In Situ Observation of Voltage-Induced Multilevel Resistive Switching in Solid Electrolyte Memory

2011 ◽  
Vol 23 (29) ◽  
pp. 3272-3277 ◽  
Author(s):  
Sang-Jun Choi ◽  
Gyeong-Su Park ◽  
Ki-Hong Kim ◽  
Soohaeng Cho ◽  
Woo-Young Yang ◽  
...  
2020 ◽  
Author(s):  
Tingting Yang ◽  
Hui Li ◽  
Yongfu Tang ◽  
Jingzhao Chen ◽  
Hongjun Ye ◽  
...  

Abstract The growth of lithium (Li) whiskers is detrimental to Li batteries. However, it remains a challenge to directly track Li whisker growth. Here we report in situ observations of electrochemically induced Li deposition under a CO2 atmosphere inside an environmental transmission electron microscope. We find that the morphology of individual Li deposits is strongly influenced by the competing processes of cracking and self-healing of the solid electrolyte interphase (SEI). When cracking overwhelms self-healing, the directional growth of Li whiskers predominates. In contrast, when self-healing dominates over cracking, the isotropic growth of round Li particles prevails. The Li deposition rate and SEI constituent can be tuned to control the Li morphologies. We reveal a new “weak-spot” mode of Li dendrite growth, which is attributed to the operation of the Bardeen-Herring growth mechanism in the whisker’s cross section. This work has implications for the control of Li dendrite growth in Li batteries.


2010 ◽  
Vol 31 (3) ◽  
pp. 246-248 ◽  
Author(s):  
H.J. Wan ◽  
P. Zhou ◽  
L. Ye ◽  
Y.Y. Lin ◽  
T.A. Tang ◽  
...  

2014 ◽  
Vol 105 (11) ◽  
pp. 113504 ◽  
Author(s):  
D. S. Hong ◽  
W. X. Wang ◽  
Y. S. Chen ◽  
J. R. Sun ◽  
B. G. Shen

ACS Nano ◽  
2018 ◽  
Vol 12 (7) ◽  
pp. 7335-7342 ◽  
Author(s):  
Sungkyu Kim ◽  
Hee Joon Jung ◽  
Jong Chan Kim ◽  
Kyung-Sun Lee ◽  
Sung Soo Park ◽  
...  

2012 ◽  
Vol 7 (1) ◽  
pp. 559 ◽  
Author(s):  
Chung-Nan Peng ◽  
Chun-Wen Wang ◽  
Tsung-Cheng Chan ◽  
Wen-Yuan Chang ◽  
Yi-Chung Wang ◽  
...  

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