Temperature-Controlled Assembly and Release from Polymer Vesicles of Poly(ethylene oxide)-block- poly(N-isopropylacrylamide)

2006 ◽  
Vol 18 (21) ◽  
pp. 2905-2909 ◽  
Author(s):  
S. Qin ◽  
Y. Geng ◽  
D. E. Discher ◽  
S. Yang
Keyword(s):  
Ethylene Oxide ◽  
Controlled Assembly ◽  
Polymer Vesicles ◽  
Poly Ethylene Oxide ◽  
Temperature Controlled ◽  
Poly Ethylene

scholarly journals Embedding of superparamagnetic iron oxide nanoparticles into membranes of well-defined poly(ethylene oxide)-block-poly(ε-caprolactone) nanoscale magnetovesicles as ultrasensitive MRI probes of membrane bio-degradation

2019 ◽  
Vol 7 (30) ◽  
pp. 4692-4705 ◽  
Author(s):  
Adeline Hannecart ◽  
Dimitri Stanicki ◽  
Luce Vander Elst ◽  
Robert N. Muller ◽  
Annie Brûlet ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Ethylene Oxide ◽  
Iron Oxide Nanoparticles ◽  
Superparamagnetic Iron Oxide ◽  
Superparamagnetic Iron Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Polymer Vesicles ◽  
Nanoprecipitation Method ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

The present study reports the preparation of PEO-b-PCL polymer vesicles via a nanoprecipitation method and the loading of hydrophobically coated USPIO into the membrane of these nanovesicles, whose thickness was measured precisely by SANS.

A catalyst-free, temperature controlled gelation system for in-mold fabrication of microgels

2018 ◽  
Vol 54 (50) ◽  
pp. 6943-6946 ◽  
Author(s):  
Andreas J. D. Krüger ◽  
Jens Köhler ◽  
Stefan Cichosz ◽  
Jonas C. Rose ◽  
David B. Gehlen ◽  
...  
Keyword(s):  
Ethylene Oxide ◽  
Propylene Oxide ◽  
Self Assembly ◽  
Chemical Properties ◽  
Catalyst Free ◽  
Poly Ethylene Oxide ◽  
Mold Fabrication ◽  
Temperature Controlled ◽  
Poly Ethylene ◽  
Epoxy Groups

Star-shaped poly(ethylene oxide-stat-propylene oxide) polymers are end-modified with amine and epoxy groups to produce anisometric microgels with adaptable mechanical and (bio)chemical properties and self-assembly behaviour.

The Structure of Radiation Cross-Linked Poly (ethylene oxide) Gels

1971 ◽  
Vol 29 ◽  
pp. 76-77
Author(s):  
C. E. Cluthe ◽  
G. G. Cocks
Keyword(s):  
Molecular Weight ◽  
Ethylene Oxide ◽  
Parallel Plate ◽  
Average Molecular Weight ◽  
Radical Reaction ◽  
Free Radical Reaction ◽  
Nitrogen Gas ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Initial Viscosity

Aqueous solutions of a 1 weight-per cent poly (ethylene oxide) (PEO) were degassed under vacuum, transferred to a parallel plate viscometer under a nitrogen gas blanket, and exposed to Co60 gamma radiation. The Co60 source was rated at 4000 curies, and the dose ratewas 3.8x105 rads/hr. The poly (ethylene oxide) employed in the irradiations had an initial viscosity average molecular weight of 2.1 x 106.The solutions were gelled by a free radical reaction with dosages ranging from 5x104 rads to 4.8x106 rads.

Preparation of Organized Mesoporous Silica from Sodium Metasilicate Solutions in Alkaline Medium Using Nonionic Surfactants

2003 ◽  
Vol 68 (10) ◽  
pp. 2019-2031 ◽  
Author(s):  
Markéta Zukalová ◽  
Jiří Rathouský ◽  
Arnošt Zukal
Keyword(s):  
Mesoporous Silica ◽  
Ethylene Oxide ◽  
Sodium Metasilicate ◽  
Spherical Particles ◽  
Structure Directing Agent ◽  
Inorganic Species ◽  
Poly Ethylene Oxide ◽  
Acidic Conditions ◽  
Poly Ethylene ◽  
Hydrolysis Of

A new procedure has been developed, which is based on homogeneous precipitation of organized mesoporous silica from an aqueous solution of sodium metasilicate and a nonionic poly(ethylene oxide) surfactant serving as a structure-directing agent. The decrease in pH, which induces the polycondensation of silica, is achieved by hydrolysis of ethyl acetate. Owing to the complexation of Na+ cations by poly(ethylene oxide) segments, assembling of the mesostructure appears to occur under electrostatic control by the S0Na+I- pathway, where S0 and I- are surfactant and inorganic species, respectively. As the complexation of Na+ cations causes extended conformation of poly(ethylene oxide) segments, the pore size and pore volume of organized mesoporous silica increase in comparison with materials prepared under neutral or acidic conditions. The assembling of particles can be fully separated from their solidification, which results in the formation of highly regular spherical particles of mesoporous silica.

Sign in / Sign up

Export Citation Format

Share Document