe by Co does not change the octahedral shape of their parent Fe-MIL-88B. Crystallizations conducted in NaOH medium, however, results in rod like with 2-end octahedral shape crystals. The BET specific surface area is 139cm2/g. The TGA data indicated that the presence of Co resulted in an increase in thermal stability of synthesized samples compared to parent Fe-MIL-88B. The CO2 adsorption isotherms in Fe-MIL-88B-Co samples were measured volumetrically at five temperatures:278K, 288K, 298K, 308K, 318K. The obtained results showed that Fe-MIL-88B-Co is a potential adsorbent with a maximum adsortption capacity of 1.2312 mmol/g (at T= 278K). The sample synthesized in alkali medium exhibited a better adsorbent for CO2 storage. Keywords MIL, adsorption, CO2 References [1] S. Chu, Carbon Capture and Sequestration, Science325(2009)1599 [2] R.S. Haszeldine,Carbon Capture and Storage: How Green Can Black Be?, Science325(2009) 1647[3] D.M. D’Alessandro, B. Smit, J.R. Long,Carbon Dioxide Capture: Prospects for New Materials, Angewandte Chemie International Edition. 49(2010) 6058[4] S. Bai, J. Liu, J. Gao, Q. Yang Can Li,Hydrolysis controlled synthesis of amine-functionalized hollow ethane–silica nanospheres as adsorbents for CO2 capture, Microporous and Mesoporous Materials151(2012) 474[5] K. Sumida, D.L. Rogow, J.A. Mason, T.M. McDonald, E.D. Bloch, Z.R. Herm, T.H. Bae, J.R.[6] Long,Carbon Dioxide Capture in Metal–Organic Frameworks, Chemical Reviews, 112(2012) 724[7] J.D. Carruthers, M.A. Petruska, E.A. Sturm, S.M. Wilson,Molecular sieve carbons for CO2 capture, Microporous and Mesoporous Materials,154 (2012) 62[8] X. Yan, L. Zhang, Y. Zhang, K. Qiao, Z. Yan, S. Komarneni,Amine-modified mesocellular silica foams for CO2 capture, Chemical Engineering Journal,168 (2011), 918[9] A. Zukal, C.O. Arean, M.R. Delgado, P. Nachtigall, A. Pulido, J. Mayerova, J. Cˇejka,Combined volumetric, infrared spectroscopic and theoretical investigation of CO2 adsorption on Na-A zeolite,Microporous and Mesoporous Materials 146 (2011) 97[10] S. Keskin, T.M. van Heest, D.S. Sholl, Can Metal–Organic Framework Materials Play a Useful Role in Large‐Scale Carbon Dioxide Separations?, ChemSusChem3 (2010) 879[11] T.M. McDonald, W.R. Lee, J.A. Mason, B.M. Wiers, C.S. Hong, J.R. Long, Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc), Journal of the American Chemical Society134 (2012) 7056[12] X. Yan, S. Komarneni, Z. Zhang, Z. Yan(2014),Extremely enhanced CO2 uptake by HKUST-1 metal–organic framework via a simple chemical treatment, Microporous and Mesoporous Materials183 (2014) 69–73[13] Gia-Thanh Vuong, Minh-Hao Pham and Trong-On Do*, Direct synthesis and mechanism of the formation of mixed metal Fe2Ni-MIL-88B†, CrystEngComm, DOI: 10.1039/c3ce41453a[14] Lê Văn Khu, Nguyễn Quốc Anh, Nguyễn Ngọc Hà, Lê Minh Cầm, Tổng hợp, đặc trưng và khảo sát khả năng hấp phụ CO2 của Fe-MIL-88B, Tạp chí xúc tác và hấp phụ 4 (1) (2015) 52[15] K. S. W. Sing, D. H. Everett, R. A. W. Hau et.al, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity, Pure and Applied Chemistry 57 (1985) 603

Process-level modelling and optimization to evaluate metal–organic frameworks for post-combustion capture of CO2

2020 ◽  
Vol 5 (7) ◽  
pp. 1205-1218 ◽  
Author(s):  
Daison Yancy-Caballero ◽  
Karson T. Leperi ◽  
Benjamin J. Bucior ◽  
Rachelle K. Richardson ◽  
Timur Islamoglu ◽  
...  
Keyword(s):  
Carbon Capture ◽  
Pressure Swing Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Economic Optimization ◽  
Metal Organic ◽  
Pressure Swing ◽  
Process Level ◽  
Modelling And Optimization ◽  
Organic Framework

Process and economic optimization of several pressure swing adsorption cycles were carried out to rank promising metal-organic framework (MOF) materials for post combustion carbon capture.

scholarly journals Unexpected Selective Gas Adsorption on a ‘Non-Porous’ Metal Organic Framework

Crystals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 548
Author(s):  
Stuart Beveridge ◽  
Craig A. McAnally ◽  
Gary S. Nichol ◽  
Alan R. Kennedy ◽  
Edmund J. Cussen ◽  
...  
Keyword(s):  
Carbon Capture ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Lewis Base ◽  
Base Interaction ◽  
Full Characterization ◽  
Sorbent Regeneration ◽  
Metal Organic ◽  
Organic Framework

A metal organic framework Cu(tpt)BF4·¾H2O was synthesized as a potential carbon capture material, with the aim being to exploit the Lewis base interaction of the incorporated ligand functionalities with acidic gas. The material displays high thermal stability but an exceptionally low surface area; however, this contrasts starkly with its ability to capture carbon dioxide, demonstrating significant activated diffusion within the framework. The full characterization of the material shows a robust structure, where the CO2 sorption is 120% greater than current industrial methods using liquid amine solutions; the thermal energy required for sorbent regeneration is reduced by 65%, indicating the true industrial potential of the synthesized material.

scholarly journals Metal‐Organic Framework MIL‐68(In)‐NH 2 on the Membrane Test Bench for Dye Removal and Carbon Capture

2022 ◽  
Author(s):  
Bahram Hosseini Monjezi ◽  
Benedikt Sapotta ◽  
Sarah Moulai ◽  
Jinju Zhang ◽  
Robert Oestreich ◽  
...  
Keyword(s):  
Carbon Capture ◽  
Dye Removal ◽  
Test Bench ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework
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